Halogen Free Flame Retardant For Pbt

Halogen Free Flame Retardant for PBT

    Specifications
    HS Code 837717
    Flame Retardancy Class UL94 V-0 (or relevant rating)
    Halogen Content Negligible or compliant with halogen - free standards
    Mechanical Strength High tensile strength, flexural strength
    Thermal Stability Good heat resistance, high melting point
    Chemical Resistance Resistant to many chemicals
    Electrical Properties Good electrical insulation
    Processability Easy to mold, extrude
    Dimensional Stability Maintains shape under various conditions
    Impact Resistance Moderate to high impact resistance
    Colorability Can be colored as required

    As an accredited Halogen Free Flame Retardant for PBT factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 5 - kg bags of Halogen - Free Flame Retardant for PBT, suitable for PBT applications.
    Storage Storage for Halogen - Free Flame Retardant for PBT Store the halogen - free flame retardant for PBT in a cool, dry place. Keep it away from direct sunlight, as UV rays can potentially degrade its properties. Ensure the storage area is well - ventilated to prevent the build - up of any harmful fumes. Package it in air - tight containers to avoid moisture absorption, which could affect its effectiveness during application in PBT manufacturing.
    Shipping Halogen - Free Flame Retardant for PBT is shipped in sealed, corrosion - resistant containers. These are carefully packaged to prevent spills. Shipments are via reliable freight carriers, following all chemical transportation safety regulations.
    Free Quote

    Competitive Halogen Free Flame Retardant for PBT prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please call us at +8615380400285 or mail to sales2@liwei-chem.com.

    We will respond to you as soon as possible.

    Tel: +8615380400285

    Email: sales2@liwei-chem.com

    Halogen Free Flame Retardant for PBT Halogen Free Flame Retardant for PBT
    General Information
    Historical Development
    Bromine flame retardant, in the use of plastics, although it has been successful in the past, but because of the release of halogens, harming people and harmful substances, it is increasingly taboo by the world. It is the old craftsmen who began to find ways to replace halogens. Phosphorus, nitrogen and inorganic flame retardants have been gradually introduced into the application of PBT. At first, the performance was not as good as halogens, but the process was refined, and more and more supplements were made. In recent years, there have been calls for environmental protection, regulations have become stricter, and halogen flame retardant scenery has decreased. PBT halogen is a free flame retardant, so it has risen rapidly. Its smoke is low and toxic, and its suppression and heat resistance are not reduced. Manufacturers have followed their own path, widely distributed production and sales, and strategies have also become more and more diverse. Looking at the trend now, halogen flame retardant has retreated and made a virtue,
    Product Overview
    This product is a Halogen Free Flame Retardant for PBT. It adopts a novel chemical formula and is away from halogen components, which is not only environmentally friendly, but also ensures the safety of users. Its body is fine, easy to blend with polybutylene terephthalate (PBT), does not change the function of the body, has long-lasting heat resistance, outstanding flame retardant effect, and inhibits the spread of flames. It is used in electronic, electrical appliances, and automotive components to reduce smoke and poison, and is applied to molding without precipitation or contamination of products. Authorized certification, it meets international standards such as ROHS and REACH. It has a clean appearance, no odor, and excellent compatibility, which makes the product have both appearance and mechanical properties, and is widely respected by the market. This agent should be in line with the green and low-carbon way, help high-performance plastics, and expand its application prospects.
    Physical & Chemical Properties
    Halogen Free Flame Retardant for PBT, strong and white in color, with a slightly milky appearance, higher melting point than regular products, and non-flammable in case of fire. Its stability, excellent heat resistance, insoluble in water and common organic solvents. It is dry and non-hygroscopic, especially at high temperatures, and rarely reacts with strong acids and bases. The molecular structure is tight, the volatility is low, the volatiles are thin, and the correction is not easy to infect other substances. When applied to PBT, it is very compatible with resins, and can improve the flame resistance level without the escape of salty gas. In case of high temperature carbonization, it can form a tough carbon layer, isolate the air, and stop the spread of flames. It has increased the stability of light and heat, and it is difficult to change color for a long time. The use of materials can actually offset the danger of public hazards, ensuring both safety and environmental protection.
    Technical Specifications & Labeling
    This product Halogen Free Flame Retardant for PBT. It has excellent properties, is pure and halogen-free, and can be environmentally friendly. Shape like white or slightly yellow fine powder, uniform particle size, easy to mix. Decomposition temperature is higher than 280 degrees Celsius, excellent heat resistance, and adapts to a variety of processes. High oxygen index, little smoke during combustion, effectively suppressing the spread of flame. Good compatibility, does not damage the mechanical properties of the substrate. It is recommended to add 15 to 20% of the base material. Humidity adsorption rate is low, and storage needs to be dry and ventilated to avoid exposure. Paper-plastic composite bags are commonly used for packaging, with a net weight of 25 kilograms per bag. It is widely used in the fields of electronics, electrical appliances, automobiles, etc., and meets the European Union ROHS and REACH environmental protection standards.
    Preparation Method
    Phosphorus-based flame retardants are taken as the main raw materials, supplemented by nitrogen-based and silicon-based additives, and polymer organic esters are selected as the matrix. First, the components are mixed in proportion, placed in a high-temperature melt extruder, heated and stirred at about 180 degrees Celsius, to promote the raw materials to be fully mixed and polymerized. After water-cooled wire drawing, crushing and granulation, halogen-free flame retardant masterbatch is obtained and used in PBT blending. In the reaction step, acid catalysis is used to promote the reaction of phosphorus-nitrogen compounds with the matrix hydroxyl group to form a stable structure, and silicon-based additives decompose at high temperature into an inert layer to block oxygen conduction. The synergy of various additives can form phosphoric acid and other substances in the flame, isolate heat sources, and inhibit combustion spread. The production process focuses on average temperature control and rate, and the catalytic mechanism is to improve the rapid polycondensation and flame retardant effect. The flame retardant and polymer structure are firmly integrated, resulting in an excellent PBT halogen-free flame retardant product.
    Chemical Reactions & Modifications
    Bromine chlorine and the like, although it can prevent flame, but when it is incinerated, toxic gases escape and damage people. Today, Halogen Free Flame Retardant for PBT. The reason is that phosphorus, nitrogen or inorganic substances are inserted into the polymer chain, causing it to form a carbonized film when it encounters fire, isolating oxygen and preventing the spread of fire. Its preparation is mostly made of phosphate esters, polyphosphazene, aluminum magnesium hydroxide, etc., which are dispersed in the PBT matrix by blending, grafting or micro-nano. This method can greatly increase the flame retardancy and maintain the original mechanical properties of PBT. During the reaction process, a coupling agent is often supplemented to increase interfacial adhesion and prevent migration and loss. The new method is a heavy-duty modification process, which is not only green and environmentally friendly, but also gives the material excellent heat resistance, flame retardancy and stability, and publicizes the application of polymer materials.
    Synonyms & Product Names
    Halogen Free Flame Retardant for PBT is also a halogen-free flame retardant for polybutylene terephthalate. It is also known as halogen-free flame retardant masterbatch, or halogen-free environmentally friendly flame retardant. The market may be labeled with HF FR PBT, Halogenless Flameproof Agent, and PBT special flame retardant. Other synonymous names include low-smoke halogen-free additives, green flame retardant additives, and PBT halogen-free flame retardants. Or simply halogen-free FR for PBT in English, which is called halogen-free fire retardant masterbatch, halogen-free flame retardant imparting agent, such as these names, which refer to the same thing. It is mainly used in PBT resin products to help it isolate fires, reduce smoke and dust, be green and environmentally friendly, and conform to the world's cherished ecological heart. Each trade name may be named EcoFR, SafePBT FR, GreenShield, etc. Although the names are different, they are all designed to be halogen-free flame retardant and fireproof protective materials.
    Safety & Operational Standards
    Halogen Free Flame Retardant for PBT, specially designed for the needs of plastic fire protection. Its quality is clean and halogen-free, suitable for many fields such as electronics, electrical appliances, automobiles, etc. However, the most important thing in using this object is safety and standardization, and it cannot be ignored. Where craftsmen operate, they must be aware of its properties in advance. This object is fine and easy to emit dust. It is first opened and hidden. You must wear a mask to prevent inhalation, gloves to prevent skin contact, long sleeves to protect the body, and a ventilated place is the best place. Do not close and sultry it. It is easy to hurt the eyes, and the contact muscles may have spots. If there is any mistake, do not be afraid to wash and clean urgently, and then seek medical treatment. For weighing and feeding, special utensils must be used, and utensils for eating and drinking must not be mixed. Wet places in poor alleys are prone to moisture and change. The way to collect, when dry and stable, constant temperature and humidity, strictly prevent sun and rain, and keep away from children's play places.
    When operating, it should be fortified according to regulations. Fire-fighting equipment is necessary, and fire awareness still exists. In case of fire, water is not available, and dry powder, foam or carbon dioxide fire extinguishers should be used. The production line should always be ventilated and alarmed. Waste should be handled in accordance with environmental protection laws. Do not arbitrarily dispose of the soil in the ditch, for fear of polluting the environment and involving the people. Standardized signs, dignified and clear, all must be trained in their duties, and do not let ignorance take risks. After each shift, wash your hands and rinse your mouth, and your clothes are Every time the superior constantly inspects, it is necessary to prevent micro-disasters. If there is a leak, it must be corrected, and if there is a violation, it must be eliminated. Safety rules, recited early in the heart, standardized operation, the most important thing is to be constant. If you can abide by this path, the operator will be safe, the factory will be free of disasters, and make the best use of everything to benefit the crowd.
    Application Area
    Halogen Free Flame Retardant for PBT, and has a wide range of application fields. Its characteristics are non-toxic and harmless, and there is no corrosive gas escape during combustion, which meets the needs of environmental protection. Commonly used in electronic appliances, it can make all kinds of connectors, terminals, switch housings, and insulating parts to prevent electrical fires and ensure electricity safety. It can also be used in the automotive industry, suitable for lamp housings, engine parts, etc., to reduce the risk of incineration and improve vehicle safety. Communication, office equipment, etc., need materials that are both anti-inflammatory and environmentally friendly, especially halogen-free PBT mixtures. In the field of building decoration, various flame retardant accessories are selected to adapt to many environmental norms. Nowadays, the industry advocates environmentally friendly new materials, and halogen-free flame retardants are increasingly important to the industry. The future application space is even wider and more boundless.
    Research & Development
    Since the widespread application of Halogen Free Flame Retardant for PBT, its flammability has been hindered by technological progress. However, the long-term use of halogen flame retardants has led to increasing environmental and health concerns. Therefore, they are interested in the development of halogen-free flame retardant materials. The craftsmen have dedicated themselves to studying, with the help of advanced chemical synthesis and molecular modification methods, green elements such as phosphorus and nitrogen have been introduced. The structure is novel, and it has both high efficiency and low smoke and less toxicity. The experiment is precise and screened layer by layer to ensure that the flame retardant is compatible with PBT and excellent, with stable performance and undiminished mechanical properties. The process is gradually optimized, and environmental protection and energy saving are strived. Finally, the new halogen-free flame retardant PBT is not only in line with international regulations, but also meets the requirements of sustainable Sri Lanka is struggling, but the results are impressive, which has promoted the progress of the high-performance engineering plastics industry and opened a new chapter for green manufacturing.
    Toxicity Research
    Bromochlorine flame retardants are used in polybutylene terephthalate, and it has been doubtful for a long time. Today, craftsmen add halogen-free new agents to it to test its toxicity. Take mice as an example, high doses are ingested, and there is no sudden death, and no damage to the liver and kidneys. When seen in vitro cells, if the concentration is moderate, it may be healthy, and the activity is not reduced; if the concentration is too high, there will be mild damage at first, but it is slower than halogen. Dissolution test, looking at the leachate, only low-level organic matter, no halogen secretion in the outside. Vascular test, respiratory tract and skin irritation is minimal, no severe discomfort. Long-term accumulation, difficult to accumulate in the body, easy to metabolize and excrete. After all, although the new agent has reduced toxicity compared with the old method, the operation in the workplace should also be carefully guarded, and the long-term impact of its environment and health should be monitored to ensure safety.
    Future Prospects
    Looking at the Halogen Free Flame Retardant for PBT resins today, it is more and more appropriate to adapt to the trend of environmental protection. It does not contain halogen, less harmful to incineration, and is in line with the purpose of green and low carbon. However, there is still room for improvement in flame retardant performance and processing adaptability. Future research and development should be based on high-efficiency flame retardant, complete function and controllable cost, or new nano-materials can be incorporated and compounded with PBT to enhance its stability and improve combustion performance. It should also take into account that the materials are widely used, involving automobiles, electronics and electrical appliances, and the performance needs to be compatible with multiple needs. It is expected that throughout the market trend, technology and regulations will advance simultaneously, and halogen-free flame retardant PBT will have its own broad application space to promote industrial upgrading and meet the hope of social green development.
    Where to Buy Halogen Free Flame Retardant for PBT in China?
    As a trusted Halogen Free Flame Retardant for PBT manufacturer, we deliver: Factory-Direct Value: Competitive pricing with no middleman markups, tailored for bulk orders and project-scale requirements. Technical Excellence: Precision-engineered solutions backed by R&D expertise, from formulation to end-to-end delivery. Whether you need industrial-grade quantities or specialized customizations, our team ensures reliability at every stage—from initial specification to post-delivery support.
    Frequently Asked Questions

    As a leading Halogen Free Flame Retardant for PBT supplier, we deliver high-quality products across diverse grades to meet evolving needs, empowering global customers with safe, efficient, and compliant chemical solutions.

    What are the main ingredients of Halogen Free Flame Retardant for PBT?
    Halogen Free Flame Retardant for PBT typically consists of three core components: phosphorus-based compounds, nitrogen-containing synergists, and inorganic additives. Phosphorus-based compounds, such as ammonium polyphosphate (APP), resorcinol bis(diphenyl phosphate) (RDP), and triphenyl phosphate (TPP), are the primary flame-retardant agents. They act by promoting char formation in the condensed phase and releasing phosphorus radicals to quench flame reactions in the gas phase. Nitrogen-containing synergists, including melamine, melamine cyanurate (MCA), and piperazine derivatives, enhance the flame-retardant efficiency by releasing non-flammable gases (e.g., ammonia, nitrogen) that dilute oxygen and fuel vapors, while also stabilizing the char layer. Inorganic additives like aluminum hydroxide (ATH) or magnesium hydroxide (MH) serve as auxiliary flame retardants, absorbing heat through endothermic decomposition and releasing water vapor to cool the material surface. These components are often blended in specific ratios to optimize compatibility with PBT (polybutylene terephthalate), a semi-crystalline polyester. For example, a common formulation might combine 60-70% phosphorus-based compounds with 20-30% nitrogen synergists and 5-10% inorganic additives, ensuring balanced flame retardancy, thermal stability, and dispersion in PBT matrices. The absence of halogens (chlorine, bromine) eliminates toxic gas emissions during combustion, aligning with eco-friendly requirements.
    What percentage of Halogen Free Flame Retardant for PBT is added to the PBT material?
    The addition percentage of Halogen Free Flame Retardant for PBT in PBT materials typically ranges from 15% to 30% by weight, depending on the desired flame retardant grade, PBT viscosity, and application requirements. For general-purpose PBT (e.g., non-reinforced grades), 15-20% addition is often sufficient to achieve UL94 V-2 or V-1 ratings, where the material self-extinguishes within 30 seconds with limited dripping. For high-performance applications requiring UL94 V-0 (the highest vertical burning rating), 20-30% addition is necessary. V-0 requires the material to self-extinguish within 10 seconds without dripping that ignites cotton. Glass fiber-reinforced PBT (30-50% glass content) may need slightly higher loadings (25-30%) due to the dilution effect of glass fibers, which reduce the flame retardant’s concentration in the polymer matrix. In specialized cases, such as thin-walled parts (<1mm thickness), additions up to 35% might be required to ensure uniform flame retardancy across the material. However, excessive loading (>35%) can compromise mechanical properties (e.g., impact strength) and processability (e.g., melt flow), so manufacturers often optimize formulations to balance flame retardancy and performance.
    What flame retardant grades can Halogen Free Flame Retardant for PBT achieve?
    Halogen Free Flame Retardant for PBT can achieve several key flame retardant grades, with UL94 ratings being the most widely recognized. At typical addition levels (15-30%), it consistently meets UL94 V-0 for PBT materials with thicknesses ≥0.8mm, where specimens self-extinguish within 10 seconds after two 10-second flame applications, with no dripping that ignites cotton. For thinner sections (0.4-0.8mm), it often achieves UL94 V-1, where self-extinguishing occurs within 30 seconds. Beyond UL94, it complies with other critical standards. For electrical and electronic applications, it meets IEC 60695-2-11 (Glow Wire Ignition Temperature, GWIT) ≥750°C and IEC 60695-2-12 (Glow Wire Flammability Index, GWFI) ≥850°C, ensuring resistance to ignition from hot surfaces. In automotive and industrial uses, it achieves UL 94 5VA/5VB ratings for thick-section materials (>3mm), indicating no burning through the specimen after 5 minutes of flame exposure. It also meets ISO 5660 (Heat Release Rate) requirements, reducing peak heat release by 40-60% compared to untreated PBT, and passes ASTM D3801 (flammability of plastic films), making it suitable for thin PBT films in electrical insulation. These grades validate its versatility across industries requiring strict fire safety.
    How does Halogen Free Flame Retardant for PBT affect the physical properties of PBT materials?
    Halogen Free Flame Retardant for PBT can impact PBT’s physical properties, though effects are manageable with formulation adjustments. Mechanical properties: Tensile strength typically decreases by 10-20% at 20-30% loading, as inorganic flame retardant particles create stress concentration points, weakening the polymer matrix. Impact strength (Charpy or Izod) may drop by 15-30%, especially in glass-reinforced PBT, due to reduced fiber-polymer adhesion. Flexural modulus, however, often increases by 5-15% due to the rigid nature of the flame retardant, enhancing stiffness. Thermal properties: Heat deflection temperature (HDT) under load is generally maintained or slightly improved (by 5-10°C) because the flame retardant’s char layer enhances thermal stability. Melting point remains unchanged, but crystallization rate may slow, affecting molding cycle times. Processability: Melt flow rate (MFR) decreases by 20-40% due to increased viscosity, requiring higher processing temperatures (250-270°C vs. 240-260°C for neat PBT) or screw speeds to ensure proper mold filling. Moisture absorption by some flame retardant components (e.g., nitrogen synergists) can cause hydrolysis in PBT, leading to discoloration or voids, so pre-drying is critical. Mitigation strategies include using surface-treated flame retardant particles (to improve dispersion), adding compatibilizers (e.g., maleic anhydride grafts), or blending with elastomers to restore impact strength, balancing flame retardancy and performance.
    Does Halogen Free Flame Retardant for PBT meet environmental and related certification standards?
    Halogen Free Flame Retardant for PBT complies with major environmental and certification standards, making it suitable for global markets. Environmental safety: As a halogen-free additive, it contains no chlorine, bromine, or fluorine, so combustion releases no toxic halides (e.g., HCl, HBr) or dioxins, reducing risks to human health and ecosystems. It is low in heavy metals (lead, cadmium, mercury) and meets RoHS 2.0 restrictions, prohibiting hazardous substances in electrical/electronic equipment. Regulatory certifications: It aligns with REACH (Registration, Evaluation, Authorization, and Restriction of Chemicals) in the EU, with no Substances of Very High Concern (SVHCs) in its formulation. For automotive applications, it meets ELV (End-of-Life Vehicle) Directive requirements, ensuring compatibility with recycling processes. Industry standards: It complies with UL 94 (flame retardancy), ISO 14001 (environmental management), and IEC 61249 (halogen-free materials for printed circuits). In Asia, it meets China’s GB/T 24279 (flame retardants for wires/cables) and Japan’s JIS C 3005 (plastics for electrical equipment). These certifications validate its suitability for eco-conscious industries, including electronics, automotive, and consumer goods, where sustainability and safety are priorities.