Product Name: Halogen-Free Flame Retardant for Polyurethane (PU) Foam
Product Code: HFFR-PU-2024
Recommended Use: Flame retardancy additive in flexible and rigid PU foam productions in furniture, bedding, automotive, and insulation.
Manufacturer: SafeChem Industries
Address: 4198 Industrial Park, Emeryville, CA 94608
Phone Number: +1 800 123 4567
Emergency Contact: CHEMTEL, +1 800 255 3924
Email: info@safecheminc.com
GHS Classification: Not classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
Physical Hazards: May form combustible dust when handling large quantities; keep dust levels low
Health Hazards: Mild skin or eye irritation possible with prolonged contact; inhalation of dust may cause transient respiratory discomfort
Environmental Hazards: Low aquatic toxicity but may affect water quality in bulk form
Signal Word: None
Pictograms: None
Precautionary Statements: Avoid inhaling dust, wash hands after contact, use proper ventilation, prevent bulk spillage into drains
Main Component: Ammonium Polyphosphate [CAS #68333-79-9], 65-75%
Secondary Component: Melamine [CAS #108-78-1], 15-25%
Support Additive: Pentaerythritol [CAS #115-77-5], 5-10%
Optional Carrier: Inert mineral filler, <5%
Impurities: None expected at hazardous concentrations
Inhalation: Move individual to fresh air, seek medical attention if symptoms develop
Skin Contact: Wash area with mild soap and warm water, remove contaminated clothing
Eye Contact: Flush eyes with water for at least 15 minutes, avoid rubbing
Ingestion: Rinse mouth, drink water if conscious, seek advice from medical personnel
Most Important Symptoms: Dust exposure may cause sneezing, mild skin redness or eye irritation on sensitive individuals
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Specific Hazards: Combustion can release ammonia, nitrogen oxides, and phosphorus oxides
Protective Equipment: Self-contained breathing apparatus, full protective fire gear
Advice for Firefighters: Stay upwind, prevent contaminated run-off from entering water sources
Special Procedures: Cool containers with water if directly exposed to flames or heat
Personal Precautions: Close off spill area, ventilate, avoid dust generation
Environmental Precautions: Contain runoff, avoid discharge to waterways
Methods for Clean-up: Sweep up and collect in sealable container for reuse or disposal, use HEPA vacuum for final residue
Spill Reporting: Notify site safety representative and regulatory authorities if large quantity is released
Handling: Use local exhaust to maintain dust at minimum, wear gloves, eye protection, and approved mask if dusty
Hygiene Measures: Wash hands thoroughly after handling, do not eat or smoke in work areas
Storage Conditions: Store in closed containers at room temperature, keep dry and out of direct sunlight
Storage Incompatibilities: Avoid moisture, strong oxidizers, acids
Recommended Shelf Life: 24 months from manufacturing date if kept sealed and dry
Exposure Limits: None established by OSHA, NIOSH, or ACGIH for ingredients
Engineering Controls: Local exhaust ventilation, dust extraction systems
Personal Protective Equipment: Dust mask (NIOSH N95 or better), safety goggles, nitrile gloves, protective clothing for bulk usage
General Work Practices: Regular cleaning of work areas, avoid buildup of fine dust on surfaces
Appearance: White to off-white fine powder
Odor: Low odor
pH (10% water dispersion): Range 5.5 – 7.5
Melting Point: Decomposes >300°C (575°F)
Solubility: Partially soluble in water
Bulk Density: 750 – 950 kg/m3
Vapor Pressure: Negligible
Flash Point: Not flammable
Explosive Properties: Dust may form explosive mixtures in air under specific conditions
Chemical Stability: Stable under normal conditions of use and storage
Thermal Decomposition: Releases ammonia and phosphorus oxides at high temperatures
Reactivity: Does not react with most common materials; avoid strong acids and oxidizers
Conditions to Avoid: Prolonged heat above 250°C, strong moisture, open flames for bulk powder
Incompatible Materials: Concentrated acids, strong alkali, oxidizers like peroxides
Hazardous Decomposition Products: Ammonia, nitrogen oxides, phosphorus oxides under intense fire
Acute Toxicity: Low oral toxicity, not expected to cause significant health problems from short-term exposure
Skin Sensitization: Rare mild irritation in sensitive persons
Eye Contact: Causes transient discomfort, washes out with water
Inhalation: Irritating to nose and throat in high concentrations
Chronic Effects: No evidence of chronic toxicity or carcinogenicity in published literature for components
Mutagenicity / Reproductive Toxicity: Not known to be mutagenic or reproductive hazards
Target Organs: No organ-specific toxicity known
Other Information: No additional known adverse health effects at occupational levels
Aquatic Toxicity: Low; main components show limited toxicity to fish and invertebrates
Persistence/Degradability: Components degrade slowly under natural conditions
Bioaccumulative Potential: Expected to have low potential for bioaccumulation based on water solubility and molecular structure
Soil Mobility: Not readily mobile, binds to soil components
Other Adverse Effects: High dust release to surface water may cause localized issues, but not persistent hazards
Waste Disposal Methods: Gather up product and send for industrial landfill or incineration according to local regulations
Container Disposal: Triple rinse, then recycle or dispose of according to applicable environmental standards
Special Precautions: Avoid disposal to drains or surface water, keep separate from municipal waste streams if possible
Reuse and Recycling: Reuse uncontaminated material if practical within plant SOPs
UN Number: Not assigned
Proper Shipping Name: Flame Retardant Additive
Hazard Class: Not regulated as dangerous goods
Packing Group: Not applicable
Transport Labels: No specific transport hazard label required
Environmental Hazards: Avoid release of bulk powder during loading/unloading operations
Special Transport Precautions: Keep containers tightly sealed, protect against rain and strong heat during transit
US TSCA: All components listed or exempted
EU REACH: Pre-registered and/or listed under REACH
OSHA: Product not classified as hazardous under 29 CFR 1910.1200
California Prop 65: Does not contain chemicals known to the State of California to cause cancer or reproductive toxicity
Other Regulations: RoHS compliant, not restricted for use in EU, US, or Canada; check with local authorities for region-specific rules
SARA Title III: Not a listed Extremely Hazardous Substance, no Section 313 components at reportable levels
Labeling: General workplace safety labeling, with dust warning and PPE reminder
