Product Name: Flame Retardant Masterbatch for XPS
Chemical Family: Flame-retardant polymer additive blend
Product Use: Additive for enhancing fire resistance in extruded polystyrene (XPS) foam
Manufacturer's Name: [Insert Manufacturer]
Supplier Address: [Insert Supplier Contact Information]
Phone: [Insert Emergency Contact Number]
Email: [Insert Technical Inquiry Email]
Hazard Classification: Not classed as hazardous under GHS; small particulate matter may irritate airways; prolonged skin contact can cause mild irritation
Label Elements: Contains flame retardant agents, handle with care
Signal Word: Warning
Hazard Statements: Avoid inhaling dust; wear gloves; keep away from heat sources
Prevention: Use with proper ventilation, do not eat or drink while handling, avoid eye contact
Response: If inhaled, move to fresh air; rinse exposure area with water
Polystyrene Carrier: Filled copolymer, 65-80%
Brominated Flame Retardant: Hexabromocyclododecane (HBCD) or alternative, 15-25%
Synergist (e.g. Antimony Trioxide): Supports flame retardancy, 3-10%
Stabilizer and Additives: Proprietary blend, <5%
CAS Numbers: 25637-99-4 (Polystyrene), 3194-55-6 (HBCD), 1309-64-4 (Antimony Trioxide)
Inhalation: Move to fresh air; seek medical attention if coughing or breathing difficulty persists
Skin Contact: Remove contaminated clothing; wash skin with soap and water
Eye Contact: Rinse eye with plenty of clean water for at least 15 minutes; see doctor if discomfort continues
Ingestion: Rinse mouth with water; do not induce vomiting; get medical attention if symptoms show
Suitable Extinguishing Media: Dry powder, foam, carbon dioxide; water spray can cool surfaces
Specific Hazards: Toxic fumes of carbon monoxide, brominated compounds, and antimony oxides if burning
Protective Equipment: Self-contained breathing apparatus, full protective gear
Firefighting Instructions: Keep containers cool by spraying with water; avoid inhaling gases; remove unburned material from area if safe to do so
Personal Precautions: Avoid generating dust; use respiratory protection if dust is present
Spill Cleanup Methods: Sweep up spills; collect in closed container for disposal; ventilate area
Environmental Precautions: Keep away from drains, waterways, and soil; inform authorities if large spills could cause pollution
Containment: Dike area with sand or earth to limit spread; prevent contact with ignition sources
Handling: Wear suitable gloves, protective clothes, and avoid direct skin and eye contact; use extraction ventilation near work areas; avoid eating, drinking, or smoking during handling
Storage: Keep containers tightly closed in dry, cool, and well-ventilated space; store away from oxidizing agents and strong acids; avoid stacking too high to prevent container collapse; keep away from food and feed products
Engineering Controls: Install local exhaust ventilation to extract dust; general mechanical ventilation recommended
Personal Protective Equipment: Respiratory mask for dusty work; impervious gloves; long sleeves; safety goggles
Threshold Limit Values: Antimony trioxide (Occupational Exposure Limit): 0.5 mg/m3 TWA (ACGIH)
Hygiene Measures: Wash hands before eating, after handling; dispose of soiled clothing; eye wash stations in working area
Appearance: White or off-white granular pellet
Odor: Odorless or faint hydrocarbon smell
pH: Not applicable
Melting Point: 90°C – 120°C
Boiling Point: Not applicable (solid blend)
Flash Point: >250°C
Vapor Pressure: Negligible
Solubility: Insoluble in water
Bulk Density: 0.85 – 1.05 g/cm³
Partition Coefficient: Not available
Chemical Stability: Stable under normal use and storage conditions
Conditions to Avoid: Extreme heat, open flame, sources of ignition
Materials to Avoid: Strong acids, strong oxidizing agents
Hazardous Decomposition Products: CO, CO₂, brominated organic vapors, antimony fumes
Polymerization: Not known to occur under specified conditions
Acute Toxicity: Low expected toxicity via oral, dermal, and inhalation routes at normal exposure levels
Skin/Eye Irritation: May cause mild irritation with prolonged contact, especially with dust exposure
Respiratory Sensitization: Fine dust may aggravate symptoms in individuals with asthma or dust allergies
Chronic Health Effects: Long-term dust inhalation linked to lung irritation and, in case of antimony exposure, possible respiratory effects
Carcinogenicity: IARC classifies antimony trioxide as possibly carcinogenic to humans (Group 2B); other components not regulated as carcinogens by OSHA
Ecotoxicity: Brominated flame retardants can persist in environment, may be toxic to aquatic organisms
Bioaccumulation: Potential for bioaccumulation in aquatic species; avoid release into waters
Persistence and Degradability: Not readily biodegradable; additives can persist in soil and sediment
Mobility in Soil: Low mobility due to solid pellet form; additive migration possible over time
Other Adverse Effects: Considered hazardous to aquatic environment if bulk material leaks or spills
Waste Disposal Methods: Collect residue and contaminated material in sealed containers; send to approved industrial waste facility
Incineration: Avoid open burning; incinerate only in facilities with proper emission controls
Recycling: Do not attempt to recycle contaminated masterbatch through standard processes
Contaminated Packaging: Treat as hazardous waste; clean if possible for recycling, or dispose of according to local regulations
Regulatory Compliance: Observe all federal, state, and municipal laws regarding disposal of chemical substances
UN Number: Not classified as hazardous for transport
Shipping Name: Polymer Additive Blend, N.O.S.
Transport Hazard Class: Non-hazardous
Packing Group: Not applicable
Environmental Hazards: Not a marine pollutant under normal conditions
Special Precautions: Protect from moisture and physical damage; secure containers to prevent movement during transit
OSHA Status: Not regulated as a hazardous substance under standard workplace rules
TSCA Status: All components listed or exempt
SARA Title III: May contain Section 313-listed antimony compounds
REACH Registration: Required for brominated and antimony components in some territories
Labeling: Chemical labeling as per local/international requirements
Other Requirements: Safety training recommended for handlers; monitor local regulations regarding flame retardant restrictions
