Product Name: Fire Retardant Polyethylene (PE) Masterbatch
Code: FR-PE-MB
Recommended Use: Production of plastic goods, cable sheathing, films, injection-molded items where resistance to fire is crucial
Supplier: Additive Polymers Pvt Ltd, 475 Industrial Lane, Export Zone, City, ST 00500
Emergency Contact: +1-800-555-1200
Classification: Not classified as a hazardous substance under OSHA regulations, though dust generation may irritate respiratory passages
Primary Hazards: Melting or burning releases fumes that can irritate eyes, throat, and lungs
Label Elements: Caution labeling for dust and thermal processing, advice on confined spaces, pictogram for respiratory protection
Other Hazards: Pellets could present a slip hazard on floors
Chemical Nature: Polyethylene resin blended with fire retardant additives
Major Components: Polyethylene resin (CAS 9002-88-4: 60-90%)
Fire Retardant Additives: Ammonium polyphosphate (CAS 68333-79-9: 10-30%), Aluminum hydroxide (CAS 21645-51-2: 5-15%), Proprietary synergists (<5%)
Other Additives: Dispersing agents, processing aids, colorants as needed, all non-hazardous under normal use
Inhalation: Move exposed person to fresh air, keep at rest, seek medical attention if coughing or breathing difficulty develops
Skin Contact: Wash with mild soap and water, if molten material contacts skin, cool rapidly with water without removing material, get medical help for burns
Eye Contact: Flush with plenty of clean water for a minimum of 15 minutes; seek medical attention for persistent irritation
Ingestion: Rinse mouth; get medical advice if large quantities swallowed or discomfort persists
Extinguishing Media: Dry chemical, foam, water spray (do not aim strong stream directly as it may spread fire), carbon dioxide
Hazards During Fire: Fumes contain carbon monoxide, carbon dioxide, and irritating gases; dense black smoke can form
Protective Equipment: Full-face self-contained breathing apparatus, chemical-resistant suit, avoid skin and eye contact with runoff
Specific Advice: Cool fire-exposed containers with water spray, prevent fire water from entering waterways
Personal Precautions: Isolate spill area, avoid dust generation, wear gloves and a dust mask if cleanup is needed
Environmental Precautions: Block entry to sewers or water bodies, collect pellets immediately to prevent wildlife ingestion
Methods for Clean-up: Collect by sweeping or vacuuming, place in suitable containers for recycling or disposal, wash spill area to remove residue
Handling: Keep bags closed, use mechanical ventilation where pellets are handled, avoid breathing dust or contact with hot melt
Storage: Store in dry, cool, well-ventilated space, away from direct sunlight, ignition sources, strong acids or oxidizing chemicals
Specific Storage Needs: Stack pallets securely, avoid stacking too high to prevent falling, keep away from extreme heat
Engineering Controls: Local exhaust ventilation at workstations, process enclosures, dust collection systems
Respiratory Protection: Dust mask during manual handling, NIOSH-approved respirator during thermal processing if ventilation is poor
Skin Protection: Protective gloves, long-sleeve work clothing, impervious apron if repeated contact is likely
Eye Protection: Safety goggles, face shield for large-scale or hot work
Workplace Hygiene: Wash hands and face after handling, do not eat or drink in work areas, remove contaminated clothing before breaks
Form: Opaque plastic granules or pellets
Color: White to off-white, sometimes colored depending on formulation
Odor: None at room temperature; slight odor during thermal processing
Melting Point: 110°C – 140°C (polyethylene base)
Density: 1.1 – 1.5 g/cm³ depending on additive load
Solubility: Not soluble in water
Flash Point: >350°C
Other: Stable under recommended storage, not volatile
Chemical Stability: Stable under standard conditions, no dangerous reactions with air or water
Reactivity: Strong acids, oxidizers may cause degradation, avoid unnecessary thermal stress
Hazardous Decomposition: Thermal decomposition yields fumes, including carbon monoxide, carbon dioxide, irritating phosphorous compounds
Incompatible Materials: Acids, oxidizers, strong alkalis, reducing agents
Acute Toxicity: Not acutely toxic under normal exposure, dust or fumes may irritate respiratory tract
Skin/Eye Effects: Prolonged contact with dust or hot material can cause redness, pain, or burns
Chronic Effects: No known chronic health hazards from regular properly-used exposure, fire retardant components widely studied, not carcinogenic at levels used in masterbatch
Other Health Data: No sensitization or mutagenic effects observed in normal use scenarios
Ecotoxicity: Pellets pose choking risk to aquatic and terrestrial animals if released to the environment, fire retardants may harm aquatic species at high concentrations
Persistence: Polyethylene is slow to degrade, can persist in land and water for years
Bioaccumulation: No significant bioaccumulation expected for polymer or main additives
Other Environmental Concerns: Large-scale spills in water bodies should be avoided, proper collection is essential to safeguard wildlife
Waste Disposal: Recycle if possible through properly licensed facilities, landfill in accordance with local guidelines, do not incinerate unless facility is equipped to scrub fire retardant emissions
Container Disposal: Triple-rinse, puncture, and manage according to applicable waste rules, avoid reuse for non-industrial purposes
Special Precautions: Prevent dust and pellet escape during transfer and disposal, store waste in closed containers
UN Number: Not regulated for transport
Transportation Type: Non-hazardous goods, no special DOT/ADR/IMDG requirements
Precautions: Avoid wetting during shipment, secure packaging to stop spillage
Label Needs: Standard product identification, emergency contact details, dust warning
Safety Standards: OSHA-compliant for industrial use, not subject to SARA Title III, not regulated as hazardous waste under RCRA
Labeling: Product label gives warnings for fire risk and first-aid, includes hazard pictograms if dust hazard
Country Regulations: Meets requirements in EU (REACH), China, and North America for use as manufactured resin
Other Regulatory Notes: Fire retardant additives listed on TSCA, not on California Proposition 65 regimen, no ODS use
