Product Name: Ammonium Polyphosphate Mflam AP230
Synonyms: APP, Ammonium Polyphosphate
Product Code: AP230
Recommended Use: Flame retardant additive for use in plastics, coatings, adhesives, textiles
Manufacturer: Mflam Chemical Technologies
Supplier Address: [Insert Location]
Emergency Contact: [Insert Emergency Phone Number]
Email: [Insert Manufacturer Contact Email]
Classification: Not classified as hazardous under GHS criteria
Primary Health Risks: Mild irritation to eyes, skin, or respiratory tract may occur with direct contact or large releases
Pictogram: None required
Signal Word: None present
Hazard Statements: May cause mechanical irritation
Precautionary Statements: Use proper PPE; avoid dust generation; store appropriately
Other Hazards: Fine dust might create a small risk of explosion if mixed with air in dusty environments
Chemical Name: Ammonium Polyphosphate
CAS Number: 68333-79-9
EC Number: 269-789-9
Concentration: Greater than 95%
Impurities: Moisture content less than 3%; minor traces of orthophosphates and ammonia
Formulation: White crystalline or powder, nearly odorless
Eye Contact: Flush with plenty of running water for at least 15 minutes. Hold eyelids open. Seek medical attention if irritation persists.
Skin Contact: Wash with soap and water. Take off contaminated clothing. Get medical help for ongoing irritation.
Inhalation: Move to fresh air. Keep the person warm and at rest. Seek medical advice if coughing, dizziness, or difficulty breathing continues.
Ingestion: Rinse mouth. Drink water to dilute. Do not induce vomiting. Get medical attention only if large quantities are ingested or symptoms develop.
Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide (CO2)
Unsuitable Extinguishing Media: Avoid strong water jets to minimize the risk of dust spread
Hazards During Fire: Thermal decomposition can produce ammonia, oxides of phosphorus, nitrogen oxides
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Special Information: Product can suppress nearby flames but generates dense, potentially irritating smoke if burned
Personal Precautions: Avoid breathing dust, ventilate the area, wear protective gloves, eye protection, and dust mask
Environmental Precautions: Prevent significant quantities from entering watercourses, soil, and drains
Methods for Clean-Up: Sweep or vacuum up without generating dust; use non-sparking tools. Place in a container for disposal. Wash remaining traces with plenty of water
Handling Spills: Avoid dry brushing, use damp methods to reduce dust, and clearly identify contaminated tools for proper cleaning
Handling: Handle in a cool, dry, and well-ventilated area. Minimize dust creation with local exhaust if needed. Use correct lifting techniques for large bags or drums. Avoid eating, drinking, or smoking while handling. Wash hands and face thoroughly after use.
Storage: Keep containers tightly sealed. Store on a solid pallet off the ground, away from direct sunlight, heat, acids, bases, and moisture. Use containers made from corrosion-resistant materials. Store in original packaging or approved containers clearly labeled according to workplace regulations.
Exposure Limits: No established occupational exposure limits for ammonium polyphosphate; respect dust nuisance limits (inhalable: 10 mg/m3; respirable: 3 mg/m3)
Engineering Controls: Provide local exhaust ventilation where dust is produced. Keep process closed as much as possible
Respiratory Protection: Use a dust mask or respirator (EN 149 FFP2 or NIOSH N95 rated) if exposure levels approach limits
Eye Protection: Safety goggles or face shield
Skin Protection: Chemical resistant gloves, protective clothing with sleeves to minimize contact
Hygiene Measures: No food or drinks at the workplace, remove contaminated clothing after use, shower before leaving work area
Appearance: White, crystalline powder
Odor: Practically odorless
Odor Threshold: Not applicable
pH (10% solution): 5.5 to 7.0
Melting Point / Range: Above 250 °C (decomposes before melting)
Boiling Point: Not applicable
Flash Point: Not flammable
Evaporation Rate: Not applicable
Flammability: Not classified as flammable
Explosive Properties: Explosive dust/air mixtures possible in extreme conditions
Vapor Pressure: Negligible
Relative Density: 1.8 – 2.1 g/cm³
Solubility: Slightly soluble in water (1-3% at room temperature)
Partition Coefficient (n-octanol/water): Not determined
Decomposition Temperature: Above 240 °C
Chemical Stability: Stable under regular storage conditions
Incompatible Materials: Strong acids, strong bases, reducing agents; contact with water can increase solubility but does not cause dangerous reaction
Hazardous Reactions: No known dangerous reactions with common industrial materials
Conditions to Avoid: Avoid exposure to moisture and elevated temperatures for prolonged time
Hazardous Decomposition Products: Ammonia, phosphorus oxides, nitrogen oxides during fires or above decomposition temperature
Acute Toxicity: Oral LD50 (rat): >2,000 mg/kg (low acute toxicity)
Chronic Toxicity: Not classified as a chronic health hazard
Skin Corrosion/Irritation: Low risk of irritation with prolonged contact
Serious Eye Damage/Irritation: May cause mechanical irritation or mild redness
Respiratory Sensitization: No known effects
Skin Sensitization: No data showing skin sensitization
Carcinogenicity: Not listed by IARC or NTP
Reproductive Toxicity: No evidence of reproductive risk
Mutagenicity: No mutagenic effects observed in tests reported
Ecotoxicity: Practically non-toxic to aquatic life at expected environmental concentrations. Fish (96h, LC50): >100 mg/l (species: rainbow trout)
Persistence and Degradability: Breaks down slowly to ammonium and phosphate ions; low persistence as a pollutant
Bioaccumulation Potential: Not likely to bioaccumulate due to highly soluble ionic forms
Mobility in Soil: Leaching possible with water, more mobile in sandy soils
Other Adverse Effects: Large spills may cause excessive algae growth in waterways (eutrophication risk)
Disposal Methods: Dispose of by landfilling or incineration at authorized facilities according to local regulations
Packaging Disposal: Clean bags, drums or containers before disposal. Recycle if possible
Additional Notes: Do not dump into drains, surface waters, or soil without prior government approval
Waste Codes: Follow national and local codes for phosphate waste streams
UN Number: Not regulated as dangerous goods
Proper Shipping Name: Ammonium Polyphosphate
Transport Hazard Class: Not applicable
Packing Group: Not applicable
Labels Required: None
Special Precautions: Prevent bag breakage and dust leaks during transit; keep dry
Regulatory Status: Not considered hazardous for ground, air, or sea transport
Regulations: Listed on TSCA (US), EINECS (EU), AICS (Australia), DSL (Canada)
Labelling Requirements: No hazard pictograms or warnings required for GHS compliance in standard use
Other Regulatory References: Not covered by REACH restriction or authorization. Not regulated by OSHA as a hazardous chemical, but covered by workplace safety labeling laws
Restrictions: None for typical industrial, commercial, or consumer-accepted applications
