Material Safety Data Sheet: Aluminum Diethylphosphinate Flame Retardant (Mflam LX-15)

Identification

Product Name: Aluminum Diethylphosphinate Flame Retardant Mflam LX-15
Chemical Formula: C6H15AlO6P2
CAS Number: 225789-38-8
Synonyms: Aluminum salt of diethylphosphinic acid
Manufacturer: [Company Name and address should be specified by supplier]
Recommended Uses: Additive for flame retardant applications in polymers
Supplier Emergency Contact: [Supplier contact information]
Product Description: White powder with a faint odor, designed to improve fire resistance in plastics and coatings

Hazard Identification

Classification: Eye irritation, Category 2; Specific Target Organ Toxicity – Single Exposure, Category 3 (Respiratory)
Signal Word: Warning
Hazard Statements: May cause eye irritation, may cause temporary discomfort to respiratory system if dust inhaled
Pictograms: Exclamation mark
Precautionary Statements: Use protective eyewear, avoid breathing dust, wash hands thoroughly after handling
Other Hazards: Dust may cause mechanical irritation, not expected to have significant acute toxicity unless ingested or inhaled in large amounts

Composition / Information on Ingredients

Chemical Name: Aluminum Diethylphosphinate
Concentration: 98–100%
Impurities/Additives: Trace moisture, potential trace solvents from manufacturing
Other Ingredients: No hazardous impurities present above disclosure limits

First Aid Measures

Inhalation: Move person to fresh air, keep at rest, seek medical attention if symptoms develop such as coughing or shortness of breath
Skin Contact: Wash skin with soap and water, remove contaminated clothing, seek medical help if irritation persists
Eye Contact: Rinse cautiously with water for at least 15 minutes, lift eyelids, seek medical attention if redness or pain continues
Ingestion: Rinse mouth with water, do not induce vomiting unless directed by medical personnel, get professional medical help if symptoms occur
Note for Medical Providers: Symptomatic treatment; product exhibits low acute toxicity but prolonged exposure may justify monitoring

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide; avoid straight water stream to prevent spreading powder
Specific Hazards: Combustion may release irritating fumes containing phosphorous oxides and aluminum oxide
Protective Equipment: Firefighters should use self-contained breathing apparatus and full protective gear
Special Procedures: Cool containers with water if exposed to fire, prevent runoff into drains or waterways to avoid environmental contamination
Combustion Products: Phosphorus oxides, aluminum oxide, carbon oxides

Accidental Release Measures

Personal Precautions: Wear gloves, protective eyewear, and an approved dust mask (P2 or N95); ensure adequate ventilation
Environmental Precautions: Avoid releasing large amounts into surface water or soil
Containment Methods: Sweep up gently to minimize dust formation and collect using appropriate tools, place in labeled container for disposal
Cleanup Procedures: Ventilate area, wash spill area after removal, dispose of residues in accordance with local regulations

Handling and Storage

Safe Handling: Use with adequate ventilation, avoid breathing dust, practice good hygiene, keep away from incompatible substances (strong oxidizers, acids)
Protective Measures: Use personal protective equipment including gloves and goggles, handle with care to prevent dust formation
Storage Conditions: Store in cool, dry, well-ventilated place, keep container tightly closed, avoid direct sunlight and moisture
Incompatibilities: Avoid storing with strong oxidizing agents, acids, food, or antimicrobial agents
Other Recommendations: Store away from drains and sewers to reduce accidental environmental release potential

Exposure Controls and Personal Protection

Exposure Limits: No specific national occupational exposure limits; minimize dust exposure to generally accepted nuisance dust limits (e.g., 10 mg/m3 total dust)
Engineering Controls: Use local exhaust ventilation; provide washing facilities
Respiratory Protection: Use dust mask or respirator approved for particulates if dust is generated
Eye Protection: Wear safety glasses or goggles
Skin Protection: Wear gloves; choose material impermeable to the chemical
Hygiene Measures: Wash hands before eating, do not consume food or drinks where product is handled, change contaminated clothing promptly

Physical and Chemical Properties

Appearance: White powder
Odor: Faint, non-irritating
Odor Threshold: Not available
pH: 6.0–8.0 (10% suspension in water)
Melting Point: > 300°C (decomposes)
Solubility in Water: Slight (<1 g/L at 20°C)
Vapor Pressure: Negligible at 20°C
Density: 1.3–1.6 g/cm³
Partition Coefficient (n-octanol/water): Not established
Decomposition Temperature: > 300°C
Flammability: Product is non-flammable
Explosive Properties: Not explosive
Other Properties: Stable under normal conditions, no significant volatility, dust may be generated during use

Stability and Reactivity

Chemical Stability: Stable under storage and handling conditions recommended
Reactivity: No dangerous reactions known under normal conditions of use
Conditions to Avoid: Exposure to strong acids, oxidizers, excessive moisture, and high temperature
Hazardous Decomposition Products: Phosphorus oxides, carbon oxides, aluminum oxide when heated to decomposition
Materials to Avoid: Strong oxidizers, acids, alkalis

Toxicological Information

Acute Toxicity: Data on similar phosphinate salts indicate low oral, dermal, and inhalation toxicity; estimated oral LD50 in rats > 2,000 mg/kg
Skin Contact: Not classed as corrosive or an irritant under GHS, but mechanical irritation possible
Eye Contact: May cause temporary irritation, redness, or watering
Inhalation: Dust may cause coughing, throat or respiratory tract irritation, risk higher in poorly ventilated settings
Chronic Effects: No data indicating carcinogenicity or reproductive toxicity; not listed as hazardous by IARC, NTP, or OSHA
Other Effects: Not expected to cause sensitization, not a mutagen or teratogen based on available information

Ecological Information

Acute Aquatic Toxicity: Not expected to be toxic to aquatic organisms based on structure and studies on analogs
Persistence and Degradability: Low solubility and slow biodegradation, anticipated to remain mostly in particulate phase
Bioaccumulative Potential: No significant bioaccumulation expected due to low solubility
Mobility in Soil: Tends to adsorb onto soil particles, unlikely to leach into groundwater
Other Adverse Effects: Large spills could temporarily increase sediment loads; minimize release to water bodies to protect the environment

Disposal Considerations

Waste Treatment Methods: Dispose of in accordance with local, regional, or national waste regulations; landfilling preferred if incineration unavailable
Product Disposal: Gather and place unused material in suitable sealed container for industrial waste management
Contaminated Packaging: Rinse thoroughly before recycling or see chemical waste service
Other Disposal Recommendations: Avoid dumping into sewers or waterways, seek licensed chemical disposal contractor for large quantities

Transport Information

UN Number: Not regulated as dangerous for transport
Proper Shipping Name: Aluminum Diethylphosphinate Flame Retardant
Hazard Class: Not classified as hazardous
Packing Group: Not applicable
Special Precautions: Protect containers from physical damage during transport, store as per storage instructions
Additional Information: Avoid wet conditions during transportation to maintain chemical stability

Regulatory Information

GHS Labeling: Warning (Eye Irritant, Category 2; STOT SE, Category 3)
United States (TSCA): Compound listed
EU (REACH): Pre-registered or registered by supplier
Other Regulations: Not subject to major international transport regulations, not listed under major carcinogen categories
Inventory Status: Listed in many global chemical inventories (check with supplier for country-specific details)
SARA Title III: Not a reportable hazardous substance under Sections 302, 304, or 313
WHMIS Classification (Canada): Non-controlled
Other Legal Requirements: Observe workplace controls and use recommendations to reduce exposure