Product Name: CGN Flame Retardant
Chemical Family: Phosphorus and Nitrogen-based flame retardant
Recommended Use: Industrial fire resistance treatment for textiles, plastics, and building materials
Manufacturer: CGN Chemical Industries, 28 Riverside Park, Indiana, USA
Contact Number: 1-800-400-6588
Emergency Telephone: CHEMTREC 1-800-424-9300
Email: info@cgnchem.com
Synonyms: CN-Guard, CGN Fire Blocker
Product Code: CGN-115F
Date of Last Revision: June 2024
Classification: Acute toxicity (Oral, Category 5), Skin irritation (Category 2), Serious eye irritation (Category 2A)
GHS Label Elements: Warning, Exclamation mark
Hazard Statements: May cause skin and eye irritation. Harmful if swallowed. Prolonged exposure causes itching and rashes.
Precautionary Statements: Avoid inhalation. Avoid contact with skin and eyes. Washing thoroughly after handling reduces irritation.
Routes of Exposure: Skin, ingestion, inhalation.
Pictograms: Exclamation mark for irritation hazard.
Signal Word: Warning
Component 1: Ammonium polyphosphate (CAS# 68333-79-9) — 55%
Component 2: Melamine (CAS# 108-78-1) — 30%
Component 3: Pentaerythritol (CAS# 115-77-5) — 10%
Component 4: Inert mineral filler — 4%
Component 5: Surface conditioner (trade secret) — 1%
Impurities: Trace moisture, below 0.5%
Eye Contact: Rinse eyes gently with water for 15 minutes. Lift eyelids occasionally. Seek medical attention for persistent discomfort.
Skin Contact: Wash skin with water and mild soap. Take off contaminated clothing. Use soothing lotion if irritation develops.
Inhalation: Move person to fresh air. Rest in a comfortable position. Seek medical advice if coughing, wheezing, or shortness of breath occurs.
Ingestion: Wash mouth with water. Do not induce vomiting. Drink water to dilute the effect. Contact a doctor if unwell.
Note to Physician: Treat symptomatically. Show this safety data sheet to medical personnel.
Suitable Extinguishing Media: Water spray, dry chemical powder, carbon dioxide, foam.
Unsuitable Extinguishing Media: High-pressure water jet may disperse material.
Specific Hazards: Heating releases ammonia, nitrogen oxides, phosphoric acid vapors. Powder may form irritating fumes above 250°C.
Protective Equipment: Wear self-contained breathing apparatus, full protective gear.
Hazardous Combustion Products: Ammonia, phosphorus oxides, carbon monoxide, formaldehyde at very high temperatures.
Advice for Firefighters: Cool containers exposed to flames with mist. Get clear of toxic vapors. Standing upwind is recommended.
Personal Precautions: Isolate area. Ventilate space. Wear gloves, goggles, particle filter mask.
Environmental Precautions: Avoid spillage into sewers, soil, waterways. Dike area for large leaks.
Spill Cleanup: Scoop up product mechanically. Use dust suppressing methods — light mist, wet rag, or vacuum with HEPA filter.
Waste Disposal: Collect spill in containers for authorized landfill disposal. Avoid raising dust.
Decontamination: Wash contaminated surfaces with water and detergent to reduce slippery residue.
Handling: Wear protective gloves, safety glasses, and dust mask. Clean up dust promptly. Avoid breathing airborne powder. Wash hands and face before eating or drinking. Handle in a well-ventilated area.
Storage: Keep in tightly closed original containers. Store in cool, dry, and well-ventilated locations, away from food, feed, and strong acids or bases. Temperature recommended: 5–35°C. Protect from moisture.
Incompatibilities: Store away from oxidizers and strong alkalis to prevent chemical reaction.
Regulations: Do not keep near open flame, heat sources, or direct sunlight. Use secondary containment to prevent accidental loss.
Occupational Exposure Limits: No OSHA PEL for components. ACGIH TLV for nuisance dust: 10 mg/m³ (total), 3 mg/m³ (respirable).
Engineering Controls: Local exhaust recommended for bulk handling. General room ventilation minimizes airborne exposure.
Personal Protective Equipment: Chemical-resistant gloves, safety glasses with side shields, long-sleeve clothing. Use a dust mask (NIOSH N95 or better) in areas of heavy dust.
Hygiene Measures: Wash after handling. No eating, drinking, or smoking in work areas.
Environmental Controls: Collect any residue from processes or spills for proper disposal.
Appearance: Off-white fine powder
Odor: Slight chemical scent
Odor Threshold: Below detection
pH (1% in water): 6.2–7.0
Melting Point/Freezing Point: 190–200°C (decomposes)
Boiling Point: Not applicable (decomposes before boiling)
Flash Point: Not flammable
Evaporation Rate: Negligible
Flammability: Material does not ignite
Vapor Pressure: Not volatile
Vapor Density: Not applicable
Relative Density: 1.7–2.2 g/cm³
Solubility: Moderately soluble in water
Partition Coefficient: Not determined
Auto-ignition Temperature: Above 300°C
Decomposition Temperature: 220°C
Viscosity: Not applicable
Particle Size: 20–80 microns typical
Bulk Density: 0.55–0.65 g/cm³
Chemical Stability: Stable under normal handling and storage. No hazardous polymerization.
Reactvity: Will react with strong acids, alkalis, and oxidants.
Hazardous Reactions: Slow breakdown produces ammonia and phosphoric acids.
Conditions to Avoid: Prolonged moisture, excessive heat, strong sunlight.
Incompatible Materials: Strong acids, alkalis, oxidizers.
Hazardous Decomposition Products: Heating liberates toxic gases — ammonia, nitrogen oxides, phosphorus compounds.
Acute Toxicity: Oral LD50 (rat): > 2500 mg/kg
Skin Corrosion/Irritation: Moderate irritation on repeated contact
Serious Eye Damage/Irritation: Causes redness and watering
Respiratory Sensitization: Inhalation dust may trigger asthma-like symptoms in sensitive persons
Germ Cell Mutagenicity: No evidence from animal studies
Carcinogenicity: Not listed by IARC, NTP, OSHA as carcinogen
Reproductive Toxicity: No data for reproductive or developmental toxicity
STOT-Single Exposure: High dust levels cause coughing or sore throat
STOT-Repeated Exposure: Prolonged skin contact dries and cracks skin
Aspiration Hazard: Powder form unlikely to cause aspiration
Toxicity to Aquatic Life: Harmful in large quantities, especially for fish and invertebrates
Persistence and Degradability: Slowly degrades in soil and water
Bioaccumulative Potential: Components show low bioaccumulative potential in aquatic species
Mobility in Soil: Transported short distances through run-off
Other Adverse Effects: Phosphates may encourage algal blooms in waterways
Monitoring: Regular local water testing recommended after significant spills
Waste Treatment Methods: Landfill disposal in accordance with local and federal regulations. Approved industrial incineration for large volumes.
Container Handling: Triple rinse empty containers before recycling or disposal.
Special Precautions: Do not wash residues into drains or open waterways.
Disposal Code: Non-hazardous for transport but must avoid uncontrolled dumping.
UN Number: Not regulated under UN transport
Proper Shipping Name: Not classified as hazardous
Transport Hazard Class: Non-dangerous goods (no label required)
Packing Group: Not assigned
Marine Pollutant: Not listed as marine pollutant
Special Precautions: Keep containers sealed, do not stack above three layers. Secure to prevent movement.
Transport in Bulk: Avoid exposure to rain or high humidity during transport
Label Requirements: Product requires warning label for eye and skin irritation risk.
TSCA Status: Components listed on US TSCA inventory
SARA Title III: No ingredients subject to Section 313 reporting
California Proposition 65: Product does not contain chemicals subject to warning
Canada WHMIS Classification: Not controlled
REACH Status: Components registered under EU REACH
Other Regulations: Handle as non-hazardous, observe worker safety guidelines, provide regular risk training.
