MSDS for DEPAL Flame Retardant Mflam ADP

Identification

Product Name: DEPAL Flame Retardant Mflam ADP
Chemical Family: Phosphinate salt compounds
Manufacturer: [Manufacturer Name and Address]
Contact Number: [Emergency Phone Number]
Recommended Use: Flame retardant additive for plastics, textiles, and coatings
Synonyms: Aluminium diethylphosphinate
Product Code: [Internal Reference Code]
Supplier: [Supplier Name and Address]

Hazard Identification

Classification: Irritant to eyes and skin, may cause respiratory irritation upon dust inhalation
Hazard Statements: Causes eye irritation, prolonged exposure can irritate skin, dust inhalation may lead to coughing and discomfort
Precautionary Statements: Avoid breathing dust, use personal protective equipment, wash hands after handling
Signal Word: Warning
Label Elements: Exclamation mark symbol, protective gloves symbol
Potential Environmental Effects: May be harmful to aquatic life with long-term effects
Health Effects: Possible mild irritation of eyes, skin, and respiratory tract, no chronic toxicity identified from regular industrial exposure

Composition / Information on Ingredients

Chemical Name: Aluminium diethylphosphinate
CAS Number: 225789-38-8
Concentration: 95–100%
Impurities: No hazardous impurities above reportable limits
Other Components: Trace amounts of inorganic phosphinate residues
Molecular Formula: C6H15AlO6P2

First Aid Measures

Inhalation: Move person to fresh air, loosen tight clothing, seek medical attention if persistent irritation develops
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, seek medical advice if rash or irritation continues
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses, continue rinsing, consult a physician if irritation persists
Ingestion: Rinse mouth with water, do not induce vomiting, seek medical help if large amount swallowed or symptoms arise
Most Important Symptoms: Sore throat, red or watery eyes, dry or itchy skin, mild respiratory discomfort
Note to Physician: Treat symptomatically, no specific antidote known

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: None known for product itself
Special Hazards: May generate phosphorus oxides, aluminium oxides, or irritating fumes under fire conditions
Protective Equipment: Wear self-contained breathing apparatus and protective suit, avoid inhaling combustion products
Fire Fighting Instructions: Use water spray to cool unopened containers nearby, contain firefighting effluent to prevent environmental contamination
Explosion Data: Product is not sensitive to mechanical impact or static discharge
Combustion Byproducts: Harmful phosphorus-based gases, potential aluminium-containing particulates

Accidental Release Measures

Personal Precautions: Wear dust mask, goggles, gloves, and protective clothing
Emergency Procedures: Evacuate unnecessary personnel, ventilate area if indoors, avoid dust formation
Containment: Prevent powder dispersal, avoid runoff to sewers or waterways
Cleanup Methods: Sweep up without water, place in suitable labeled containers for disposal, clean area with damp cloth to remove residues
Spill Reporting: Notify local health, safety, and environmental authorities as required

Handling and Storage

Handling: Handle in well-ventilated area, avoid generating or breathing dust, do not eat, drink, or smoke while handling
Protective Practices: Use protective gear (gloves, masks, goggles), wash hands after use, minimize direct contact with product
Safe Storage Conditions: Store in tightly closed original containers, keep away from moisture, heat, direct sunlight, and incompatible materials
Storage Temperature: Maintain at room temperature, avoid freezing or excessive heat
Incompatible Materials: Acids, strong oxidizers, strong bases
Other Precautions: Keep out of reach of children, segregate from food and feedstuffs

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limit set for aluminium diethylphosphinate, observe general dust limits (ACGIH TLV for particulate matter: 10 mg/m3)
Engineering Controls: Use local exhaust ventilation, maintain airflow to reduce dust levels
Personal Protective Equipment: Safety goggles or face shield, chemical-resistant gloves, long-sleeved clothing, dust respirator (P2 or N95 equivalent)
Hygiene Measures: Thorough hand washing after handling, do not touch face or eyes, launder work clothes regularly
Environmental Protection: Limit dust emission to air, avoid release to water bodies

Physical and Chemical Properties

Appearance: Fine, white to off-white powder
Odor: Odorless or faint chemical smell
Odor Threshold: Not applicable
pH (10% in water): 4–6
Melting Point: >300°C (decomposes before melting)
Boiling Point: Not applicable (decomposes prior to boiling)
Flash Point: Not flammable
Evaporation Rate: Not applicable
Flammability: Not classified as combustible
Vapor Pressure: Negligible at room temperature
Vapor Density: Not applicable
Relative Density: 1.3–1.4 g/cm³
Solubility: Very slightly soluble in water
Partition Coefficient (n-octanol/water): Not determined
Decomposition Temperature: >300°C
Particle Size: D50: 10–30 microns

Stability and Reactivity

Chemical Stability: Stable under normal storage and use conditions
Reactivity: Product does not react vigorously with common materials
Hazardous Reactions: None under recommended conditions
Incompatible Materials: Strong oxidizing agents, acids, alkaline substances
Conditions to Avoid: Excess heat, humidity, direct sunlight, strong acids or alkalis
Hazardous Decomposition Products: Phosphorus oxides, aluminium oxides, irritating fumes under intense heat
Polymerization: Product will not undergo hazardous polymerization

Toxicological Information

Routes of Exposure: Inhalation, skin and eye contact, ingestion
Acute Toxicity: Low expected toxicity for single exposure, oral LD50 (rat) > 2,000 mg/kg
Skin Corrosion/Irritation: Mild, transient irritation possible on prolonged or repeated contact
Eye Damage/Irritation: May cause mild, temporary irritation
Respiratory Sensitization: Dust may cause irritation or cough
Chronic Effects: No evidence of sensitization, mutagenicity, carcinogenicity, or reproductive toxicity from standard tests
Specific Target Organ Toxicity: Not identified in available studies
Medical Conditions Aggravated: Asthma, pre-existing respiratory, or skin conditions

Ecological Information

Ecotoxicity: Slightly hazardous to aquatic organisms with potential for long-term adverse effects
Aquatic Toxicity: LC50 (fish, 96 hr): >100 mg/L, EC50 (daphnia, 48 hr): >100 mg/L
Persistence and Degradability: Product persists in environment, slow biodegradation
Bioaccumulation: No significant potential for bioaccumulation in aquatic species
Mobility in Soil: Low to moderate, binds to soil particles
Other Adverse Effects: Avoid uncontrolled release into environment due to phosphorus content

Disposal Considerations

Product Disposal: Dispose as non-hazardous industrial waste in accordance with local, regional, and national regulations
Container Disposal: Rinse thoroughly before recycling or disposal, never reuse packaging for food or drink
Disposal Methods: Landfill preferred for bulk quantities, incineration not recommended due to potential for toxic phosphorus oxides
Precautions: Do not allow to enter drains, surface water, or soil
Regulatory Notes: Check local requirements for phosphorus compound disposal

Transport Information

UN Number: Not regulated for transport
UN Proper Shipping Name: Not classified as dangerous
Transport Hazard Class: None
Packing Group: Not assigned
Environmental Hazards: No classification under transport rules
Special Precautions: Prevent packaging damage, avoid generating dust during transfers
Other Transport Guidance: Ensure containers are secure and properly labeled during transit

Regulatory Information

Regulatory Status: Registered under applicable chemical control regulations, not classified as hazardous under GHS
Label Elements: Warning symbol, risk phrases indicating irritation
TSCA Status (US): Listed
REACH Status (EU): Registered/Exempted
SARA Title III: Not listed as extremely hazardous
Other Global Inventories: Included on Australian AICS, Canadian DSL, Japanese ENCS, Chinese IECSC
Workplace Labeling: Refer to site-specific workplace hazard communications under OSHA, WHMIS
Other Applicable Laws: Singapore Poisons Act, Chinese Catalog of Hazardous Chemicals (not listed)