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What are the main ingredients of Flame Retardant Masterbatch for PC?
Polycarbonate (PC) is a widely used polymer material today. Its performance is excellent, but it is flammable and prone to fire hazards. Therefore, it is urgent to add flame retardants to improve safety. Flame retardant masterbatch, the cover is specially designed for this demand, and its main ingredients are:
The first is phosphorus-based flame retardants, such as organophosphates, polyphosphates, etc. These compounds escape phosphorus and oxygen radicals at high temperatures to block the combustion chain reaction, and have both smoke suppression and low toxicity. There are nitrogen-based flame retardants, such as melamine salts, which release non-flammable gases when heated, dilute oxygen, and reduce the probability of ignition. There are also new flame retardants that introduce halogen-free elements to achieve green environmental protection, reduce toxicity and harm. Inorganic flame retardants such as magnesium hydroxide and aluminum hydroxide, although the heat resistance temperature is limited, are used in combination with organic compounds, which can help the flame retardant effect is significant.
In order to improve the compatibility of flame retardants and PC resins, dispersants, compatible agents and other additives are often supplemented to make them evenly distributed without damaging the physical properties of the body. In addition, the choice of carrier resin is particularly important. The PC itself is mostly used as the carrier to ensure uniform mixing to ensure that the performance of the finished product does not drop.
The flame retardant masterbatch is granulated and mixed to make the main agent and auxiliary materials into a uniform small particle, which is not only convenient for subsequent processing, but also easy to compound with PC raw materials. Its preparation also takes into account thermal stability, migration, smoke output and other aspects, and strives for the best overall performance.
In summary, the main component of Flame Retardant Masterbatch for PC is an organic flame retardant containing phosphorus and nitrogen, or supplemented with inorganic fillers, additives and PC as a carrier, scientifically prepared into granules. This masterbatch is easy to add, has high flame retardant efficiency, and has both environmental protection and excellent processing performance. It is an indispensable auxiliary material for the modern polymer industry.
What is the addition ratio of Flame Retardant Masterbatch for PC?
Polycarbonate (PC), with its strong and tough quality and good light transmission, is widely used in electronics, electrical appliances, transportation and other fields. However, its nature is flammable, it is easy to delay in case of fire, and smoke is generated in case of high temperature. In order to increase its flame retardant effect, flame retardant masterbatch is often added when preparing. For flame retardant masterbatch, the flame retardant is wrapped in a carrier and made by granulation process, which is easy to mix evenly with PC resin. However, the addition ratio must comply with technical specifications, taking into account safety and performance.
In terms of experience, the addition ratio of flame retardant masterbatch depends on the type of flame retardant used and its effective content. Flame retardant masterbatch is commonly used in the market, and its addition amount generally accounts for 5% to 15% of the total weight of PC resin. If you want to achieve V-0 grade flame retardant effect, it usually needs to be between 8% and 12%. However, if only V-2 grade is required, it can be appropriately reduced, about 5%. However, the proportion should not be too high, because the flame retardant masterbatch contains mostly inorganic fillers. If you use too much, you may cause the material properties to decline, such as toughness loss, transparency damage, mechanical strength reduction, and even affect the processing fluidity of the product. Therefore, when designing the formula, technicians must take into account the flame retardant effect and material properties, and take a scientific dosage.
The choice of flame retardant masterbatch also depends on the required flame retardant grade of the finished product. If it needs to pass the UL94 V-0 standard, the type of flame retardant should be selected with good thermal stability. Common flame retardant masterbatches include halogen, phosphorus and halogen-free environmentally friendly types. The amount of halogen may be slightly lower than that of halogen-free type, but the environmental protection is slightly inferior. Phosphorus and halogen-free types are environmentally friendly, but the amount may be slightly higher.
Each flame retardant masterbatch has a recommended addition ratio in the manufacturer, and its instructions should be carefully checked. When blending, first mix the masterbatch with PC resin, and then extrude or injection molding. When the product is completed, its flame retardant properties and other physical and mechanical properties should be inspected to ensure that they meet the needs. If necessary, the addition ratio can be adjusted moderately to make the flame retardant safety and material quality complement each other, which is the best policy.
Does Flame Retardant Masterbatch for PC affect the mechanical properties of PC materials?
Polycarbonate is referred to as PC, which is tough and transparent, and is widely used in many fields such as electronics, automobiles, and construction. However, PC has a low self-ignition point and is easy to release harmful gases when burned, so it is often necessary to add flame retardant masterbatch to increase its flame retardancy. Flame retardant masterbatch is compounded with a carrier polymer and granulated into granules, which is easy to process. However, although it can stop combustion, it has no effect on material properties.
Flame retardant masterbatch is incorporated into PC, how can there be no regrets at all? To stop open flames, it often contains halogens, phosphorus, nitrogen, inorganic fillers, etc. If its chemical or physical structure is different from the main chain of PC, it will be dispersed in the matrix, or agglomerated into groups, and the interface will not be well combined. Therefore, the microstructure is disturbed, and there are minor defects in the material. Common ones such as tensile strength and impact strength decrease, and ductility is weakened. The higher the content of flame retardant masterbatch, the greater the impact on mechanical properties. Especially phosphorus-based, nitrogen-based flame retardants, or inorganic particles such as talc powder and aluminum hydroxide are added, the cohesion is weakened, and the impact strength decreases, which is a common characteristic.
However, in the view of modern processing technology, most flame retardant masterbatches have improved the formula, and the dispersion of fillers is optimized through technologies such as compressors and coupling agents to improve the interface bonding with PC. If the masterbatch and PC are blended evenly, the particle size is appropriate, and the amount added is moderate, the impact on mechanical properties can be significantly reduced. However, if too much is taken, it will inevitably damage the original rigidity and toughness of the main material.
In short, the flame retardant masterbatch added to the PC, although it can play a flame retardant effect, there is a lot of loss to the mechanical properties of the material, the degree of which is related to the formula of the masterbatch, the addition ratio, the mixing process and other factors. When used in high-performance applications, it is necessary to weigh the gains and losses of flame retardant properties and mechanical properties, and carefully select high-quality flame retardant masterbatches with high compatibility and low addition amount to ensure the safety and toughness of the material.
Does the Flame Retardant Masterbatch for PC meet environmental or ROHS standards?
If you have any questions about whether the Flame Retardant Masterbatch for PC can meet the standards of environmental protection and ROHS. Please be reasonable: With the industrial progress of this world, many synthetic materials have emerged in an endless stream, and polycarbonate (PC) is one of the commonly used polymers. However, its flammability is very high, so it is necessary to add flame retardant masterbatch to ensure its safe use. Nowadays, environmental pollution is becoming more and more serious, many harmful elements endanger life, and industry norms are becoming more and more rigorous. ROHS (Restriction of Hazardous Substances Directive) is formulated by the European Union to limit the content of six harmful elements in electronic and electrical products, including lead, cadmium, mercury, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers, etc.
Shangjia prepares flame retardant masterbatch, and there are also a variety of formulations. Its materials are both organic and inorganic. If traditional flame retardants such as bromine compounds, antimony series, etc., or contain harmful heavy metals, it is difficult to meet ROHS and environmental protection standards. If new environmentally friendly flame retardants are used, such as phosphorus series, nitrogen series, silicone, etc., without heavy metals and harmful halogens, and polymer coating, synergistic efficiency and other processes, it can be easier to pass third-party testing and obtain ROHS compliance certificates.
The environmentally friendly Flame Retardant Masterbatch for PC sold in the market now pays more attention to green formulas and strictly controls the production process. Before leaving the factory, it must be tested by SGS, Intertek and other public trust to ensure that the content of various harmful substances does not exceed the ROHS standard limit. However, whether the finished product is absolutely in compliance, it is still necessary to check the product qualification report and the conformity statement presented by the manufacturer. Only in this way can it be concluded that its environmental performance is reliable.
All in all, if the Flame Retardant Masterbatch for PC adopts environmentally friendly ingredients and processes, it can indeed meet the environmental protection standards such as European Union ROHS. However, when purchasing and applying, you must carefully check the product description and compliance certificate, and do not trust its propaganda. Only in this way can we ensure the green environmental protection of subsequent products, without violating the general trend of energy conservation and emission reduction in the times.
What are the storage and usage considerations for Flame Retardant Masterbatch for PC?
Flame Retardant Masterbatch is used to give flame retardant properties to polycarbonate (PC) materials. Its storage and use must follow a careful and meticulous method. This material is unique in nature. If it is not handled properly, it will affect its efficacy, or even cause deterioration, and losses are inevitable. Today's analysis of its precautions is as follows.
The way to store it is in a clean, dry and ventilated place. When moisture invades, it is easy to make the pellets damp and weaken the flame retardant performance. It should be stored in a sealed container, not near water vapor, and it should not be stored with corrosive chemicals. The temperature should not be too high. It is better to stay away from heat sources and fires at room temperature. In case of high temperature, it is easy to make the flame retardant components in it deteriorate and affect the effect of subsequent use. It should be protected from exposure to the sun, and strong direct sunlight is not advisable. Seal tightly with the original packaging bag, store it on the shelf or on the tray, and do not directly contact the ground to prevent moisture absorption. After each opening and use, it should be sealed in time to prevent air intrusion, prolong the storage life, and ensure the same quality.
When using, it is necessary to review the nature of the substance and the batch number to prevent confusion with other plastic raw materials. Before use, if the material is slightly humid, it should be dried first. Generally, it should be kept at about 80 degrees Celsius for two to four hours. Do not make the temperature too high to avoid decomposition. When mixing, it must be fully mixed with the PC base material to make the flame retardant components evenly distributed and ensure that the flame retardant function is not omitted. During the process, the hopper, screw and other equipment should be clean to prevent impurities from mixing in, so as to avoid damage to the performance of the finished product.
Look at the color and appearance of the sheet and grain. If any abnormality is found, the feeding should be stopped and inspected in time. It should be avoided to use with additives sensitive to high temperature decomposition reaction to prevent performance cancellation. Unused flame retardant masterbatch remaining in the equipment should not be retained for a long time. If it needs to be suspended, it must be drained in time. The operator should wear gloves and masks to prevent inhalation of dust and direct contact to ensure safety.
For the connection, store it when it is moisture-proof and sealed, away from high temperature and hot sun; dry and dehumidify before use, and mix it evenly. All of these are necessary rules for the storage of flame retardant masterbatch and cannot be ignored.