Ecofriendly Flame Retardant for PP UL94 V2 - Material Safety Data Sheet (MSDS)

1. Identification

Product Name: Ecofriendly Flame Retardant for Polypropylene (PP) UL94 V2
Recommended Use: Designed for manufacturing, compounding, and modifying polypropylene resins in electrical housings, automotive interiors, and household goods where fire risk must stay controlled
Supplier: GreenFlame Technologies Inc.
Address: 214 Oakrow Lane, Columbus, OH 43214
Telephone: 1-800-456-1122
Email: info@greenflametech.com
Emergency Phone: CHEMTREC - 1-800-424-9300

2. Hazard Identification

Hazard Classification: Not classified as a hazardous chemical under OSHA GHS
Health Hazards: Irritates eyes if dust enters, drying effect on skin after prolonged handling, inhalation of dust may cause mild respiratory discomfort
Environmental Hazards: Potential to persist in soil and water, does not bioaccumulate, classified as low risk for aquatic ecosystems
Signal Word: None required
Precautionary Statements: Wash hands thoroughly after use, avoid generating or inhaling dust, use personal protection when handling large volumes

3. Composition / Information on Ingredients

Polyphosphate Ester: 45-55%, CAS: 68333-79-9
Ammonium Polyphosphate: 15-25%, CAS: 68333-79-9
Magnesium Hydroxide: 15-20%, CAS: 1309-42-8
Inert Carriers (Biodegradable): 10-15%, proprietary blend
Hazardous Impurities: Contains less than 0.1% heavy metals, no halogenated compounds, no intentionally added PFAS

4. First Aid Measures

Eye Contact: Rinse immediately with cool running water for at least 20 minutes, remove contact lenses if present, seek medical help if irritation lingers
Skin Contact: Wash off with water and soap, use lotion if dryness or redness occurs
Inhalation: Move to an area of fresh air, seek medical attention if cough persists
Ingestion: Rinse mouth thoroughly, drink water, obtain medical help if any discomfort appears, do not induce vomiting unless told by medical personnel

5. Fire-Fighting Measures

Extinguishing Media: Water spray, dry chemical, foam, CO2
Special Hazards: May emit light smoke and small amounts of ammonia or phosphorous oxide when burned
Protective Equipment: Full protective clothing and self-contained breathing apparatus for significant fires
Advice for Firefighters: Approach from upwind, douse with water spray to prevent dust resuspension, stay vigilant for slippery residues

6. Accidental Release Measures

Personal Precautions: Use dust mask, chemical-resistant gloves, safety goggles
Environmental Precautions: Block from entering waterways, minimize dust spread with gentle sweeping or vacuum set with filter, pack spilled material into sealed containers
Cleanup Methods: Shovel into clean, labeled drums, wash surfaces with water after collecting bulk of material, ventilate affected area
Waste Disposal: Follow local and state solid waste laws, prevent runoff during disposal process

7. Handling and Storage

Handling: Avoid dust creation, use with proper ventilation, wear basic personal safety equipment, avoid inhaling fine particles, wash up before eating or smoking, never reuse empty packaging
Storage Conditions: Keep in cool, dry, and well-ventilated area, seal containers tightly, avoid storage with strong acids or bases, shield from direct sunlight and moisture
Incompatible Materials: Store separately from oxidizers and strong reducing agents

8. Exposure Controls / Personal Protection

Engineering Controls: Work under local exhaust hoods if available, use sealed transfer for bulk handling
Personal Protective Equipment: Safety goggles, lightweight gloves, dust mask or NIOSH-approved respirator where dust exceeds permissible levels
Exposure Limits: Nuisance dust OSHA PEL: 15 mg/m³ (total), ACGIH TLV: 10 mg/m³
Hygiene Measures: Change out work clothes, shower after shift, wash hands before any meal, avoid touching face or mouth during use

9. Physical and Chemical Properties

Form: Off-white to light gray powder
Odor: Mild, earthy scent
Melting Point: Above 200°C
Solubility: Slight in water
Density: About 1.2–1.6 g/cm³
pH (suspension in water): 7–8.5
Flash Point: Not applicable (inorganic, non-flammable base)
Auto-ignition Temperature: Not available
Vapor Pressure: Not volatile
Decomposition Temperature: Above 250°C
Percent Volatiles: Less than 1%

10. Stability and Reactivity

Stability: Stable at room temperature, no rapid breakdown in sealed containers stored as recommended
Incompatible Materials: Strong acids may liberate ammonia, strong bases can release phosphate, will react with oxidizers
Hazardous Decomposition Products: Ammonia, slight phosphorous oxides under fire
Polymerization: No polymerization hazard

11. Toxicological Information

Acute Toxicity: LD50 oral (rat) estimated above 5000 mg/kg, low toxicity
Chronic Effects: No evidence of carcinogenicity, mutagenicity, or reproductive toxicity in ingredient review
Skin/Eye Contact: Mildly irritating in sensitive individuals, unlikely to cause more than temporary discomfort
Inhalation: Prolonged dust inhalation may stir up coughing, no long-term lung impact found
Sensitization: Not classified as a sensitizer

12. Ecological Information

Ecotoxicity: Low risk in aquatic and soil media (LC50 fish >100 mg/L, EC50 daphnia >100 mg/L)
Persistence and Degradability: Major portion inorganic, minimal breakdown in environment, biodegradable carriers break down within months
Mobility: Moderate in soil, low water solubility holds movement in check
Bioaccumulative Potential: Negligible, phosphorus cycle attendee
Other Adverse Effects: No evidence of harmful long-term environmental buildup

13. Disposal Considerations

Waste Disposal: Solidify spilled powder with sand or clay, discard as non-hazardous waste according to state/local rules
Packaging: Empty bags/drums can go with regular industrial refuse after thorough cleaning
Recycling: Not recommended, no practical methods currently
Sewage Disposal: Prevent powder from entering municipal sewage or waterways

14. Transport Information

UN Classification: Not regulated as hazardous for transport
Proper Shipping Name: Flame Retardant Compound, Non-Hazardous
Packing Group: Not applicable
Transport Hazard Class: Not required
Environmental Hazards: None significant for short-term transit, avoid container breaches to minimize powders in environment
Special Precautions: Store upright, keep dry during delivery, use clear labeling of container contents

15. Regulatory Information

OSHA Status: Not classified as hazardous under OSHA 29 CFR 1910.1200
TSCA Inventory: All ingredients listed
SARA Title III: No components present at or above reportable thresholds
California Prop 65: None of the ingredients appear on California’s Prop 65 list
REACH Compliance: All substances registered, fully compliant
RoHS/ELV Compliance: Halogen-free, no heavy metals above thresholds, meets electronics and automotive directives
Other Regulations: Product leaves out any intentionally added PFAS or ozone-depleting chemicals, does not trigger hazardous waste status per RCRA