Material Safety Data Sheet – ABS Flame Retardant Masterbatch Mflam MB ABS-02

Identification

Product Name: Mflam MB ABS-02
Chemical Type: ABS polymer blended with flame retardant additives
Manufacturer: Provided by respective supplier; contact details found on supplied packaging
Product Use: Used to enhance fire resistance in acrylonitrile butadiene styrene applications
Emergency Contact: Number displayed on packaging; ensure quick access
Synonyms: Flame Retardant ABS Masterbatch

Hazard Identification

Classification: Not classified as hazardous under GHS. Dust can ignite at high concentrations.
Physical Hazards: Fine powder or dust may present risk of ignition in confined areas
Health Hazards: May cause skin or eye irritation through prolonged contact; inhalation of dust brings discomfort to respiratory tract
Label Elements: Hazard symbol not required, but standardized warning for dust and particles generally provided
Precautionary Statements: Avoid breathing dust; wear gloves and safety glasses; clean up using tools that minimize dust generation

Composition / Information on Ingredients

Acrylonitrile Butadiene Styrene (CAS No: 9003-56-9): typical carrier resin, 60–95%
Flame Retardant Additives: Proprietary mixture, often includes brominated or phosphorous compounds
Other Ingredients: May contain antimony trioxide, compatibilizers, and release agents in quantities below reporting thresholds
Impurities: None with significant effect on classification reported by standard specification

First Aid Measures

Inhalation: Move to fresh air right away; seek help if coughing or shortness of breath continues
Skin Contact: Wash area thoroughly with soap and water, remove contaminated clothing
Eye Contact: Rinse open eyes gently with clean water for at least 15 minutes; avoid rubbing
Ingestion: Rinse mouth, do not induce vomiting; consult a medical professional if discomfort persists
Most Important Symptoms: Temporary irritation, itching, or minor abrasion, more severe reactions unlikely with correct usage

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, or water spray
Unsuitable Extinguishing Media: Straight water jet may spread burning particles
Specific Fire Hazards: Produces irritating and potentially toxic fumes including carbon monoxide, brominated gases, and hydrogen halides when burning
Protective Equipment for Firefighters: Self-contained breathing apparatus with full protective gear
Additional Advice: Cool closed containers near fire with water spray, keep run-off water away from sewers and natural waters

Accidental Release Measures

Personal Protection: Use appropriate gloves, protective eyewear, and dust mask if airborne concentrations increase
Environmental Precautions: Prevent product entering drains; contain spill using physical barriers if needed
Methods for Clean-Up: Sweep or vacuum up using equipment with HEPA filter; avoid dry brushing that creates airborne dust
Waste Handling: Collect material for proper disposal according to local, regional, or national regulations

Handling and Storage

Handling: Use with adequate ventilation; prevent spillage and minimize dust formation
Hygiene: Wash hands after handling; do not eat, drink, or smoke in work areas
Storage Conditions: Keep in tightly sealed packaging in cool, dry, and well-ventilated area, shielded from direct sunlight and ignition sources
Storage Segregation: Keep away from oxidizing agents or strong acids; avoid storing near open flames or sources of heat

Exposure Controls and Personal Protection

Occupational Exposure Limits: Not established for the product, but handle as nuisance dust (10 mg/m³ total inhalable, 5 mg/m³ respirable recommended for particulates)
Engineering Controls: Apply local exhaust ventilation where dust may accumulate; general room ventilation usually sufficient in open space
Personal Protective Equipment: Safety glasses with side shields, gloves made of compatible material like nitrile, dust mask or respirator where airborne dust exceeds limits
Special Considerations: Change contaminated clothing after use; always wash exposed skin after finishing tasks

Physical and Chemical Properties

Appearance: Pellets or granules, generally off-white to light tan
Odor: Slight, resinous smell
pH: Not applicable in solid form
Melting/Softening Point: 100–130°C typical of ABS
Boiling Point/Range: Not applicable
Flash Point: Not readily flammable, but finely divided dust can ignite if airborne
Solubility: Insoluble in water
Density: 1.05–1.15 g/cm3 depending on formulation
Vapor Pressure: Not relevant as solid
Other Data: Stable at room temperature, softens upon heating

Stability and Reactivity

Stability: Maintains form under standard temperatures and workplace conditions
Reactivity: No rapid reactions expected with common materials
Hazardous Reactions: Burning produces hazardous toxic gases; avoid heat, flame, and incompatible materials
Conditions to Avoid: High temperatures, sources of ignition, direct sunlight for prolonged periods
Incompatible Materials: Strong acids, bases, and oxidizing agents
Hazardous Decomposition Products: Brominated compounds, carbon oxides, nitrogen oxides, hydrogen halides under combustion

Toxicological Information

Acute Toxicity: No evidence for acute oral or dermal toxicity in expected exposure routes
Inhalation Effects: Dust may cause respiratory tract irritation, coughing, but no systemic toxicity at low concentrations
Skin/Eye Irritation: Minor irritation with prolonged or repeated exposure, mostly due to mechanical effects
Chronic Effects: Regular use with appropriate protection has not shown chronic health impact; product does not contain known carcinogens above regulatory limits
Sensitization: Not typical for the main components, though trace additives may irritate sensitive individuals

Ecological Information

Aquatic Toxicity: Not acutely toxic to aquatic life at anticipated concentrations, but persistent in environment
Bioaccumulation: Components not expected to bioaccumulate significantly, but accumulation in sediment possible
Mobility in Soil: Low mobility due to insolubility in water
Persistence/Degradability: Product is not biodegradable, remains in environmental matrices for extended periods
Other Adverse Effects: Release into environment best avoided; no known impacts at small accidental releases, but best managed according to environmental stewardship practices

Disposal Considerations

Safe Disposal: Dispose as industrial waste according to local regulations; do not dispose in natural water bodies or general trash
Methods: Preferred method is energy recovery via approved incineration, recycling possible if accepted by local processors
Container Disposal: Empty containers can often be recycled after thorough cleaning; otherwise follow municipal instructions for packaging waste
Special Precautions: Prevent dust, do not allow run-off into drains or surface water sources; keep records of waste movement if required by law

Transport Information

UN Number: Not regulated as dangerous goods by international transport guidelines
Proper Shipping Name: Plastic material, not otherwise specified
Transport Hazard Class: Not classified
Packing Group: Not assigned
Special Precautions for User: Keep packaging intact during transit; avoid rough handling or exposure to extreme temperatures
Transport in Bulk: Follow guidelines for loaded/unloaded goods as per local rules; no special restrictions under ADR/RID/IMDG/IATA codes

Regulatory Information

Labeling: No required hazard labeling under global harmonization standards for finished plastic articles
TSCA Status: Components appear on US Toxic Substances Control Act inventory
REACH Status: Compliant for intended industrial use; registration as polymer not applicable
Other Regulations: Observe restrictions on brominated flame retardants in some countries; always check with local regulatory authorities
Workplace Regulations: Use in line with occupational hygiene laws, dust exposure controls, and handling best practices
Right-To-Know: Product information available to staff and handlers; training requirements for safe handling apply where specified by law