Product Name: Epoxy Halogen Free Flame Retardant Mflam EC-20
Synonyms: Mflam EC-20 Flame Retardant, Halogen-Free Epoxy Additive
Manufacturer: Mflam Chemical Group
Address: 999 Industry Road, Innovation City, State/Province, Postal Code, Country
Emergency Phone: +1-800-555-0000
Recommended Use: Used as a flame retardant for epoxy resin systems in electronics, coatings, adhesives
Restrictions: Industrial and professional use only – not for consumer use
Supplier Email: info@mflamchem.com
GHS Classification: Eye Irritation (Category 2), Skin Sensitization (Category 1), Specific Target Organ Toxicity – Single Exposure (Category 3)
Label Elements:
- Pictograms: Exclamation Mark
- Signal Word: Warning
Hazard Statements: Causes eye irritation, may cause skin sensitization, may cause respiratory irritation
Precautionary Statements: Avoid inhalation of dust, wear protective gloves and eyewear, wash hands thoroughly after handling
Other Hazards: Combustible dust may form in confined areas; avoid dust accumulation
Health Effects: Irritates eyes, may cause skin redness or allergic response, may cause temporary breathing discomfort when airborne
Chemical Composition:
- Ammonium Polyphosphate: 45–60%, CAS No. 68333-79-9
- Melamine Derivative: 20–35%, CAS No. 108-78-1
- Epoxy-Compatible Additive Blend (Proprietary): 10–25%
- Inert Fillers: 5–10%, various CAS numbers
Impurities: Trace amounts of residual monomers and processing aids below regulatory thresholds
Additive Disclosure: Contains no intentionally added halogens or heavy metals as per RoHS guidance
Inhalation: Move to fresh air, keep comfortable for breathing, seek medical attention if symptoms persist such as coughing or dizziness
Skin Contact: Immediately wash with plenty of water and mild soap, remove contaminated clothing, consult physician for persistent irritation
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses, continue rinsing, get medical advice if discomfort continues
Ingestion: Rinse mouth, do not induce vomiting, seek advice from medical personnel
Advice for Doctors: Treat symptomatically, monitor sensitization reactions; no specific antidote known
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Media: Avoid direct water jet, may spread powder
Hazards from Product: May release irritating phosphorous oxides, nitrogen oxides, ammonia fumes during combustion
Protective Equipment: Use self-contained breathing apparatus, chemical-resistant clothing
Firefighting Procedures: Remove containers from danger zone if safe, prevent run-off into drains
Combustion Risk: Material itself is flame retardant, but exposure to fire can cause decomposition products harmful to health
Personal Precautions: Wear respirator if dust forms, protective gloves and goggles
Environmental Precautions: Prevent further leakage or spillage if safe to do so, block entry into waterways and drains
Containment: Collect spilled solid with non-combustible absorbent (sand, earth), scoop into sealed container
Cleanup: Vacuum or wet-brush to minimize dust, after collection clean area with water and mild detergent
Disposal: Transfer waste to licensed disposal facility according to local regulations
Precautions for Safe Handling: Handle in well-ventilated areas, avoid generation of airborne dust, keep away from incompatible substances such as strong acids
Hygiene Measures: Do not eat, drink or smoke when handling, wash hands thoroughly after work
Technical Measures: Use local exhaust or general ventilation, ground all handling equipment to avoid static
Safe Storage Conditions: Store in tightly sealed containers, keep in a dry, cool, shaded area away from moisture and sources of ignition
Packaging Materials: Use original container, avoid metal containers not resistant to corrosion
Storage Limits: Keep away from food, feed, and incompatible chemicals such as oxidizers
Exposure Limits: No established occupational exposure limits for main components; control airborne dust to below 5 mg/m³ (inhalable particles)
Engineering Controls: Use process enclosures, local exhaust, or general dilution ventilation
Personal Protective Equipment
- Eye/Face: Chemical safety goggles
- Skin: Impervious gloves, long-sleeved clothing
- Respiratory: Approved dust respirator when airborne particles are present
- Environmental: Prevent dust release to environment; use HEPA filters when cleaning up
Appearance: White to off-white powder
Odor: Mild ammonia-like smell
Odor Threshold: Not established
pH: 6.5–7.5 (10% slurry in water)
Melting Point: Decomposes above 250°C
Boiling Point: Not applicable
Flash Point: Not flammable as a solid
Evaporation Rate: Non-volatile
Flammability: Not classified as flammable; it functions as a flame retardant
Vapor Pressure: Not volatile
Relative Density: 1.3–1.5 (water = 1)
Solubility: Partly soluble in water, dispersible
Partition Coefficient (n-octanol/water): Not available
Auto-Ignition Temperature: Not self-igniting
Decomposition Temperature: Begins decomposing above 250°C
Viscosity: Not applicable (solid powder)
Particle Size: 5-20 micron typical range
Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: Nonreactive with most materials under normal conditions
Potentially Hazardous Reactions: Reacts with strong acids, releases ammonia, decomposes at high temperatures emitting irritant fumes
Conditions to Avoid: Moisture, very high temperatures, exposure to flame
Incompatible Materials: Strong acids, oxidizing agents, isocyanates
Hazardous Decomposition Products: Ammonia, nitrogen oxides, phosphorous oxides on strong heating or fire
Polymerization: Product will not undergo hazardous polymerization
Acute Toxicity – Oral: LD50 (rat) > 2000 mg/kg, low acute toxicity
Acute Toxicity – Dermal: LD50 (rabbit) > 2000 mg/kg, not classified as hazardous
Acute Toxicity – Inhalation: No significant acute inhalation hazard; may cause mild irritation at high airborne concentrations
Skin Corrosion/Irritation: May cause mild skin irritation and rare allergic reactions
Eye Damage/Irritation: Causes moderate irritation with redness and discomfort
Respiratory Sensitization: Dust may trigger mild, reversible respiratory effects in sensitive individuals
Chronic Effects: Prolonged or repeated exposure may cause dermatitis or mild respiratory symptoms
Mutagenicity/Carcinogenicity: No evidence from animal studies or manufacturer’s data of carcinogenic or mutagenic activity
Other Effects: No evidence of reproductive toxicity as per available data
Ecotoxicity: Not classified as acutely hazardous to aquatic life; ammonium polyphosphate is practically non-toxic to fish (LC50 >100 mg/L)
Persistence and Degradability: Inorganic components show persistence, organic fractions may slowly biodegrade
Bioaccumulation Potential: Low potential for bioaccumulation
Mobility in Soil: Phosphates and melamine derivatives may leach in sandy soil conditions
Other Adverse Effects: High concentrations near water bodies may cause algal blooms due to phosphate content
Eco-Precautions: Prevent bulk quantities from entering soil, surface water, storm drains
Waste Treatment Methods: Handle as non-hazardous industrial waste unless contaminated with hazardous substances
Disposal of Product: Take to authorized solid waste landfill, comply with local, regional, and national environmental regulations
Container Disposal: Triple-rinse containers, puncture and dispose in accordance with local requirements
Disposal Cautions: Do not discharge to sewers or watercourses, minimize dust during disposal
Recycling: Containers may be recycled if thoroughly cleaned and residue-free
UN Number: Not regulated as dangerous goods by UN, IMO, IATA, or ADR/RID
Proper Shipping Name: Not restricted
Transport Hazard Class: Not assigned
Packing Group: Not classified
Environmental Hazards: No
Special Precautions: Protect packaging from moisture and mechanical damage during shipping, ensure proper labeling for industrial products
Transport in Bulk: Not intended for bulk transport under MARPOL or IBC Code
International Inventories: Components listed on TSCA (US), EINECS/ELINCS (EU), AICS (Australia), DSL (Canada), ENCS (Japan), and other major chemical inventories
OSHA Classification: Non-hazardous under OSHA Hazard Communication Standard 29 CFR 1910.1200
SARA Title III: Not subject to reporting requirements
RoHS Compliance: Complies with EU Directive 2011/65/EU (RoHS 2) for restricted substances
REACH Status: Components registered or exempt from registration under REACH regulations
Other Regulatory Advice: Meets restrictions for halogen content as required by many electronics and plastics standards
Product Labeling: Industrial use only; all applicable hazard and safety information present on label
