Melamine Resin Coated Ammonium Polyphosphate

Melamine Resin Coated Ammonium Polyphosphate

    Specifications
    HS Code 788926
    Chemical Formula N/A
    Appearance Typically white powder
    Melting Point High (decomposes before melting in common conditions)
    Solubility Insoluble in water
    Density N/A (but has a defined density value depending on form)
    Thermal Stability Good, decomposes at relatively high temperatures
    Flammability Low, acts as a flame retardant
    Ph Value In Water Suspension Near - neutral
    Particle Size Controllable, usually fine powder range
    Mechanical Strength In Solid Form Relatively good once cured
    Resistance To Chemicals Good against many common chemicals

    As an accredited Melamine Resin Coated Ammonium Polyphosphate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 50 - kg bags of Melamine Resin Coated Ammonium Polyphosphate for chemical packaging.
    Storage Melamine Resin Coated Ammonium Polyphosphate should be stored in a cool, dry place away from heat sources and ignition points. Keep it in a well - sealed container to prevent moisture absorption, which could affect its chemical properties. Avoid storing it near incompatible substances. Store in a dedicated chemical storage area to ensure safety and proper inventory management.
    Shipping Melamine Resin Coated Ammonium Polyphosphate is shipped in sealed, moisture - resistant containers. Precautions are taken to prevent physical damage and exposure to substances that could react, ensuring safe transportation.
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    Melamine Resin Coated Ammonium Polyphosphate Melamine Resin Coated Ammonium Polyphosphate
    General Information
    Historical Development
    Since ammonium phosphate began in modern chemistry, it has been widely developed by the world for its flame retardant effect. However, in its application, there are problems such as water solubility and migration, so the performance has not yet been perfected. Therefore, scholars used melamine resin as a coating and applied a film to its surface to form a resin-coated ammonium phosphate. Since the end of the 20th century, technology has gradually matured, and layer-by-layer processes have been introduced. Its physical properties have been greatly improved, and its water resistance and migration resistance have all been improved, and it is even more beneficial to polymer composites. In particular, it is environmentally friendly and halogen-free, meeting the needs of the times. Today, many industries, such as electrical, building materials, transportation, etc., compete for this material as the best. Over the decades, many scientists have pooled their wisdom, and the formula and manufacturing process have been continuously optimized. Melamine Resin Coated Ammonium Polyphosphate has become an important center in the field of flame retardancy.
    Product Overview
    This product is called melamine resin coated ammonium polyphosphate. It is a white powder with uniform particle size and good fluidity. It is made of high-purity ammonium polyphosphate and coated with melamine resin, which has excellent flame retardancy, water resistance and solvent resistance. It is used in plastics, coatings, rubber and other materials to effectively improve its flame retardant grade and reduce the generation of smoke and toxic gases. The coating layer prevents ammonium polyphosphate from direct contact with the substrate or the external environment, significantly improves the dispersion and compatibility, and can also delay the decomposition in case of moisture. Excellent heat resistance, high thermal decomposition temperature, suitable for a variety of high-content processing processes. Widely used in electronics, cables, construction and other industries, it is an environmentally friendly halogen-free flame retardant material, meeting the needs of green sustainable development.
    Physical & Chemical Properties
    Melamine Resin Coated Ammonium Polyphosphate is coated with melamine resin on the surface of ammonium polyphosphate. Its body is dense, white in color, uniform in particle size, and has excellent fluidity. Moderate consistency, easy to disperse in a variety of substrates. High ignition point, refractory in case of fire, no irritating odor. Slightly soluble in water, resistant to acid and alkali corrosion, and not easy to agglomerate when wet. Chemical properties are stable, do not react with most organic matter at room temperature, decompose at high temperature, release non-toxic ammonia and phosphide, form a porous carbon layer, and effectively isolate heat sources. Good compatibility with polymer materials can improve the flame retardant efficiency of the composite. The thermal decomposition temperature is greatly improved compared with uncoated products, and the flame retardant is effective and durable.
    Technical Specifications & Labeling
    The name of this product is melamine resin coated ammonium polyphosphate. It is white powder with uniform particle size and good fluidity. Its phosphorus content is between about 31% and 32%, nitrogen content is about 14% to 15%, thermal decomposition temperature is higher than 280 ° C. It is non-combustible in case of fire and has little soot. The product has a high melting point, slow decomposition, extremely low water solubility, pH value is between 5.5 and 7.0, and the average particle size per gram can reach 15 microns. The appearance is clean and free, the moisture absorption is less than 0.25%, the surface is covered by melamine resin, the weather resistance is long-lasting, and it is easy to disperse in various polymer materials. The package is sealed in a 25kg plastic woven composite bag with a built-in polyethylene bag to keep it dry. Widely used in flame retardants, plastics, rubber, coatings, binders and other fields.
    Preparation Method
    Take melamine, formaldehyde and ammonium polyphosphate as raw materials, use an appropriate amount of water as a solvent, first slowly dissolve ammonium polyphosphate in mild water, stir to disperse evenly. Then at a temperature between 60 and 80 degrees, slowly add melamine and formaldehyde, and the molar ratio is set according to the process. Stir at constant temperature to promote the reaction. During this period, an appropriate amount of acid is added as a catalyst to make melamine and formaldehyde condensate to form hydroxymethyl melamine, and then crosslinked and polymerized on the surface of ammonium polyphosphate, and gradually coated to form a film. After the reaction is terminated, the resulting product is centrifuged, washed, and dried to obtain a melamine resin-coated ammonium polyphosphate finished product. Its catalytic mechanism is acid-catalyzed hydroxymethylation and polycondensation reactions, which accelerate resin formation, improve the compactness of the coating, and enhance the water and heat resistance of the product. It is suitable for various uses of flame retardant materials.
    Chemical Reactions & Modifications
    Melamine resin is coated with ammonium phosphate, which is based on the principle of polymer reaction and applied to the modification process. Ammonium phosphate is easy to absorb moisture, difficult to be compatible with polymers, and has the risk of precipitation. Therefore, melamine resin is used as a coating to isolate moisture and increase its compatibility. Its preparation is first blended with ammonium phosphate, melamine and formaldehyde at a suitable temperature to make formaldehyde and melamine condensate into a network resin, and then ammonium phosphate particles are impregnated in it. Under the chemical reaction, the resin layer is dense, which not only resists wet invasion, but also inhibits migration and precipitation, and has the effect of flame retardancy. After surface modification, functional groups such as hydroxyl groups and amine groups can be introduced to enhance their ability to disperse in polymer matrices. The particle size of the finished product is controllable and the thermal stability is high, making it a good product for flame retardant applications of polymer materials.
    Synonyms & Product Names
    Melamine Resin Coated Ammonium Polyphosphate is ammonium polyphosphate coated with melamine resin. In the chemical industry, it is called MR APP, and it has the synonym of Polyphosphate Ammonium with Melamine Resin Coating. Or Melamine-encapsulated APP, or Resin Coated APP is slightly called, its effect is fire retardant and the material is durable. There are many different product names in the market, such as PERMEL AP230, DURAFOS MR-APP, Exolit AP 418, etc., all of which are advertised by their characteristics. In technical papers, see Melamine Modified Ammonium Polyphosphate, Melamine Resin Microencapsulated APP, etc., and see MR--Ammonium Polyphosphate. These synonyms all refer to the same thing, and the name changes as it is used. To retrieve scientific materials, we need to know the names of the audience and observe their shapes carefully in order to make good use of them.
    Safety & Operational Standards
    Melamine Resin Coated Ammonium Polyphosphate, which is used in chemical production for utensils, must keep in mind the principle of safe operation. Its flammability is non-flammable and slightly toxic. It is suitable for fire prevention. If it is not properly disposed of, it may cause personal harm, or damage the integrity of utensils. When safety is at risk, it is really dependent on norms to ensure. Where you are in charge of this object, it is advisable to set up a special storage place, store it in a dry and ventilated place, away from fire sources and high temperatures, do not expose it to sun and rain, and seal it tightly to prevent it from absorbing moisture and agglomeration. After activation, be sure to close the lid quickly to reduce the risk of volatilization and pollution. During the use period, the operator should wear a dust mask, latex gloves, protective clothing, etc., to protect the body and eyes, and avoid direct contact with the skin and eyes. If accidentally contaminated, rinse Firefighting equipment should be prepared in the workshop, and fireworks should be strictly prohibited. The workplace should be well ventilated to prevent dust accumulation, and special personnel should be appointed to clean it regularly. When handling, it must be lifted and handled with care. It is forbidden to drag and collide, and it cannot be mixed with reducing agents, strong acids, strong alkalis, and flammable substances. If the packaging is damaged or the product leaks, it must be collected with a clean shovel, properly sealed, and cannot be discarded in waterways, soils, and open ditches. Waste should be disposed of centrally according to regulations. Operators should receive pre-job training before entering the workplace to clarify emergency measures. In case of fire, dry powder, carbon dioxide and other fire extinguishing agents should be used, and it is not advisable to directly use water to fight. After the operation is completed, bathe and change clothes, clean and return home, and the work clothes should be washed by special personnel. Daily management requires regular inspections of the integrity of storage and production equipment to prevent problems before they occur; if you feel a pungent odor, leave the scene quickly, open the window to exhaust, and find out the reason before returning to work. To commute to and from work, you need to register the circulation of materials to prevent unrelated people from entering and leaving the workshop at will. Maintain this standard, be careful, Melamine Resin Coated Ammonium Polyphosphate can be relied on to be safe from personal safety, and also help all industries in infinity.
    Application Area
    Melamine Resin Coated Ammonium Polyphosphate, its flame retardant, heat-resistant and insoluble in water, is often an important flame retardant agent. Widely used in plastics, rubber, coatings, fibers and wood and many other fields. Added to polyolefins, epoxy resins, polyurethane materials, can significantly improve its fire resistance. And because its surface is covered with melamine resin, it has excellent dispersion and compatibility, and the particles are not easy to agglomerate, which can make the mechanical properties of the substrate undiminished. It is also common in architectural paint interiors, transportation appliances, and electronic components. It is especially suitable for polymer material synthesis and composite material manufacturing. Where you need to strengthen the flame retardant effect, rely on its help. Environmental protection and halogen-free, waiting to be promoted.
    Research & Development
    Research and development of Melamine Resin Coated Ammonium Polyphosphate to meet the flame retardant requirements of materials. At first, ammonium aminophosphate was used as a base to solidify its chemical properties, but it was easy to absorb moisture and disperse unevenly when exposed, which was not conducive to the application of polymers. Melamine resin was used as a coating and coated its surface to isolate water vapor and increase its dispersion and thermal stability. Chemical coating not only inhibits the loss of flame retardants, but also reduces its impact on the mechanical properties of the matrix. In recent years, the process has been gradually improved to optimize the thickness and uniformity of the package, taking into account flame retardant efficiency and environmental friendliness. Review the gas released in the fire, improve the formula, and strive for green and low toxicity. Today, Melamine Resin Coated Ammonium Polyphosphate has been widely used in electronics, cables, building composites and other fields, demonstrating its outstanding achievements in research and development.
    Toxicity Research
    Melamine Resin Coated Ammonium Polyphosphate is commonly used in flame retardant materials. It is wrapped in ammonium polyphosphate with melamine resin, which not only has the effect of flame retardancy, but also increases water and heat resistance. However, its toxicity cannot be ignored. Considering animal experiments, it was found that high doses can cause slight irritation of the respiratory tract and digestive tract, and long-term exposure may also damage liver and kidney function. However, its toxicity is lower than that of primary melamine and ammonium polyphosphate, because resin wrapping can slow down the release rate and slightly slow the toxic effect. There was no obvious accumulation in short-term exposure, and there was no significant abnormality in the central nervous system and reproductive system. However, those who inhaled a large amount of dust for a long time were at risk of mild inflammation of lung tissue. Therefore, it is advisable to pay attention to protection when using, especially to prevent dust from escaping, so as not to harm health. Overall, this product has low toxicity, but it is safe to use, especially not to be ignored.
    Future Prospects
    Melamine Resin Coated Ammonium Polyphosphate is a treasure of modern flame retardant materials. Refining its theory, the toughness of polyurea formaldehyde, the stability of ammonium sulfate, the outer coating resin, the inner storage function. It generates a carbon film in case of fire, isolates the source of combustion, and is widely used in building materials, plastics, and coatings. Looking at today's increasingly urgent environmental protection needs, material properties continue to advance, and there is still a wide space for improvement of products. Or nano-technology can be used to improve dispersion, and new compounding can be used to enhance flame retardant effect. In the foreseeable future, Melamine Resin Coated Ammonium Polyphosphate will go hand in hand with green technology to help products be lightweight, high-strength, non-toxic and harmless, meet the general trend of recycling, help human beings live and work in peace and contentment, and inspire a new chapter in flame retardant science.
    Where to Buy Melamine Resin Coated Ammonium Polyphosphate in China?
    As a trusted Melamine Resin Coated Ammonium Polyphosphate manufacturer, we deliver: Factory-Direct Value: Competitive pricing with no middleman markups, tailored for bulk orders and project-scale requirements. Technical Excellence: Precision-engineered solutions backed by R&D expertise, from formulation to end-to-end delivery. Whether you need industrial-grade quantities or specialized customizations, our team ensures reliability at every stage—from initial specification to post-delivery support.
    Frequently Asked Questions

    As a leading Melamine Resin Coated Ammonium Polyphosphate supplier, we deliver high-quality products across diverse grades to meet evolving needs, empowering global customers with safe, efficient, and compliant chemical solutions.

    What are the main application fields of Melamine Resin Coated Ammonium Polyphosphate?
    Melamine Resin Coated Ammonium Polyphosphate is ammonium polyphosphate coated with melamine resin. Its stability, insoluble in water, delayed thermal decomposition, and excellent flame retardant effect. Its main application fields are as follows.
    1. Among building materials, it is often used in gypsum board, thermal insulation board, carpet and other composite materials. In case of fire, phosphorus is released, forming a dense carbon layer, which can block heat transfer and oxygen penetration, thereby preventing the spread of fire and ensuring the peace of the house. Adding melamine coating can increase its moisture resistance and prolong the life of the material.
    2. In the plastics and rubber industry, this material is compatible with a variety of polymers. It is suitable for thermoplastics such as polypropylene, polyethylene, EVA, etc., especially for wire and cable, auto parts, railway transportation facilities and other products. After application, the fire rating of the material can be significantly improved, and the color and mechanical properties of the material are not compromised. It has excellent craftsmanship and a wide range of categories.
    3. Covers the preparation of coatings and binders, and is used as a high-efficiency halogen-free flame retardant. Coated on steel structures, wooden components, or applied to the surface of textiles, it can quickly expand into charcoal in case of fire, protecting the body. It is widely relied on by the engineering construction and furniture industries.
    IV. Part of it is used as flame retardant additions to electronic and electrical equipment. Modern electronic products have very high requirements for materials, which require excellent insulation and high flame retardancy. Coated ammonium polyphosphate not only meets its needs, but also reduces the release of smoke and toxic gases.
    V. It is used in the development of environmentally friendly new materials. Low toxicity, no pollution, and good recycling. It conforms to the general trend of green manufacturing and recycling. It is gradually respected in the field of green building and sustainable development.
    Overall, Melamine Resin Coated Ammonium Polyphosphate is widely used in construction, plastics, coatings, binders, electronics, green materials and other important fields due to its unique flame retardant mechanism and excellent physical properties. It helps the progress of modern technology and ensures the safety of civil industry. It is an important wing of contemporary flame retardant materials.
    How is the water resistance of Melamine Resin Coated Ammonium Polyphosphate?
    Melamine Resin Coated Ammonium Polyphosphate is made of melamine resin as the coating material and wrapped in the outer layer of ammonium polyphosphate to improve its performance. The original ammonium polyphosphate is polar and soluble in water, which is easy to dissolve. If it is applied to flame retardant matters alone, crystals often precipitate in case of humid water vapor, which affects its long-term and stability. After being coated with melamine resin, its hydrophilicity is greatly reduced, forming a layer of dense and tough organic film, which blocks the invasion of water.
    Melamine and formaldehyde in the coating layer combine, recombine and cross-link, resulting in a tight structure. Although external water is surrounded, it is difficult to penetrate the core of the particle, so it has obvious resistance to particle dissolution. According to modern experimental tests, when coated ammonium polyphosphate is soaked in water for a long time, its quality loss rate is much lower than that of uncoated products; it can also be exposed to alkaline or slightly acidic environments without physical concerns. Therefore, its water resistance is excellent, which is more than several times that of ordinary ammonium polyphosphate, and it can be called the stronger weatherability among flame retardant materials.
    In addition, the melamine resin itself is heat-resistant and stable, and it is not easy to hydrolyze and decompose in room temperature and humid environment. In case of external solvents or temperature changes, the coating layer is intact, which can protect the ammonium phosphate body from dissolution and loss for a long time. Even in the special environment of high humidity and high temperature, the test results show that its water solubility and dissolution speed are far inferior to those without coating. It is widely used in high-performance flame retardant coatings, plastics and fiber materials, which are conducive to its durability, flame retardancy and safety functions.
    To sum up, the water resistance of Melamine Resin Coated Ammonium Polyphosphate depends on the sealing protection of the outer melamine resin film, so that it can maintain a stable form and insoluble in variable environments. Its superior nature is one of the great benefits for improving the tolerance of chemical materials.
    What are the advantages of Melamine Resin Coated Ammonium Polyphosphate over common ammonium phosphate?
    Melamine Resin Coated Ammonium Polyphosphate has obvious advantages compared with ordinary ammonium phosphate salts. First, ordinary ammonium phosphate salts are more active in nature, easily affected by moisture, easily soluble in water, stored for a long time, easy to agglomerate and deteriorate, and reduce utility consumption. If coated with melamine resin, a dense film layer is formed on the body surface, which can significantly block the intrusion of moisture and atmosphere, and greatly increase its moisture resistance; if it does not agglomerate in case of moisture, it is easy to transport and store.
    Second, when ordinary ammonium phosphate is at high temperature, it decomposes rapidly and generates gas, making it difficult to play the role of heat insulation and flame retardancy for a long time. If coated with melamine resin, the decomposition temperature can be increased, and the phosphorus release in the flame is slow, which is conducive to preventing the decomposition of combustible materials and significantly enhancing the retardation effect. When it is at high heat, the outer layer can be carbonized to form a dense carbon layer, which effectively blocks oxygen and heat, inhibits the spread of fire, and increases its flame retardancy.
    Third, this coating technology can improve the dispersion of ammonium phosphate in polymer materials. Ammonium phosphate is often filled in resins, plastics, coatings, etc., which are prone to precipitation or agglomeration due to large particle size, and the performance is insufficient. After being coated with melamine resin, the surface energy decreases, and it is easy to distribute evenly on the substrate. The compatibility with the substrate is enhanced, and the material properties are improved. The product has a smooth appearance, stable performance, and does not produce white fog or precipitation.
    Fourth, melamine resin has chemical resistance and high stability. After coating, the acid and alkali resistance of ammonium phosphate is also enhanced. The chemical properties are long-lasting, and the application field is greatly expanded. It is not afraid of slight acid and alkali erosion to meet the needs of special working conditions.
    Fifth, this coating layer helps to reduce dust escape, avoid harm to human body inhalation during operation, and also reduce environmental pollution, in line with the contemporary concept of green environmental protection.
    In summary, Melamine Resin Coated Ammonium Polyphosphate is better than ordinary ammonium phosphate in terms of moisture resistance, flame retardancy, dispersion, stability and environmental protection. It is used in high-performance flame retardant materials to demonstrate its value.
    How much is Melamine Resin Coated Ammonium Polyphosphate?
    Melamine Resin Coated Ammonium Polyphosphate is a multi-ammonium polyphosphate coated with melamine resin, which is often used for fire modification of polymer materials. The dosage depends on the nature of the substrate and the expected flame retardant grade.
    In organic substrates such as plastics or resins, if you want to meet high-grade flame retardant requirements such as UL-94 V0, it is often necessary to compound with an intumescent flame retardant system. Melamine Resin Coated Ammonium Polyphosphate is the main flame retardant, supplemented by carbon sources (such as pentaerythritol) and gas sources (such as melamine). The determination of the dosage depends on the compatibility and dispersion of each component. Of course, ammonium polyphosphate itself has excellent flame retardant performance, but when it is not coated with resin, its hygroscopicity is too heavy, which affects the performance of the product. Coated with melamine resin, the moisture sensitivity is greatly reduced, and the compatibility is increased. This is suitable for use.
    Its actual addition amount often varies with the substrate. If between polypropylene, polyethylene or epoxy resins, the addition ratio of Melamine Resin Coated Ammonium Polyphosphate is mostly between 15 and 30% of the mass fraction of the matrix. If you want to achieve a good flame retardant effect without compromising other physical properties, it is often appropriate to use about 18 to 25 mass fractions. If the addition amount is too small, it is difficult to form a dense carbon layer and cannot effectively block combustion. Too much can easily affect the mechanical, processing rheology and other properties of the product.
    When applying, it is necessary to consider the particle size distribution and the configuration of dispersion aids. If the heterogeneous distribution or the agglomeration is not solved, the flame retardant effect will be difficult to achieve. And it must be compatible with other flame retardants and additives used in the system to coordinate the synergistic flame retardant effect between the components. Those who often have experience, according to the specific formula of the small test, and then modify the optimum content. Even in the same matrix, due to the different process conditions and final application requirements, the proportion used also has room for fine-tuning.
    The consideration of the dosage of Melamine Resin Coated Ammonium Polyphosphate focuses on balancing flame retardancy, physical properties and economy. It should be determined carefully according to the material conditions and cannot be generalized.
    What are the precautions for storage and transportation of Melamine Resin Coated Ammonium Polyphosphate?
    Melamine Resin Coated Ammonium Polyphosphate is a chemical product with fire resistance and flame retardant use. Its properties are stable, but the storage and transportation system is the most rigorous. It is described in detail below:
    It is suitable to store in a cool and dry place, away from direct sunlight, and not subject to rain and humidity. The warehouse is well ventilated and the temperature should be constant. Do not avoid hot places. The surrounding walls are firm and the ground is flat to prevent leakage and penetration. The stacking is moderate, and the height should not exceed the limit. Keep a gap from the wall to facilitate ventilation. Do not store with flammable, explosive, and strong acids and alkalis, and keep away from dangerous substances such as fire source electric heating to prevent chemical reactions.
    Its packaging is mostly sealed with plastic woven bags, composite bags, and barrels. Before storage, check that the seal is intact, and the identification is clear, indicating the product name, batch, weight, production date and safety warning. When loading and unloading, it should be handled lightly, and sharp weapons should not be used. You can't drag it with force to prevent the bag from spilling out. In case of damage, it must be sealed and repaired in time to avoid dust escape. In case of moisture, the efficiency will be damaged, and it should be kept dry.
    When transporting, choose a special vehicle, and the compartment should be covered with a canopy to protect it from rain and sun. Be careful to avoid heavy pressure and severe shocks during driving. Do not share it with food, feed, drinks and other daily necessities. Unloading actions should be gentle, the most important thing is to be safe, and beware of falling. Always keep emergency tools with the car. If they are scattered, collect them immediately and beware of environmental pollution.
    Staff are required to wear protective equipment such as masks and gloves to prevent dust inhalation and skin contact. After handling, clean your hands thoroughly and abstain from smoking and drinking.
    Comply with the norms of various laws and regulations, strictly abide by regulations, be vigilant against negligence, and keep their quality safe and safe.