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What are the main uses of Water Insoluble APP?
Water-insoluble ammonium phosphate polymer, commonly known as water-insoluble APP, is a commonly used flame retardant in modern industry and scientific research. It is strong, insoluble in water, has excellent heat resistance and durability, and is widely used in various high-performance materials. In terms of its main uses, it is roughly as follows:
First of all, water-insoluble APP is often added to thermosetting, thermoplastics and resins to improve the flame retardant properties of materials. It is well known that plastics and their composites are flammable, and fires occur frequently, so the demand for flame retardants is increasing. When water-insoluble APP burns at high temperatures, it can release non-flammable gases or form a carbonized protective layer, blocking the contact between oxygen and flames, effectively delaying the combustion rate and protecting the substrate from rapid damage. Not only that, its physical and chemical properties are stable, so after long-term use and multiple heating, the flame retardant effect is still significant, and there is no water analysis.
Secondly, water-insoluble APP is also an important component of wood fire retardant coatings and wall coatings. Its structure is stable and not easy to be eroded by rainwater, so it can be used for fire prevention and anti-corrosion treatment inside and outside buildings. Coating with APP-based coatings on the surface of wooden structures not only prolongs the life of wood, but also is not easy to support combustion in case of fire, greatly improving building safety, and is widely favored by the construction industry.
Because water-insoluble APP is non-toxic, harmless, and meets the requirements of green environmental protection, it is also widely used in children's toys, electronic components, and food packaging. APP is also used as the main flame retardant source, combined with other additives and binders, to develop a variety of high-performance flame retardant composites, providing multiple guarantees for modern industry.
It can also be seen in the transportation industry, such as automobiles, aircraft and high-speed rail interior materials, which have extremely high requirements for fire performance. APP also has a place in such occasions with its excellent activity and stability. To sum up, water-insoluble APP has a wide range of uses, high stability, and wide adaptability. It is a powerful tool for modern society to live and work in peace and contentment and technological progress.
What are the chemical components of Water Insoluble APP?
Water-insoluble ammonium phosphate (APP) is one of the commonly used flame retardant materials today. Its chemical formula can be expressed as (NH PO 🥰) _n, in which the n number can be large or small, and the quality also changes. Water-insoluble APP refers to the higher degree of polymerization, and the degree of polymerization is generally above 100. It is a long-chain polyphosphate, which is mainly composed of ammonium ions and polyphosphate. Its production method is mostly phosphoric acid and ammonia as the main raw materials, which are obtained by concentration, heating and polymerization.
Its main component is polymeric ammonium phosphate, which contains polyphosphate ions and ammonium ions. In the structure, phosphorus atoms and oxygen are connected by P-O-P bonds to form a linear or partially branched polymer skeleton. Common structures such as: - [-PO 🥰 NH -] - _n. Interspersed with trace amounts of unpolymerized ammonium phosphate or ammonium diphosphate impurities, but the main chemical composition is still polymer polymerized ammonium phosphate. According to its degree of polymerization, it can be divided into Type I and Type II. Type II has a higher degree of polymerization, that is, it is more difficult to dissolve in water. Its chemical properties are stable, resistant to high temperature and moisture, and decompose during combustion to produce non-flammable gases, which play an excellent flame retardant effect.
Its main component is ammonium polyphosphate, which contains three elements: phosphorus, nitrogen and oxygen. According to experimental analysis, the phosphorus content is about 30% to 34%, the nitrogen content is about 11 to 16, and the rest is oxygen. Its color is mostly white and fine powder, which is easy to disperse in a variety of polymer materials. During the preparation process, free ammonia and free phosphoric acid that do not participate in the polymerization are mostly retained in very small amounts, and there are very few impurities in those who pass the test.
If the whole is described, the chemical composition of water-insoluble APP is mainly highly polymerized ammonium phosphate, the general formula is (NH~ PO 🥰) _n, in which ammonium root (NH~ 🥰) and polymerized polyphosphate root (PO 🥰~) are interleaved to form a polymer structure. In addition, a very small amount of additives can be added to adjust its thermal decomposition temperature, dispersibility or improve synergistic flame retardancy. However, it is still ammonium polyphosphate. In summary, water-insoluble APP is a high molecular weight ammonium polyphosphate salt with simple main components and stable structure. It is widely used in the flame retardancy of polymer materials, resulting in better safety and flame resistance.
How is the heat resistance of Water Insoluble APP?
Water Insoluble Ammonium Polyphosphate (APP) is one of the important flame retardants in modern materials. Its quality is firm and dense, the granular shape is uniform, and the surface is smooth. Under the action of high temperature, it exhibits excellent heat resistance. The APP molecule contains a polymer chain, and the phosphorus-oxygen bond is very stable, so it is extremely difficult to decompose at room temperature. Only at high temperature and after a long time can it slowly fission. Probably at temperatures as high as 250 to 300 degrees Celsius, subtle decomposition and water escape begin, and after 350 degrees Celsius, it becomes more and more obvious. As for its decomposition products, most of them are polyphosphoric acid and amorphous phosphate, which are stable at high temperatures. The thermogravimetric analysis shows that the initial weight loss temperature is high, and the decomposition temperature of 5% of most polymeric APP can reach more than 300 degrees, indicating that its heat resistance is long-lasting and not easy to dissipate.
And APP can form a dense carbon layer on the surface of the substrate at high temperature, isolating oxygen and heat sources, and inhibiting the spread of combustion, which is the so-called "phase transfer flame retardant effect". Its carbonization temperature is about 280 degrees Celsius, and the resulting carbon layer is resistant to high temperature and stable in structure, enhancing the flame resistance of the body. Furthermore, APP is not easy to produce significant volatile by-products due to heat, nor does it have a strong irritating odor, so it is widely used in polypropylene, polyethylene, wood, epoxy resin and other materials that require high heat resistance. It is an ideal flame retardant component in polymer composite flame retardant materials.
To sum up, the heat resistance of APP is rooted in the stability of its polymer chain and phosphorus-oxygen skeleton, which can withstand high temperature test and is not easy to decompose. In addition, the decomposition temperature is high, the carbon layer protection is significant, the properties are stable, and the thermal cracking products are safe, so it has an outstanding position in the field of polymer material heat resistance modification and flame retardancy. Due to its essence, it has been strong for a long time and is an indispensable element of contemporary materials science.
What should I pay attention to when storing and transporting Water Insoluble APP?
Water-insoluble ammonium phosphate (APP) has stable properties. However, during storage and transshipment, it is especially necessary to be cautious and safe. There are five reasons, which are briefly described as follows:
First, choose a place for storage. The warehouse must be dry and ventilated, away from moisture and water sources. In case of moisture, the APP may be invaded by moisture, or gradually deteriorated, or agglomerated and difficult to use, affecting its effectiveness. Waterproofing facilities should be installed, and the roof and ground should not leak. The warehouse wall should be guarded against mildew moss, and it should be constantly swept to keep it clean everywhere.
Second, stack in batches. The bags should not be placed higher than the shoulders to prevent collapse and hurt people. Between each stack, leave a wide gap for ventilation and bypass, so as not to retain moisture. The backing plate is laid at the bottom, so that the goods are not grounded and the earth gas is isolated. And the wall distance is more than one foot, so as to avoid the moisture return of the wall.
3. Proper packaging. APP commonly used woven bags are sealed, and each bag must be strictly sealed, so as not to leak. When accessing and handling, handle it with care to prevent damage and leakage. In case of package rupture, it should be repaired quickly, and do not store with residual bags.
4. Partition storage. APP should not be mixed with acids, alkalis, flammable substances, explosive substances, food, feed, etc. Storage area must be clearly marked and managed by a special person. Do not expose to high temperature sun exposure. In case of sun exposure, or physical and chemical reactions, it will affect its properties.
5. Fire prevention hazards. Although the APP is self-flammable, the bag material is flammable. Open flames are prohibited in the warehouse, and electric welding and smoking are not allowed. Prepare dry powder fire extinguishers and check them on time. Regular inspections, and dispose of any abnormalities immediately.
When transporting, it must be covered with a clean vehicle and a rain cloth to prevent wind and rain from invading. Loading and unloading must be gentle to prevent the outer bag from breaking. It is strictly forbidden to assemble and transport with other chemicals on the way, especially avoid mixing with flammable and corrosive products.
Looking at all things, it is more important to be cautious. Be careful to prevent moisture, properly pack, clearly identify, prohibit mixing, and avoid fire sources. Then the water-insoluble APP can be of its full quality and safe.
What are the advantages of Water Insoluble APP compared to ordinary APP?
Water-insoluble ammonium phosphate (APP) has many advantages over ordinary ammonium phosphate polymers (APP). APP is often used as a flame retardant in plastics, rubber, fibers and wood, and its performance depends on its water solubility and thermal stability. Ordinary APP is mostly water-soluble and easily soluble in water. If it is used in occasions that require water resistance and washable resistance, it is easy to be lost, which greatly reduces the flame retardant efficiency and also affects the mechanical properties and durability of the product. Therefore, the water-insoluble APP came into being after seeking its improvement.
Water-insoluble APP is to adjust the degree of polymerization during the preparation process, or through special surface treatment, so that the molecular chain is long, the structure is dense, and it is difficult to be soluble in water. Its main advantages are three: First, the water resistance is greatly increased, and it is insoluble in water. It is suitable for products, fabrics, coatings, etc. that need to be washed many times or are in a humid environment. It can effectively prevent the loss of flame retardants due to washing, and ensure the flame retardant lasting. Second, the thermal stability is enhanced. Due to the dense molecular structure and high thermal cracking temperature, it can better play a flame retardant role in case of fire. Third, the mobility is small, and it is not easy to migrate outward and precipitate when placed in the product. It can maintain the appearance and performance of the product for a In addition, water-insoluble APP is mostly a polymer with a high degree of polymerization, which decomposes and releases inorganic acids. It can be used in combination with an intumescent flame retardant system to form a dense carbon layer and improve the fire resistance of the material.
And water-insoluble APP has the advantages of low toxicity and environmental protection. It is safer than traditional halogen flame retardants and does not release harmful halogen fumes during combustion. It is respected by modern flame retardant materials. However, its preparation process is more complicated and the cost is slightly higher. However, due to its superior performance, it is widely used in high-demand flame retardant products. It is an ideal choice for coatings, fiberboards, flame-retardant fabrics, electronic and electrical shells, etc. From this point of view, water-insoluble APP is unattainable for ordinary APP due to its excellent water resistance, heat resistance, environmental protection and durability.