Flame Retardant Dopo

Flame Retardant DOPO

    Specifications
    HS Code 195931
    Chemical Formula C12H9O2P
    Molecular Weight 216.17 g/mol
    Appearance white to off - white powder
    Melting Point 110 - 112 °C
    Boiling Point 381.9 °C at 760 mmHg
    Flash Point 184.8 °C
    Solubility insoluble in water, soluble in some organic solvents like toluene
    Flame Retardant Mechanism forms a char layer to inhibit combustion
    Thermal Stability good thermal stability
    Low Toxicity relatively low toxicity

    As an accredited Flame Retardant DOPO factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Flame Retardant DOPO in 25 - kg bags, ensuring safe storage and transport.
    Storage Flame Retardant DOPO should be stored in a cool, dry, and well - ventilated area. Keep it away from heat sources, ignition sources, and direct sunlight. Store in a tightly - sealed container to prevent moisture absorption and contamination. Separate from oxidizing agents and incompatible substances to avoid chemical reactions.
    Shipping Flame Retardant DOPO is shipped in sealed, corrosion - resistant containers. It adheres to strict hazardous chemical shipping regulations, ensuring safe transportation to prevent any potential risks during transit.
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    Competitive Flame Retardant DOPO prices that fit your budget—flexible terms and customized quotes for every order.

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    Tel: +8615380400285

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    Flame Retardant DOPO Flame Retardant DOPO
    General Information
    Historical Development
    Since ancient people used fire, there is an inherent need to prevent flames. With the gradual rise of industry, many materials have been subject to frequent fires, so scholars have made great efforts to explore the way of flame retardancy. In the middle of the twentieth century of the Western calendar, organophosphorus compounds began to show their work, and DOPO (nonhydro-10-oxa-10-phosphaphenanthrene-10-oxy) was also precipitated by chemists. Its unique structure, both high-efficiency flameout performance, and good compatibility, have been widely favored since its inception. Later, due to the fact that traditional flame retardants damage the environment and avoid harmful bromine systems, DOPO is widely used because of its environmental protection and halogen-free nature. From resins, coatings, electronics and other industries, it has been used as a flame retardant. After decades of improvement, its process, performance and scope of application have become increasingly refined, and it has become a key player in the industry so far. The development of DOPO shows the principle that scientific progress and social needs resonate.
    Product Overview
    Flame Retardant DOPO is the best of new chemical materials. Its properties are white or yellowish crystalline, have a slight odor, dissolve in a variety of organic solvents, and have a stable chemical structure. It is used in polymers, epoxy resins and polyolefins, etc., and has a special flame resistance and efficiency. Its function is to prevent the spread of combustion, generate phosphate radicals, inhibit flame transmission, and is an important device for the safety of modern materials. Compared with traditional flame retardants, DOPO products are halogen-free and environmentally friendly, have little volatility, and reduce the danger to the human body and the environment. They are also compatible with a variety of compounds, easy to add, and have wide adaptability. They are widely used in the fields of electronics, electrical appliances, and building materials. Its manufacturing process is excellent, the quality is elegant, and the performance of the products is stable. It has been tested by the market
    Physical & Chemical Properties
    DOPO, which is a diphenyl phosphate-based compound, is white or white-like crystalline and has a special odor. Stable in nature, not easy to volatilize, melting point is about 116-120 degrees Celsius, boiling point is as high as 200 ° C or more, mild in chemical properties, can react with strong oxidants or strong acids and bases. Slightly soluble in water, soluble in co-polar organic solvents such as alcohol, ether, acetone. Its molecular structure contains phosphorus and oxygen rings, which improve thermal stability and endow good flame retardant properties. When decomposed at high temperature, phosphoric acid derivatives are released, which can form a dense carbon layer on the surface of the material. Storage needs to be sealed, away from humid heat, and protected from light to prevent deterioration. Its non-combustible, high ignition point, and both environmentally friendly and efficient properties are suitable for a variety of polymer materials as flame retardant additives.
    Technical Specifications & Labeling
    Flame Retardant DOPO, widely used in flame retardants of polymer materials. Its appearance is white to off-white crystalline powder, no odor. The melting point is about 116 to 120 degrees Celsius, and the purity is often more than 98%. Molecular formula C12H9O2P, molecular weight 226.17. Phosphorus content is about 13 to 14 percentage points. Moisture generally does not exceed 0.5%. Soluble in organic solvents, such as acetone, ethanol, benzene, with minimal solubility in water. Packaging is mostly lined with plastic bags and covered with woven bags, the net weight of each bag is 25 kilograms or according to customer requirements. Storage should be in a dry and cool place to prevent sun exposure and moisture. Light packaging and light unloading should be used during transportation to avoid impurities from being mixed in. Product name, batch number, and net weight are clearly marked to facilitate traceability and acceptance.
    Preparation Method
    With Flame Retardant DOPO as the main raw material, take 1-2 equivalents, prepare benzoquinone or its derivatives, dissolve in anhydrous toluene, and control the temperature at 60 to 80 degrees Celsius. Gradually add an alkaline catalyst, such as triethylamine, and stir to make the reaction uniform, which lasts for two to four hours. During this time, DOPO phosphate is nucleophilic added to the double bond of aroquinone, generating new phosphorus-carbon bonds, releasing slight heat. If catalyzed by Lewis acid, often take ZnCl ² or AlCl ², activate the reaction center, and increase the yield. Then cool, remove the supernatant, precipitate with ethanol, wash repeatedly to remove impurities, and filter dry to obtain a white or yellowish solid. The obtained product can be verified by infrared and nuclear magnetism to confirm its structural purity, which is used to give flame retardant effect.
    Chemical Reactions & Modifications
    Flame Retardant DOPO, a pseudonym heterophosphine ring compound, is a commonly used flame retardant in organic synthesis. Its properties are stable, but when it encounters active functional groups, it is prone to reactions, especially with epoxy and isocyanates. Or by addition of hydroxyl groups, it is copolymerized with resins to give the material flame retardant properties. It can also be modified with aromatic compounds to generate new phosphorus-nitride compounds to enhance heat resistance and smoke suppression. There are many modification methods, including the introduction of inorganic fillers, synergistic effect, or grafting polymer chains to improve dispersion and compatibility. The reaction mechanism is mainly free radical capture and dehydration condensation, and finally inhibits combustion. DOPO and its derivatives are widely used in thermoplastics and thermosetting materials. The way of chemical reaction and modification makes it flame retardant, durable and environmentally friendly, which is the key to the innovation of polymer materials.
    Synonyms & Product Names
    Its scientific name is diphenylphosphonic acid, also known as 9,10-dihydro-9-oxo-10-phosphophenanthrene. There are many synonymous names in the market, or DOPO flame retardant, also marked as 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide. There are many trade names, such as ADEKA DOPO, BASF DOPO, SABOFLAME DOPO, FrontierChem DOPO, Yoke DOPO, etc., all of which are famous in the city. It is sometimes referred to as flame retardant phosphophenanthrene, or phosphophenanthrene, implying its delicate structure and unique function. In materials, it is outstanding for its high-efficiency and low-smoke properties, and is often used in plastics, epoxy resins, and polymer composites. It is widely used in international trade and scientific research. Although the names are different, they are the same, all referring to this flame retardant essential product.
    Safety & Operational Standards
    The Flame Retardant DOPO is also a chemical, which is widely used in the field of fire protection of polymer materials. Its properties are slightly irritating, and even the skin, eyes and breathing can cause harm. When handling the product, you must be cautious and not be careless. First of all, it should be properly stored, and it should be placed in a cool and dry room, away from fire and heat sources. The utensils should be tightly closed, not subject to moisture, and avoid mixing with strong oxides and strong acids and alkalis to prevent diseases. Operators should wear protective clothing and hats, wear chemical-resistant gloves, and goggles should not be absent. In the workplace, the windows are often opened for ventilation, and the breath is well ventilated to make the breath fresh. If the skin is splashed occasionally, soak it in clean water urgently; rinse it with running water when entering the eye, and resume medical treatment in severe cases. If the powder or vapor is absorbed by mistake, the patient should go to a ventilated place and seek medical attention as soon as possible. Do not leave the product in an unguarded place. After the work is completed, the residue must be disposed of according to regulations, and cannot be disposed of at will to prevent leakage and pollution of soil and water bodies. To clean up the splash, an inert adsorbent should be used, and a sealed vessel should be filled with a special person to take care of it. In case of fire, apply dry powder, carbon dioxide, and sand. Do not use water injection to prevent severe reactions. All transportation and handling must be handled with care to prevent the risk of package cracking and leakage. Newcomers must be trained first to understand their character and emergency measures. Continuously inspect the post environment. If there is any abnormal condition, make a declaration and operate according to regulations. Rules and regulations, be careful to prevent slack, but this will ensure that the workshop is free of trouble, the operation is Antai, and all are peaceful.
    Application Area
    Flame Retardant DOPO has excellent properties and a wide range of uses. It is the best flame retardant and is widely used in plastics, epoxy resins, polyurethane, rubber and other materials to increase its fire resistance and flame protection effect. Craft products, electronic appliances, building components, and multi-purpose fibers all rely on this. Especially in the polymer material industry, it is often covered with cables to prevent the spread of fires. And because of its environmental protection and high efficiency, it is widely favored by scientific research and industry. The flame retardant parts of automobiles, aviation, and rail transit equipment are also supplemented by DOPO to make them safer and better. Its application is increasingly prosperous and indispensable in modern industry.
    Research & Development
    Since ancient times and the present, scholars have been competing to explore ways to prevent fire. Today, science is flourishing, and the need for flame suppression is particularly urgent. Flame Retardant DOPO are outstanding, stable in nature, and have attracted wide attention. Researchers based on molecular structure, refined the advantages of its phosphorus content, strengthened thermal stability, and paid attention to environmental friendliness and reduced harmful by-products. Optimize the synthesis route, increase the yield, and develop new derivatives to deal with diverse materials, taking into account the convenience of processing and high efficiency of flame retardancy. He also worked hard on the analysis of microscopic mechanisms, gained insight into the principles of shielding free radicals and inhibiting heat release, and achieved fruitful results. Industry-academia collaboration and continuous innovation have made DOPO series products widely used in electronics, building materials, and transportation fields. From this perspective, the research and development of DOPO flame retardant products not only inherits the wisdom of the sages, but also integrates modern technology.
    Toxicity Research
    Flame Retardant DOPO, a useful chemical substance, is widely used in the flame retardant industry. However, its toxicity can not be ignored. Now, according to the prescription, the experimental mice were given, and their physiological reactions were observed by gavage at different doses. If there is no obvious abnormality at the low dose, the middle dose shows slight behavioral retardation, and the high dose causes weight loss, and the shape of liver and kidney is slightly different. Blood tests showed that the activity of liver enzymes increased, and renal function was slightly damaged. After long-term exposure, a few experimental mice had puffy internal organs and local cell damage. However, the limit of acute toxicity is still high, and no death was found from conventional exposure. It has little effect on embryonic development, but accumulation can cause genetic perturbation. Analyzing its structure, when it contains phosphorus and oxygen rings, it can be excreted in urine after metabolism, and the half-failure in the body The conclusion is obvious: appropriate application, no damage; if abnormal, or cumulative exposure, it is necessary to beware of its toxicity.
    Future Prospects
    In today's world, science and technology are changing with each passing day, and the use of materials is becoming more and more important. Flame Retardant DOPO has outstanding performance and is widely used in the polymer industry. Its flame retardant performance and environmental friendliness are both, and it has gradually become an industry leader. As for the future, it is expected that its research and development will be more advanced, and the improvement of molecular structure can combine flame retardancy and compatibility, and its halogen-free and low-toxicity characteristics will become more prominent. With the emergence of new materials and new energy, DOPO may expand its use and enter the fields of aviation, electronics and construction. Material engineers learn from others' strengths and innovate processes to greatly improve its performance. Relying on the guidance of international cooperation and green standards, DOPO products can follow the path of low-carbon environmental protection. Looking ahead, DOPO flame retardants are certain to maintain strong demand in the global market, assist in industrial upgrading, and usher in a new era.
    Where to Buy Flame Retardant DOPO in China?
    As a trusted Flame Retardant DOPO manufacturer, we deliver: Factory-Direct Value: Competitive pricing with no middleman markups, tailored for bulk orders and project-scale requirements. Technical Excellence: Precision-engineered solutions backed by R&D expertise, from formulation to end-to-end delivery. Whether you need industrial-grade quantities or specialized customizations, our team ensures reliability at every stage—from initial specification to post-delivery support.
    Frequently Asked Questions

    As a leading Flame Retardant DOPO supplier, we deliver high-quality products across diverse grades to meet evolving needs, empowering global customers with safe, efficient, and compliant chemical solutions.

    What are the main application fields of Flame Retardant DOPO?
    Flame Retardant DOPO is an exquisite compound in flame retardants and is well-known in the field of modern chemical industry. Its properties are stable, excellent heat resistance, and halogen-free and environmentally friendly, making it a leader in modern flame retardant materials. In today's discussion of its application field, the summary is as follows. First, the electrical and electronic industry. In today's world, electrical circuits are becoming more and more complicated, and the element is hidden in the danger of current. If it encounters heat damage, it may be burned. The introduction of DOPO can significantly improve the flame retardancy of epoxy resins and insulating materials without damaging their dielectric and mechanical strength. It is commonly found in printed circuit boards, fire-resistant connectors, electronic packaging, etc. Second, transportation. Airplanes, rail trains, and automobiles are in great need of lightweight and flame-resistant materials.Flame Retardant DOPO is widely applied to polyester, polycarbonate, polyurethane foam and other polymer materials, so that its structural parts, interiors, seats, etc. have good flame retardant properties. And its low smoke, low toxicity, fire safety, and more in line with many laws and regulations of aerospace and subway buses. Third, construction and decoration. Buildings are towering and densely populated, and fire prevention laws cannot be ignored. Flame Retardant DOPO are said to be applied to coatings, sealing materials, composite panels, etc., such as fireproof doors and windows, ceilings, floors and even thermal insulation systems, which can greatly improve the fire protection level of buildings, and the material color is not easy to turn yellow, increasing its beauty and practicality. Fourth, textile field. Modern household clothing and industrial fibers are easy to burn and damage in case of open flames. DOPO-modified fibers can achieve flame resistance and anti-melting effect. They are widely used in curtains, carpets, mattresses, work clothes, etc., to ensure the safety of the people. Fifth, new energy field. Lithium batteries are often dangerous due to thermal runaway. DOPO and its derivatives can be used as additives and mixed in the electrolyte to inhibit fire and flame, and improve the intrinsic safety of new energy devices. In short, Flame Retardant DOPO have penetrated into polymer materials, construction, transportation, electronics, textiles, and new energy industries due to their unique molecular structure and excellent flame retardant mechanism. This is a witness to the prosperity of materials science and a powerful tool to protect the safety of human settlements.
    How does Flame Retardant DOPO improve the flame retardant properties of materials?
    In today's theory of Flame Retardant DOPO, Flame Retardant DOPOis an important flame retardant. Due to its unique structure, it contains two components of phosphine and aromatic ring, so it can significantly improve the flame retardant performance of the material. Its functions are as follows: First, during pyrolysis, DOPO can release phosphine in the early stage of polymer decomposition. When phosphine encounters high temperature phosphoric acid, it binds to the carbon base and promotes the formation of a carbonized layer. This carbon layer is continuous, hinders the penetration of oxygen, and can also prevent the escape of flammable gases. The fire source is difficult to penetrate deeply, and the combustion is self-microscopic. Secondary reason is that the benzene ring in the DOPO structure is stable and therm The lake benzene ring resists cracking at high temperature and can cooperate with the main chain to inhibit the "explosion" effect. Phosphine participates in the gas phase to capture free radicals, intercept · OH, · H, etc., and interrupt the chain reaction. In this way, the flame propagates, how can it spread? In addition, DOPO is easy to combine with various types of resins and fibres to form covalent bonds or embed in the main chain to improve the compatibility of flame retardants with the base material. The flame retardant effect is long-lasting and not easy to lose. And its dosage is low, which has seen significant effect and does not damage the physical properties of the material. In the way of environmental protection, it does not produce toxic gases and is conducive to green development. In addition, when exposed to fire, DOPO promotes the formation of phosphonic acid or pyrophosphate, and the resulting product has a high melting point, which can be precipitated on the surface to form a protective shell, further curbing the transfer of heat and mass. The complex energy is synergistic with nitrogen sources and halogens to promote each other and double the flame retardant. The structure is modified by molecules to combine multifunctional groups to improve heat resistance and aging resistance, and to expand the flame retardant use. Overall, DOPO has great advantages due to its unique molecular framework, which fuses and promotes each other with polymers, and has a real-time gas and condensation dual-phase flame retardant mechanism. The flame retardant effect is more and more obvious, and the chemical and physical properties are both. The materials used are stable and reliable, and can be widely used in electronics, transportation, and construction. This is exactly what modern flame retardant technology advocates.
    What are the chemical properties and stability of Flame Retardant DOPO?
    Flame Retardant DOPO, is one of the organic phosphorus retardant agents and is widely used in the field of polymer materials fire protection. This physical property is a white crystalline solid, soluble in a variety of organic solvents, such as acetone, ethanol and benzene, slightly soluble in water. In the chemical structure, phosphorus atoms and oxygen form a P = O bond, which has both alkyl and aromatic characteristics, so it is both stable and reactive. In terms of chemical properties, the combination of phosphorus and oxygen of DOPO gives it strong heat resistance, and it is not easy to decompose spontaneously at room temperature and pressure. However, chemical reactions such as cracking or addition can occur under high temperature, strong acid or strong alkali conditions. The active hydrogen atom and epoxy structure in its molecule give it the ability to copolymerize and graft with a variety of compounds. It often reacts chemically with epoxy resins, polyesters and other polymers with this property to enhance the flame retardant effect of materials. When heated at high temperature, DOPO can release phosphorus-containing free radicals and promote the formation of carbon layers, inhibit combustion chain reactions, and reduce flame propagation rates. The phosphorus-containing intermediates generated after the degradation of phosphorus chemical bonds react with free radicals in the combustion process and effectively inhibit flame expansion. In terms of stability, DOPO is extremely stable in general storage environments. Under dark, dry and sealed conditions, its properties are constant, and it is difficult to spontaneously ignite or explode, and there is no worry of violent decomposition. However, it is dangerous to react when mixed with strong oxidants. When storing, it is necessary to prevent the invasion of humid and high temperature environments, so as not to affect its quality. Its toxicity is low, and it is less harmful to the environment and human body. However, protective measures should still be taken when it comes into contact with the skin or inhales dust. In summary, Flame Retardant DOPO has high chemical stability and good reactivity, making it highly suitable as an additive for polymer flame retardant materials. It imparts new flame retardant energy to the material in the event of fire, and is also easy to store and manage safely under normal conditions, so it is widely used in modern flame retardant science.
    Does the Flame Retardant DOPO have an impact on the environment and health?
    Phosphorus-based flame retardant DOPO, which is used in industrial materials in this world, has excellent chemical properties, can effectively inhibit the spread of flames, and protect human lives. Due to its excellent management, phosphorus elements are used to produce highly reactive free radicals, which is not one of the essential elements in the flame. It is harmful to the burning of rare and rare elements. It is similar to the flame retardant and good in ancient times. Therefore, those who need it should not be ignored. However, the environment and health of DOPO cannot be ignored. DOPO and its derivatives, many of which have phosphorus compounds, are stable and stable, and then gather in the natural environment to decompose rapidly. If it does not burn or is not managed, there is a risk of leaving it in soil and water. It can be stored in plants, or cause imbalances in the system, and in the later stage, it contains a certain amount. And it is well known in the family. The skin of DOPO absorbs, inhales or consumes a certain amount, which may affect the liver function of human mammals, or even reproduction and fertility. It has a certain cytotoxicity to the cells of mammals when exposed to high doses. In general, the dosage is limited, and the acute toxicity of the treatment has not been exposed to daily exposure. However, it is necessary to be cautious to prevent micro-damage. The research and application of chemical products in the world requires careful assessment of their "whole life" environment and human health benefits. DOPO flame retardant is the safety of flame retardant products. If it is not used properly and the management is not legal, it will also be a problem. It is necessary to promote the development of more secure alternatives, and it is not necessary to deal with the way of recycling, so that the harm can be done before it occurs. If the user can understand the situation and follow the middle way, use it carefully, and be careful as the beginning, it can be both safe and safe forever.
    What is the dosage and addition method of Flame Retardant DOPO?
    Flame Retardant DOPO is a highly efficient phosphorus-based flame retardant and is widely used in polymer materials. Its real name is 9,10-dihydro-9-oxo-10-phosphophenanthrene-10-oxide, which is chemically stable and has a significant flame retardant mechanism, which can endow the product with excellent fire resistance. The dosage must be carefully weighed according to the nature of the material, the use and the desired flame retardant level. It should not affect the physical properties too much, and it should not be too little to prevent loss of its effectiveness. Generally, polymer materials, such as epoxy resins, polyurethane, and thermoplastics, require about five to twenty parts of DOPO per 100 parts by mass of the material, depending on various systems and national standard flame retardant requirements. If used in high-end applications such as electronic packaging and copper clad laminates, the dosage must be more actuarial to ensure balanced performance. The addition of DOPO to the material is often done in multiple ways. Or it is directly blended with the monomer before polymerization and uniformly dispersed in the high temperature reaction; or after polymerization, it is mixed by mechanical methods, such as in a double-roll open mill, extrusion or internal mixer, and the DOPO powder or solution is slowly input to make it evenly distributed in the matrix material. In some systems, DOPO is first dissolved by solvent method and then impregnated in the matrix, and then the solvent is heated and evaporated to achieve the effect of covering the flame retardant. If it is an epoxy resin system, DOPO can also be added together with a hardener or epoxy monomer to promote the reaction with a catalyst to form an interpenetrating network, taking into account flame retardant and mechanical properties. During the operation, it is recommended to keep the temperature moderate to prevent DOPO from volatilizing or decomposing, mix evenly, and avoid local enrichment. If you need to improve the compatibility with the matrix, you can also modify DOPO appropriately, or use compressors and additives to coordinate to achieve the best balance between flame retardant and material mechanical properties. Ultimately, the dosage and method must be finely adjusted according to actual needs, and do not engage in it. Burning plaster and dialing, in order to obtain efficient flame retardant materials, which not only ensure safety, but also full performance.