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What are the requirements for the component ratio when preparing Flame Retardant CU/CT?
This material is a composite flame retardant, with copper salt and stannate as the core, mixed in a weight ratio of 7:3, and modified with 5% silane coupling agent. The copper salt is selected as basic copper carbonate, and the stannate is selected as zinc stannate. Both need to be air flow crushed to less than 5μm. If the powder is ground and the particle size is uniform, it can be mixed evenly. When mixing, use a three-dimensional mixer with a speed of 15 rpm and mix for 30 minutes to make the distribution deviation of each component less than 2%, and then Flame Retardant CU/CT is obtained. Its copper content is 12% and the tin content is 8%. After X-ray fluorescence analysis, no heavy metals exceed the standard. This process is like a prescription. If the ratio is improper, the flame retardant performance will be greatly reduced, so it needs to be accurately weighed. It is a flame retardant compound for rubber and plastic.
What is the application of Flame Retardant CU/CT in rubber products?
This product is added to styrene-butadiene rubber (SBR) at a dosage of 30%. After mixing in an internal mixer (temperature 120°C), the Shore hardness after vulcanization is 65A and the elongation at break is 350%, which is 15% lower than that without addition. The combustion test reaches UL94 V-0 level, the vertical combustion self-extinguishing time is 2 seconds, and the smoke density level (SDR) is 45, which is 30% lower than the brominated flame retardant. In chloroprene rubber, the addition amount is 25%, the flame retardant level reaches V-1 level, and the oil resistance is excellent. After being immersed in 10# engine oil for 72 hours, the volume change rate is <5%. It has good compatibility with rubber and no obvious change in vulcanization speed. Therefore, it is suitable for rubber products such as cable sheaths and sealing rings, taking into account both flame retardancy and elasticity.
What are the characteristics of the flame retardant mechanism of Flame Retardant CU/CT?
When this material encounters fire, the copper salt first decomposes to generate copper oxide, catalyzing the rubber into carbon, forming a dense carbon layer with a thickness of 0.3mm, like a shield to block oxygen. The stannate releases tin oxide, captures combustion free radicals, and inhibits gas phase reactions. The dual effect makes the flame extinguish quickly. Its decomposition temperature matches the rubber vulcanization temperature (150℃), does not affect crosslinking during processing, and the carbon layer generation rate during combustion is 20% faster than that of a single copper salt, so the flame retardant efficiency is better. In polyvinyl chloride (PVC), it can also absorb HCl gas, reduce corrosive smoke, such as acid scavengers, and reduce fire hazards.
What are the advantages of Flame Retardant CU/CT over other composite flame retardants?
Compared with the bromine-antimony composite system, Flame Retardant CU/CT is halogen-free and antimony-free, and the toxic gas emissions during combustion are reduced by 50%, which meets the RoHS standard. Compared with phosphorus-nitrogen composite flame retardants, it has better compatibility in rubber, the change rate of the rubber Mooney viscosity after mixing is less than 8%, and the processing fluidity is good. Its addition amount is 5-8% less than similar compounding agents. In nitrile rubber, 25% can reach V-0 level, while the phosphorus-nitrogen system requires 30%. Although the cost is 10% higher, the product density is reduced by 5%, and the overall cost performance is better, so it is favored in rubber products with high environmental protection requirements.
What are the specifications for the processing and storage of Flame Retardant CU/CT?
This product needs to be packaged in kraft paper bags lined with PE film, 25kg per bag, and stored in a ventilated warehouse, away from acidic substances to prevent copper salts from being corroded. During processing, the rubber mixing temperature does not exceed 130℃ to avoid the decomposition of stannate, and the mixing time is controlled within 8 minutes to prevent excessive shearing and enlargement of particle size. When used for extrusion products, the die temperature should be 160℃ to fully blend the flame retardant and rubber. Its dust is slightly irritating to the skin. Gloves must be worn during operation. Rinse with clean water after contact, such as skin care and dust avoidance, to ensure safe operation.