Product Name: Flame Retardant Additive for Polyether TPU
Manufacturer: SafeChem Advanced Materials Co., Ltd.
Product Code: PEFR-TPU-2024
Recommended Use: Flame retardant additive for polyether-based thermoplastic polyurethanes used in cable insulation, films, and molded goods.
Supplier Contact: 123 Tech Drive, Industrial Park Zone B, Citysville, State/Province 10001, Country
Emergency Number: +1-800-555-9090 (24/7 service), support@safechemmat.com
GHS Classification: Skin Irritant (Category 2), Eye Irritation (Category 2), Specific Target Organ Toxicity (Single exposure) (Category 3), Acute Aquatic Toxicity (Category 2)
Signal Word: Warning
Hazard Pictograms: Exclamation Mark, Environment
Hazard Statements: Causes skin irritation, Causes serious eye irritation, May cause respiratory irritation, Toxic to aquatic life
Precautionary Statements: Avoid breathing dust/fume, Wear protective gloves/eye protection, Wash hands thoroughly after handling, Use only outdoors or in well-ventilated area, Dispose of contents/container in accordance with local/regional regulations
Main Components: Organic phosphorus compound (e.g., Bisphenol A bis(diphenyl phosphate), CAS No. 5945-33-5),
Content: 70-85%
Synergist: Melamine Polyphosphate, CAS No. 218768-87-1, 10-15%
Other Additives: Antioxidant (proprietary, 0.5-2%)
Impurities: None expected above reportable thresholds
Substances of High Concern: Does not contain SVHC under REACH Annex XIV
Inhalation: Remove person to fresh air. Get medical attention if symptoms occur like coughing or shortness of breath. Rest and monitor breathing.
Skin Contact: Remove contaminated clothing. Wash skin with plenty of soap and water. Seek medical advice if irritation persists. Clean shoes and clothes before reuse.
Eye Contact: Rinse well under running water for at least 15 minutes. Remove contact lenses if present and easy to do. Continue rinsing and seek medical attention if discomfort remains.
Ingestion: Rinse mouth thoroughly. Do not induce vomiting unless directed by qualified personnel. Drink water if conscious. Get medical help for any symptoms.
Most Important Symptoms: Redness, irritation, burning sensation in eyes or skin, coughing, difficulty breathing
Suitable Extinguishing Media: Water spray, dry chemical, carbon dioxide, foam
Unsuitable Media: Do not use strong water jets as they may spread burning material
Specific Hazards: Incomplete burning releases toxic fumes—phosphorus oxides, nitrogen oxides, carbon monoxide
Firefighter Advice: Wear self-contained breathing apparatus and full protective clothing
Special Procedures: Move containers from fire area if it can be done without risk. Use water to keep drums cool. Avoid breathing combustion products.
Personal Protection: Wear gloves, goggles, and dust mask. Prevent skin and eye contact. Remove ignition sources.
Environmental Precautions: Stop spill from entering drains, soil, rivers, or sewers. Use barriers and cover storm drains.
Spill Cleanup: Collect spilled solid with an industrial vacuum or sweeping compound. Use a shovel or broom for large material, place in closed container for disposal.
Decontamination: Wash spill area with water and detergent. Clean tools with soapy water after use.
Safe Handling: Minimize dust generation. Use only in well-ventilated areas. Wear appropriate protection. Do not eat or drink near product.
Storage Requirements: Store in tightly sealed original container, preferably in a dry, cool, and well-ventilated place (10-35°C). Avoid high humidity and direct sunlight. Keep away from food or feed.
Incompatibilities: Oxidizers, acids, strong bases
Storage Stability: Product remains stable under recommended storage for at least 12 months.
Engineering Controls: Local exhaust ventilation or dust extraction recommended for bulk transfer and mixing areas.
Occupational Exposure Limit: No specific OEL set for ingredients; avoid inhaling fine particulate.
Personal Protection: Use gloves (nitrile or PVC recommended), chemical goggles or face shield, disposable dust mask or respirator (P2 or N95), protective work clothing
Hygiene Measures: Wash hands and face after handling. Remove contaminated clothes promptly. Prohibit eating, smoking, or drinking at workstations.
Appearance: Off-white fine powder
Odor: Mild, slightly phenolic
Melting Point: 180-210°C
Decomposition Temperature: >290°C
pH (1% suspension in water): 6.2-7.5
Bulk Density: 0.45-0.65 g/cm3
Solubility: Insoluble in water; soluble in some organics
Volatile Content: <0.1%
Chemical Stability: Stable under normal conditions and usage temperatures
Reactivity: Avoid mixing with strong oxidizers and strong acids
Thermal Decomposition: Releases irritating or toxic gases like phosphorus oxides if overheated
Hazardous Polymerization: Not expected under normal processing
Incompatibles: Hydrochloric acid, nitric acid, strong bases
Acute Toxicity: Oral LD50 (rat) >2000 mg/kg; low acute oral toxicity
Skin Corrosion/Irritation: May cause redness, irritation after contact
Eye Damage/Irritation: Causes serious eye irritation on exposure
Respiratory Sensitization: Dust inhalation may cause upper respiratory tract discomfort or coughing
Chronic Effects: No evidence of carcinogenicity or mutagenicity in available data
Other Health Effects: Prolonged exposure may lead to dermatitis or respiratory irritation in sensitive individuals
Ecotoxicity: Toxic to aquatic organisms; risk of long-term harmful effects in waterways
Mobility: Not readily soluble in water; particles may settle in sediment
Persistence and Degradability: Slow biodegradation under typical environmental conditions
Bioaccumulation Potential: Low likelihood of significant bioaccumulation
Additional Notes: Prevent discharge to lakes, rivers, or soil
Product Disposal: Dispose of in accordance with local, regional, and national environmental regulations as hazardous or chemical waste
Packaging Disposal: Empty packaging should be rinsed and submitted to an approved waste handler
Contaminated Material: Treat as hazardous waste. Segregate and label clearly for disposal.
Best Practice: Incinerate in controlled facility or landfill at approved site
UN Number: Not regulated for land, air, or sea transport under UN Recommendations
Transport Hazard Class: Not classified as dangerous goods
Packing Group: Not assigned
Marine Pollutant: Product is hazardous to aquatic environment; notify carrier if >500kg per shipment
Transport Labeling: No special requirement. Suggest using "Environmentally hazardous substance" marking for bulk.
Global Inventory Status: All ingredients listed on TSCA (US), REACH (EU), AICS (Australia), ECL (South Korea), ENCS (Japan)
Labeling: Complies with GHS standard labeling
Regulatory Restrictions: Not on list of restricted or banned substances in major markets
SARA Title III: Not a listed substance under Section 302, 304, 313
RoHS/ELV Status: Meets criteria (<0.1% by weight) for lead, cadmium, mercury, hexavalent chromium
Other Regulatory Details: Not regulated as carcinogen or reproductive toxin by major agencies
