Product Name: ADK FP-2500S Piperazine Alternative
Recommended Use: Industrial corrosion inhibitor, gas treating applications
Manufacturer: Adeka Corporation
Address: 2-35, Higashiogu 7-chome, Arakawa-ku, Tokyo 116-0012, Japan
Contact Phone: +81-3-3893-7401
Emergency Phone: +81-3-3893-7402
Email: msds@adeka.com
Synonyms: Piperazine Replacement Solution, Amine Blend FP-2500S
CAS Number: Mixture, see ingredients
Product Code: ADKFP2500S
Relevant Identified Uses: Managed under safety guidelines for chemical processors and professionals familiar with amine systems
Classification: Eye irritation (Category 2A), Skin irritation (Category 2), Acute toxicity oral (Category 4), Acute toxicity dermal (Category 4)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, Causes skin irritation, Harmful if swallowed or in contact with skin
Pictograms: Exclamation mark, Health hazard
Precautionary Statements: Avoid contact with eyes, skin and clothing, Wash thoroughly after handling, Do not eat, drink or smoke during use, Wear protective gloves, clothing, eye protection, Seek medical attention if symptoms occur
Other Hazards: May cause respiratory discomfort and allergic reactions for sensitive individuals, Emits ammonia-like odor upon prolonged storage or in case of leaks
Chemical Characterization: Blend of amine-based corrosion inhibitors and solvents
Key Ingredients:
- Piperazine Derivative Compound: 20-30% (CAS Proprietary)
- 2-(2-Aminoethoxy)ethanol: 10-20% (CAS 929-06-6)
- Water: 40-60% (CAS 7732-18-5)
- Stabilizer Additives: 5-10% (CAS Proprietary)
Impurities/Additives: Does not contain impurities classified as hazardous according to GHS
Note: Composition details may vary by production batch; refer to specific batch certificate for trace components
Inhalation: Move person to fresh air as soon as possible, keep at rest, monitor for breathing difficulty, seek medical attention if adverse symptoms linger
Skin Contact: Remove all contaminated clothing, rinse skin immediately with water for at least 15 minutes, use mild soap, do not delay seeking medical help for ongoing irritation
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue flushing, seek medical attention if irritation persists
Ingestion: Do not induce vomiting, rinse mouth thoroughly, administer small sips of water only if person is conscious and alert, consult poison control center or doctor immediately
Most Important Symptoms: Redness, burning sensation, possible nausea and dizziness, dermatitis from repeated contact
Special Notes to Physician: Symptomatic treatment; monitor exposure to amine compounds
Suitable Extinguishing Media: Dry chemical, carbon dioxide, water spray, alcohol-resistant foam
Unsuitable Extinguishing Media: Direct water jet
Specific Hazards: Releases toxic vapors of nitrogen oxides, carbon monoxide, and ammonia on combustion, residue may be corrosive
Protective Equipment: Self-contained breathing apparatus, full protective chemical suit
Specific Methods: Isolate hazard area, remove containers from path of fire if possible, avoid inhalation of vapors, suppress vapors with water spray
Fire Residues: Avoid discharge to natural waters since runoff may cause aquatic harm
Personal Precautions: Evacuate personnel from area, ensure adequate ventilation, avoid breathing vapors or mist, use suitable personal protective equipment including gloves, goggles and respirator
Environmental Precautions: Prevent runoff into drains or waterways, contain spill with non-combustible absorbent (sand, earth), alert environmental authorities if contamination occurs
Cleanup Methods: Absorb spillage, collect waste into closed chemical waste container, flush residual area with water, ventilate area thoroughly, wash tools and protective gear after cleanup
Handling: Use only with adequate ventilation, wear chemical resistant gloves and eyewear, avoid ingestion and inhalation, keep containers tightly closed, avoid spills and unnecessary contact
Storage: Keep in cool, dry, well-ventilated location, store away from acids, oxidizers, strong reducing agents, avoid exposing containers to direct sunlight and high temperatures, keep containers upright and properly labeled, do not reuse empty containers for other purposes
Exposure Limits: No established limit for blend, handle as for piperazine and amine derivatives
Engineering Controls: Provide local exhaust ventilation, ensure eyewash station and emergency shower available near work area
Personal Protection Equipment: Nitrile or neoprene gloves, splash-proof chemical goggles, long-sleeved lab coat or coveralls, NIOSH-certified respirator if airborne concentrations exceed recommended levels
Hygiene Measures: Wash hands thoroughly before eating or drinking, remove and clean contaminated clothing before reuse
Appearance: Clear, pale yellow liquid
Odor: Ammonia-like, slightly sweet
pH: 10.5-12
Melting Point/Freezing Point: Estimated -10°C
Boiling Point: 102-160°C (decomposition may start at higher temperature)
Flash Point: >80°C (closed cup)
Evaporation Rate: Slower than ether, faster than water
Flammability: Not classified as flammable liquid
Vapor Pressure: 1.2 kPa at 25°C
Solubility: Miscible with water
Vapor Density: >1 (Air=1)
Relative Density: 1.06 g/cm³
Partition Coefficient (n-octanol/water): Not available
Decomposition Temperature: >170°C
Viscosity: Moderate, free-flowing
Chemical Stability: Stable under recommended handling and storage conditions
Reactivity: May react with acids to release heat and toxic gases
Possible Reactions: Violent reactions with strong oxidizers, slow corrosion of certain metals
Conditions to Avoid: Excess heat, contact with incompatible chemicals, poor ventilation
Hazardous Decomposition Products: Ammonia, nitrogen oxides, carbon oxides
Polymerization: Not expected under normal process, take care during thermal cycling
Acute Toxicity: Harmful if swallowed or in contact with skin; LD50 (oral, rat) estimated 1100-2000 mg/kg
Skin Corrosion/Irritation: Moderate to strong irritation in animal studies
Serious Eye Damage/Irritation: Causes eye irritation with risk of damage on prolonged exposure
Respiratory Sensitization: Some users may develop respiratory tract irritation with repeated exposure
Carcinogenicity: No component listed as carcinogenic by IARC, NTP, or OSHA
Mutagenicity: Not classified based on available data
Chronic Effects: Dermatitis, eczema, sensitization upon repeated skin contact
Other Information: No evidence of reproductive toxicity or teratogenicity in animal studies for main ingredients
Acute Aquatic Toxicity: Toxic to aquatic life, LC50 (fish, 96h) estimated 50-100 mg/L for main amine component
Long-Term Effects: May cause algae growth inhibition and disrupt aquatic balance, not readily biodegradable
Persistence and Degradability: Expected to persist in aquatic environments, slow breakdown in soil and water
Bioaccumulation Potential: Low, based on structural analysis and water solubility
Mobility in Soil: High, can reach groundwater if released
Other Adverse Effects: Do not discharge to surface water or sewage system without treatment, report accidental releases to authorities
Waste Handling: Treat as hazardous chemical waste, collect in designated containers,
Treatment Methods: Send to approved chemical waste facility, incinerate with afterburner and scrubber for amine residues
Container Disposal: Rinse thoroughly, puncture or crush, dispose through licensed recycler or hazardous waste contractor
Classified Waste: Follow local, state, and national regulations for amine-containing wastes
Special Instructions: Do not pour into drains, avoid environmental contamination
UN Number: UN2735
Proper Shipping Name: Amines, Liquid, Corrosive, n.o.s. (contains piperazine derivatives and amine compounds)
Transport Hazard Class: 8 (Corrosive substances)
Packing Group: III
Label: Corrosive
Sea Transport: IMDG Code: same as above
Air Transport: IATA/ICAO: regulated, follow airline DG handling procedures
Special Transport Precautions: Secure packaging, upright position, emergency instructions available during transit
TSCA Status (US): All major ingredients listed
DSL/NDSL (Canada): Components listed or exempt
REACH (EU): Main ingredients registered or pre-registered
Classifications: OSHA Hazard Communication Standard (29 CFR 1910.1200) – hazardous
Right-to-Know Listings: State and country-specific hazardous substance lists include amine blends
SARA/Title III (US): Not regulated under 302/304/313
Other Requirements: Follow workplace chemical safety, environmental release control, labeling, and reporting guidelines
