MSDS Records: Fire Retardant Chemicals for Fabrics

Ammonium Polyphosphate

Identification: Ammonium polyphosphate; CAS No. 68333-79-9; dry granular or powder; chemical formula (NH4PO3)n
Hazard Identification: May cause minor skin and eye irritation; avoids chronic risks; no known carcinogenic effects
Composition / Information on Ingredients: Above 95% ammonium polyphosphate; trace water; trace pH stabilizers
First Aid Measures: Flush eyes with water; wash skin with soap; remove to fresh air if dust is inhaled; seek medical advice for persistent discomfort
Fire-Fighting Measures: Does not burn; use water spray, dry chemical, or carbon dioxide for adjacent fires; firefighters use respirators
Accidental Release Measures: Sweep up, avoid dust; ventilate; avoid discharge into sewer; wear protective mask
Handling and Storage: Keep container closed; store in cool, dry, well-ventilated area; avoid contact with acids
Exposure Controls and Personal Protection: Wear dust mask, goggles; chemical-resistant gloves; local ventilation recommended
Physical and Chemical Properties: White granular; odorless; solubility in water less than 1%; decomposes above 240°C
Stability and Reactivity: Stable under normal conditions; avoid acids and high heat; no hazardous polymerization
Toxicological Information: Oral LD50 (rat) above 5000 mg/kg; low acute toxicity
Ecological Information: Breaks down to phosphate and ammonia; low aquatic toxicity; not persistent
Disposal Considerations: Dispose in accordance with local regulations; landfill permitted
Transport Information: Non-hazardous for transportation; standard labeling required
Regulatory Information: Not regulated; listed on TSCA; no SARA or CERCLA requirements

Borax (Sodium Tetraborate)

Identification: Borax; CAS No. 1303-96-4; white crystalline powder; Na2B4O7·10H2O
Hazard Identification: Eye and skin irritant; inhalation may cause respiratory discomfort; ingestion causes nausea
Composition / Information on Ingredients: Minimum 99% sodium tetraborate decahydrate; trace sodium carbonate or sulfate
First Aid Measures: Flush eyes with water; wash skin for irritation; remove person if overheating; seek medical help for ingestion
Fire-Fighting Measures: Non-flammable; use water spray if necessary; heat may release hazardous fumes
Accidental Release Measures: Clean up with shovel; prevent dust formation; ventilate area; use PPE
Handling and Storage: Store in dry location; keep sealed to prevent clumping; avoid moisture
Exposure Controls and Personal Protection: Use gloves, goggles, dust mask; wash hands after handling
Physical and Chemical Properties: White or colorless; odorless; soluble in water; melting point 743°C
Stability and Reactivity: Stable under normal use; reacts with strong acids; avoid contact with aluminum in moist air
Toxicological Information: Oral LD50 (rat) 2660 mg/kg; may affect fertility if overexposed
Ecological Information: Moderately toxic to plants in high concentrations; rapid environmental dilution possible
Disposal Considerations: Collect and dispose as non-hazardous waste; observe local requirements
Transport Information: Not regulated for road, rail, or sea transportation
Regulatory Information: TSCA listed; subject to California Prop 65 due to developmental concerns

Decabromodiphenyl Ether (DecaBDE)

Identification: DecaBDE; CAS No. 1163-19-5; fine white powder; C12Br10O
Hazard Identification: Causes skin and respiratory irritation; classified as potentially carcinogenic; environmental concerns
Composition / Information on Ingredients: 97-98% decaBDE; up to 1.5% impurities including lower bromodiphenyl ethers
First Aid Measures: Wash exposed skin thoroughly; flush eyes with lots of water; if inhaled, move to fresh air; medical attention if symptoms persist
Fire-Fighting Measures: Material itself does not ignite easily but may release toxic fumes if involved in fire; use dry chemical, CO2, foam; self-contained breathing apparatus
Accidental Release Measures: Minimize dust; clean with wet methods or vacuum with HEPA filter; proper PPE essential
Handling and Storage: Store in closed containers; limit dust generation; avoid contact with strong oxidizers; ventilate
Exposure Controls and Personal Protection: Respirator protection; gloves; full-cover goggles; long sleeves
Physical and Chemical Properties: Odorless white powder; insoluble in water; decomposes above 300°C
Stability and Reactivity: Chemically stable at room temp; avoid prolonged heat; incompatible with strong oxidizers
Toxicological Information: LD50 (rat) above 10,000 mg/kg; suspected developmental toxin
Ecological Information: Persistent, bioaccumulative; extremely hazardous to aquatic environments
Disposal Considerations: Incinerate in approved facility; do not landfill or release to water
Transport Information: Not regulated; package to prevent dust
Regulatory Information: RoHS and REACH restrictions in EU; TSCA and US EPA regulated substance

Diammonium Phosphate (DAP)

Identification: Diammonium phosphate; CAS No. 7783-28-0; white granules; (NH4)2HPO4
Hazard Identification: Mild eye and respiratory irritant; ingestion leads to nausea or vomiting
Composition / Information on Ingredients: 99% diammonium phosphate; moisture less than 1%
First Aid Measures: Rinse eyes; wash skin; move patient to well-ventilated area for breathing issues
Fire-Fighting Measures: Non-flammable; use extinguishing media for fires in vicinity; thermal decomposition may produce toxic gases
Accidental Release Measures: Shovel and sweep into containers; avoid dust inhalation; ventilate
Handling and Storage: Store dry, cool; keep containers closed; protect from moisture
Exposure Controls and Personal Protection: Use dust mask, gloves, goggles; provide eye washes
Physical and Chemical Properties: Crystalline; odorless; soluble in water; decomposes at 155°C
Stability and Reactivity: Stable under normal handling; avoid mixing with alkaline chemicals
Toxicological Information: Low toxicity; oral LD50 (rat) 6480 mg/kg
Ecological Information: Nutrient for plants; excess can cause eutrophication of water
Disposal Considerations: Landfill in accordance with regulations; do not release large quantities to waterways
Transport Information: Non-hazardous; general transport precautions
Regulatory Information: Complies with OSHA standards; on TSCA inventory

Tetrakis (Hydroxymethyl) Phosphonium Chloride (THPC)

Identification: THPC; CAS No. 124-64-1; clear to pale yellow liquid; C4H12ClO4P
Hazard Identification: Toxic by ingestion, inhalation; skin corrosion; causes severe eye burns
Composition / Information on Ingredients: 80% THPC; water; hydrochloric acid traces
First Aid Measures: Immediate removal from exposure; flush skin and eyes; seek urgent medical help
Fire-Fighting Measures: Not flammable but can emit corrosive hydrogen chloride on burning; use foam, CO2, dry powder
Accidental Release Measures: Contain spillage; neutralize with suitable agent; ventilate area
Handling and Storage: Avoid contact with skin and eyes; store in polyethylene drums; cool, dry, ventilated
Exposure Controls and Personal Protection: Wear chemical suit, gloves, goggles, face shield; fume hood for handling
Physical and Chemical Properties: Colorless, water-soluble liquid; slightly pungent; pH strongly acidic
Stability and Reactivity: Reacts with strong bases, oxidizing agents; keep out of sunlight and heat
Toxicological Information: Oral LD50 242 mg/kg (rat); corrosive; causes burns and systemic effects
Ecological Information: Toxic to aquatic life; decomposes to orthophosphate and formaldehyde
Disposal Considerations: Neutralize; dispose as hazardous waste; comply with local regulation
Transport Information: UN 2922; Class 8 (corrosive); hazardous shipping document needed
Regulatory Information: Regulated under TSCA, OSHA, EU REACH; SARA Title III reporting

Melamine Cyanurate

Identification: Melamine cyanurate; CAS No. 37640-57-6; white powder; blend of melamine and cyanuric acid in 1:1 ratio
Hazard Identification: Mild skin, eye, respiratory irritation; no proven carcinogenicity
Composition / Information on Ingredients: Over 98% melamine cyanurate; remaining balance water and inert dust
First Aid Measures: Wash eyes and skin thoroughly; seek fresh air for breathing; medical help for extensive exposure
Fire-Fighting Measures: Non-flammable; use water, foam, CO2 as needed
Accidental Release Measures: Avoid dust; sweep plus vacuum; prevent drainage to water sources
Handling and Storage: Store sealed, cool, dry; avoid moisture absorption
Exposure Controls and Personal Protection: Protective gloves, goggles, NIOSH-approved mask for dust
Physical and Chemical Properties: White, non-odorous powder; insoluble in water; stable up to 300°C
Stability and Reactivity: Stable at ambient temperatures; avoid acids and bases
Toxicological Information: Low oral toxicity (rat LD50 >10,000 mg/kg); not mutagenic
Ecological Information: Low bioaccumulation; degrades slowly in environment
Disposal Considerations: Approved landfill disposal; follow environmental laws
Transport Information: Not classified as dangerous
Regulatory Information: Listed by TSCA; REACH registered substance