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What is the Main Role of Ammonium Polyphosphate for Intumescent Coatings?
Phosphorus is a fire hazard and has always been valued by craftsmen. Today there are ammonium phosphate polymers, called ammonium polyphosphate, which are mainly used in paste coatings for fire protection, especially expansion coatings. Ammonium polyphosphate has stable properties, high temperature in case of fire, chemical changes, release ammonia gas, and decompose polyphosphoric acid. When fire is seen in the coating, ammonium polyphosphate is heated first, releasing acidic phosphorus, which reacts with the co-formulation material. When the acid meets the hydroxyl polymer, it promotes dehydration and carbonization, making the outer layer black carbonization and expansion layer, which is as thick as a shield and dense as a solid altar. Secondly, the expansion layer expands, which can block the heat flow of the flame and delay the flame. And because ammonium polyphosphate decomposes when gas escapes, the foam thickens, making the expansion layer more solid and preventing heat energy from penetrating into the substrate.
Ammonium polyphosphate is responsible for the expansion of the paste film, not only as a carbonization aid, but also as an acid source and a medium to promote the dehydration reaction. Its characteristics are stable, non-hygroscopic, and not easy to dissolve in water, so it is durable and can protect wood, stone, and metal for a long time. The coating is used in the same way as a carbon source and a gas source to form a ternary system of paste film, with phosphorus as the acid source, urea-formaldehyde as the carbon source, and melamine as the foaming gas source. The three complement each other and do their best to make the coating film produce carbon bubbles quickly in case of fire, protect it from the outside, delay the burning of the substrate, be firm and safe, and protect life and property.
Overall, ammonium polyphosphate is an important part of inflatable coatings, which can mainly dehydrate and promote charcoal in case of fire, face fire in the green layer, and heat in the barrier wall, which is beneficial to fire safety. In today's chemical coating processes, it is especially important for its use, which is a new fire protection device.
Ammonium Polyphosphate for Intumescent Coatings?
Ammonium phosphate polymers are an important flame retardant and are widely used in intumescent coatings for fire protection. There are several uses, which are briefly described as follows:
First, it is often compatible with carbon sources and gas sources. Ammonium phosphate polymers should be combined with polyols (such as pentaerythritol) and foaming agents (such as melamine) when entering coatings, and the weight should be determined in proportion. Harmonization is uniform, which can ensure the mechanism of expansion and foaming. When exposed to high temperature in case of fire, acid is released into charcoal, which thickens and forms a layer, isolates the flame, and shields the substrate from burning.
Second, it can be dissolved in water or some organic solutions. When formulating, water-based coating systems are often used for their good compatibility. Ammonium phosphate polymer powder can be dispersed in an appropriate solution first, ground finely and evenly, then mixed with resins and additives, stirred and mixed to make a uniform cloth. If it is a solvent-based system, it can also be selected for its suitable model, which is co-soluble with the solvent to darn the coating performance.
Third, the dosage should be balanced. Depending on the fire rating and use, the addition ratio of ammonium phosphate polymers often accounts for 10% to 30% or even more of the total solid content. If the dosage is too small, the expansion and flame retardant function will be insufficient. If the dosage is too much, the performance of the coating film will be greatly damaged. Therefore, it is necessary to choose the right medium, reconcile and fertilize.
Fourth, construction methods. After the expanded fireproof coating is added with ammonium phosphate polymers, it can be brushed, sprayed, and rolled. It should be applied to steel structures, wood, walls, etc., where flame retardancy is required. After coating, it should be dried naturally, or baked at low temperature to make the film thickness uniform. If multiple layers are applied, the front layer should be dried and then coated with the back layer to increase its firm protection.
Fifth, storage should be cautious. The paint preparation has been completed, and those containing ammonium phosphate polymers should be sealed and stored in a cool place to prevent moisture and agglomeration to maintain long-term effect. Use it immediately after opening, do not store it for a long time, and avoid qualitative change and loss of its nature.
In summary, the application of ammonium phosphate polymers must be combined with appropriate ingredients, and the proportion, dispersion, construction, and storage should be paid attention to, but in this way, the expansion type fireproof coating can recognize its flame retardant and protective function.
How is Ammonium Polyphosphate for Intumescent Coatings?
Ammonium phosphate polymer, known as Ammonium Polyphosphate in the world, is an important member of fire retardant coatings, and its use in expansion coatings is particularly significant. Considering its heat resistance, because of its high thermal decomposition temperature, it can maintain stability and is not easy to decompose when the flame is burning. Its structure is a polymeric state, with polyphosphate as the bone, so that it slowly decomposes at more than 280 degrees Celsius, releasing phosphorus-containing gas. With this mechanism, it can stimulate the carbonation reaction under high temperature conditions. Ammonium phosphate polymer is insoluble in room temperature water when heated, so it is not subject to violent fire and does not easily soften leakage. Thermal stability is better than that of monomer ammonium phosphate, and it is not easy to absorb moisture or be damaged by environmental moisture.
As for the application of intumescent coatings, ammonium phosphate polymers are used in combination with carbon sources and gas sources to release acidic phosphorides immediately when heated, catalyze the carbonization of carbon sources, and both promote expansion. Finally, a dense porous carbon bubble layer is formed on the surface of the substrate. This layer isolates the heat source from the outside, so that the substrates such as wood and steel under the coating are protected from high temperature attack and enhance the fire resistance limit. However, the thermal decomposition of ammonium phosphate polymers will not suddenly fail, and the slow-release effect is often at 300 to 400 degrees, which benefits the hysteresis heating process.
According to experiments, the degree of polymerization of commonly used ammonium phosphate polymers is different, and its heat resistance is slightly different. Those with high polymerization degree have especially high temperature resistance, which is suitable for high-performance fire protection places. Fly ash or smoke is slightly visible, it is caused by normal decomposition and release. In addition, its thermal decomposition products are mostly inorganic phosphates, which are non-corrosive, non-toxic, safe and reliable.
In summary, Ammonium Polyphosphate is the core component of the expansion type fire protection coating. Its heat resistance is excellent, and it can play a superior protective effect in high temperature environment. Today's design of fire protection system, the choice of high-quality ammonium phosphate polymer, can greatly improve the thermal stability and fire resistance of the coating, which is an indispensable good agent for modern fire protection materials.
Is Ammonium Polyphosphate for Intumescent Coatings Environmentally Safe?
Ammonium phosphate polymers are commonly used in today's fire retardant coatings. They produce a lot of chemical reactions between phosphoric acid and ammonia salts, which accumulate and form a powder that is easily soluble in water. Based on this, craftsmen mix other materials to make a fireproof coating, which can be used for wood, stone, metal and other materials. It can spontaneously expand in case of fire and form a bubble-like loose body. It is used to insulate the flame, delay the fire, protect the substrate, and preserve the substance. How is the product environmentally safe?
Examine its production method and body. It has no highly toxic odor, no explosive and insidious, and is extremely stable at room temperature and pressure. In case of high temperature fire, its decomposition is released, mostly water vapor, ammonia, phosphoric acid and other substances, which are common in nature and have no lasting injury. And its residual ash, no heavy metal toxicity, does not pollute soil and waters, is easy to biodegrade, and conforms to the principle of ecological cycle.
However, it should be noted that although the body is not severely harmful, the coating may escape a little dust during combustion, so factory workers should wear protective gear to avoid inhalation of gas. Long-term exposure to high concentration environment, or there is a slight risk of irritating breathing, but compared with other fire retardants such as halogens, bromides, etc., it has been greatly defeated, and there is no worry about carcinogenic toxin storage. If used in combination with certain organic solvents and plasticizers, they should be compatible with their properties and do not cause corrosion to seep, which will damage safety.
At the environmental level, ammonium phosphate polymers do not accumulate in the environment, and the energy consumption in the preparation process is low. It is not like asbestos or heavy metals in ancient times, which accumulate in nature and have lasting hazards. The country has many norms and is listed as a safe and environmentally friendly fireproof material. By extension, civilian industrial use can be widely distributed, without causing ecological disorders, and people can live in peace and fear.
In summary, it can be seen that ammonium phosphate polymers are excellent products for fire safety. They have stable chemical properties, no long-term evils, and are properly applied. They are suitable for the needs of the world. If regulations are followed and arrangements are made prudently, even in the event of a major change in fire, we can also protect people with environmental protection and safety, and benefit Houkun.
How long is the storage and shelf life of Ammonium Polyphosphate for Intumescent Coatings?
Ammonium Polyphosphate (ammonium phosphate salt) is commonly used in intumescent coatings to cover its good effects of fire expansion and heat insulation protection. To ensure that its properties remain unchanged and its effectiveness persists, the storage method must not be careless. The offer is as follows:
Ammonium Polyphosphate is rich in phosphate ions and ammonium ions, and its properties are stable at room temperature and pressure. It should be stored in a cool, dry and ventilated place. It should not be exposed to direct sunlight, and it should be kept away from heat sources and humidity. The container should be airtight to prevent moisture absorption and agglomeration. If the air is humid, it is very easy to absorb moisture and agglomerate, or even partially hydrolyzed, and the effect is greatly reduced. Mixed storage is classified into categories, and should not be stored with reducing agents, strong acids or flammable substances. The receptacle is mostly made of polyethylene and polypropylene, and should not be made of metal or rusty containers. Every time it is unsealed, it should be sealed and stored quickly, otherwise it is easy to cause quality passivation.
The ambient humidity of the storage place should not exceed 65%, and the temperature should be between 10 and 30 degrees Celsius. If the warehouse is well ventilated, it can prevent the growth of mold and water vapor condensation. Regular inspections are required during storage to check for moisture or deterioration. If the color is found to be vague, agglomerated, humid or odor, it should be sampled to check its performance and discarded in case of suspicion.
If properly stored, the shelf life of Ammonium Polyphosphate can reach 24 months. When the storage and sealing state is intact and there is no significant change in the properties, the validity period may be moderately extended, but it is better to use it up within the indicated period. After unsealing, in case of humid air environment, its quality is easy to be inferior, so it should be used as soon as possible, and it should not be kept for a long time. If the shelf life exceeds the warranty limit, its chemical properties must be tested. If the properties are as old as the past, it can be used as appropriate. If it has lost its due effect, it should be discarded.
It is necessary to know the use of ammonium phosphate salt. If it is stored properly, the expansion flame retardant effect and the long-lasting quality of the coating can be verified. If the storage is not careful, although it is not long, it is easy to cause damage. When it is burned, it will be difficult to recover. It is to persuade the workers with respect, focusing on compliance and being more careful than daily use.