Product Name: Acrylic Emulsion for Fire Protection Coatings
Manufacturer: Example Fire Coatings Ltd.
Address: 123 Industry Ave, Springfield, USA
Contact Number: +1-800-555-1234
Recommended Use: Formulated for application on structural steel and construction materials to improve fire resistance and slow structural failure during exposure to flame.
Emergency Contact: 24-Hour Chemtrec: +1-800-424-9300
Product Code: AFP-101
Classification: Not classified as hazardous under OSHA (29 CFR 1910.1200); can cause eye and skin irritation upon direct contact.
Physical Hazards: Contains water and acrylic polymers; not flammable in liquid state but emits hazardous vapors during fire.
Health Hazards: Prolonged inhalation of vapors or dried dust may irritate throat and lungs; skin contact could lead to dermatitis in sensitive individuals.
Environmental Hazards: High concentrations spilled in waterways may impact aquatic organisms, especially due to certain additives and surfactants.
Label Elements: Exclamation mark (Irritant); Safety phrases include: Avoid contact with skin and eyes, Use only with adequate ventilation.
Other Hazards: Dried film can build up static charge during handling or sanding processes.
Acrylic Polymer Emulsion: 40%–55%
Water: 35%–50%
Calcium Carbonate (Filler): 5%–15%
Ammonium Hydroxide (pH Adjuster): Less than 1%
Surfactants and Dispersants: Below 2% (proprietary blend, non-ionic and anionic types)
Bactericide (Preservative): Less than 0.5%
Additives for Flame Retardancy: Melamine and phosphorus compounds less than 2% combined
CAS Numbers: List available on request for raw materials
Inhalation: Move affected person to fresh air; keep at rest in comfortable position, provide artificial respiration only if necessary.
Skin Contact: Remove contaminated clothing, flush skin with plenty of water and mild soap; do not use solvents or thinners.
Eye Contact: Rinse cautiously with water for several minutes; remove contact lenses if present and easy to do so.
Ingestion: Rinse mouth thoroughly; seek medical attention if large amounts swallowed, do not induce vomiting unless directed.
Immediate Concerns: Eye and mucous membrane irritation most likely; no acute toxic effects expected at standard exposures.
Notes for Medical Professionals: Treat symptomatically and support respiratory function when necessary.
Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide; don't use direct water jet on spillage.
Special Hazards: Dried coatings can smolder and emit toxic fumes, including carbon monoxide, acrylic monomers, ammonia.
Protective Equipment for Firefighters: Self-contained breathing apparatus and full protective gear recommended.
Specific Methods: Cool closed containers exposed to fire with water spray to prevent rupture.
Unusual Fire Hazards: Runoff from fire control may cause pollution; prevent entry to waterways or drainage systems.
Personal Precautions: Use appropriate PPE—nitrile gloves, goggles, and splash-proof clothing depending on volume.
Spill Control: Ventilate area, stop leak if safe to do so, use absorbent materials (sand, earth, inert material) to contain liquid.
Cleanup: Scoop or shovel materials into containers for disposal, rinse contaminated area with water avoiding drains.
Environmental Precautions: Prevent spillage from entering sewers or storm drains where possible.
Emergency Procedures: Report large releases to local authorities as required by regulations.
Safe Handling: Avoid splashes by opening containers gently, don’t eat, drink, or smoke during use, wash hands after handling.
Storage Conditions: Store in sealed containers, away from direct sunlight, severe cold, and sources of heat; indoor climate is best.
Incompatible Materials: Strong acids or oxidizers can degrade product.
Special Storage Requirements: Keep above freezing and not above 35°C (95°F); ensure all containers are clearly labeled.
Storage Stability: Stable for at least 12 months in recommended conditions if unopened.
Workplace Limits: No OSHA or ACGIH PEL/TLV specific for acrylic emulsions; general dust/vapor guideline: 10 mg/m3.
Engineering Controls: Provide good general ventilation in working areas; use local exhaust for spray application or sanding dry film.
Personal Protective Equipment (PPE): Safety goggles or face shield, chemical-resistant gloves, protective clothing, NIOSH-approved dust/mist respirator if ventilation insufficient.
Hygiene Measures: Change contaminated clothing, clean PPE after use, wash hands before breaks and after handling.
Appearance: White or off-white milky liquid
Odor: Slight ammonia or acrylic odor
Odor Threshold: Low but detectable
pH: 8.5–9.5
Melting Point/Freezing Point: Approximately 0°C
Boiling Point: 100°C (water component)
Flash Point: Not flammable in liquid state
Solubility: Completely dispersible in water
Vapor Pressure: Similar to water
Density: About 1.18–1.28 g/cm3
VOC Content: <50 g/L
Viscosity: 6,000–15,000 cP at 25°C
Particle Size: Sub-micron dispersion, not visible to naked eye
Chemical Stability: Stable under normal storage and use; no hazardous polymerization reported.
Reactivity: Non-reactive with most building materials; avoid strong acids, alkalis, oxidizers.
Conditions to Avoid: Freezing, excessive heat, prolonged direct sunlight.
Hazardous Decomposition: Degrades to carbon dioxide, carbon monoxide, organic acids under fire conditions; ammonia fumes possible.
Incompatible Materials: Do not mix with bleach, strong oxidizers or acids to avoid unexpected reactions.
Acute Toxicity: Very low; LD50 (oral, rat) > 5,000 mg/kg for base ingredients.
Skin Irritation: Mild irritation possible after repeated or prolonged contact, especially for sensitive individuals.
Eye Irritation: Moderate, especially with liquid splashes; soreness and temporary redness.
Inhalation: Aerosols or fine particulate from dried film may irritate nose and lungs in poorly ventilated areas.
Sensitization: Rare reports of allergic skin reaction.
Long Term Effects: Not classified as carcinogenic under IARC or NTP; chronic exposure to dried dust not expected to cause systemic toxicity.
Mutagenicity/Reproductive Toxicity: No evidence based on ingredient data.
Aquatic Toxicity: Low for main polymer; surfactant and preservative additives may harm aquatic life in concentrated spills.
Mobility in Soil: Emulsion binds well to soil particles; low risk of leaching but can travel with run-off until dry.
Persistence and Degradability: Main acrylic polymer slow to degrade; some additives break down faster in aerobic conditions.
Bioaccumulative Potential: Not expected to accumulate in wildlife; low risk for food chain impacts.
Other Ecological Info: Large volume releases in waterways can create film barriers, reducing oxygen transfer.
Waste Methods: Solidify small quantities, dispose of as non-hazardous construction waste at approved facilities.
Container Disposal: Empty, dry containers may enter regular recycling where allowed; liquid residue should be cured before disposal.
Legislation: Always follow local, state, and federal guidelines for disposal; waste codes may apply in certain contexts.
Avoid: Pouring leftovers into drains or natural watercourses.
UN Number: Not regulated for transport as dangerous goods.
Proper Shipping Name: Not hazardous, water-based emulsion.
Transport Hazard Classes: None.
Packing Group: None required.
Special Precautions: Protect containers from tipping and puncture; keep sealed during all forms of transport.
Environmental Hazards: Not considered a marine pollutant.
Other Details: No restrictions for air, sea, or land transport under current GHS and DOT.
OSHA Status: Not hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
TSCA Inventory: All ingredients appear on the TSCA inventory.
EPA SARA Title III: No listed sections; trace ammonia below reporting levels.
California Prop 65: Not known to contain chemicals listed as causing cancer or reproductive toxicity.
REACH Status: All substances registered or exempt.
WHMIS (Canada): Not controlled; general workplace chemical rules apply.
Label Requirements: Safety Data Sheet available for employees; containers must display safety warnings and basic health advice.
