Material Safety Data Sheet (MSDS) List for Exolit Fyrolflex RDP Flame Retardant

Identification

Product Name: Exolit Fyrolflex RDP
Chemical Name: Resorcinol bis(diphenyl phosphate)
Manufacturer: Clariant International Ltd.
Use: Flame retardant for plastics and other applications
Contact Information: Clariant AG, Rothausstrasse 61, 4132 Muttenz, Switzerland, Tel: +41 61 469 5111
Emergency Number: CHEMTREC +1 800-424-9300 (US) / +1 703-527-3887 (International)

Hazard Identification

Classification: Eye irritation (Category 2), Aquatic chronic (Category 3)
Label Elements: Exclamation mark symbol, Warning signal word
Hazard Statements: Causes serious eye irritation, Harmful to aquatic life with long lasting effects
Precautionary Statements: Avoid release to environment, Wear protective gloves and eye protection, Wash hands thoroughly after handling, If in eyes: rinse cautiously with water for several minutes

Composition / Information on Ingredients

Main Ingredient: Resorcinol bis(diphenyl phosphate) (RDP), CAS No. 125997-21-9
Concentration: ≥ 95%
Minor Components: Proprietary additives (non-hazardous)
Impurities: Minimal, not classified as hazardous for reporting

First Aid Measures

Eye Contact: Rinse immediately with plenty of water for 15 minutes, remove contact lenses if present and easy to do, seek medical attention if irritation persists
Skin Contact: Wash with soap and water, remove contaminated clothing and shoes, get medical advice if redness or irritation develops
Inhalation: Move to fresh air, keep individual comfortable and warm, consult a physician if symptoms like coughing or difficulty breathing appear
Ingestion: Rinse mouth, do not induce vomiting, give small quantities of water, never give anything by mouth to an unconscious person, seek medical assistance

Fire-Fighting Measures

Suitable Extinguishing Media: Use foam, dry chemical powder, or carbon dioxide; do not use water if possible due to product’s tendency to spread flames on water surfaces
Specific Hazards: Formation of toxic gases like phosphorus oxides, carbon monoxide, carbon dioxide, and phenols during combustion
Special Protective Equipment: Firefighters should wear full protective gear and self-contained breathing apparatus
Instructions: Isolate area, cool surrounding containers with water spray, prevent runoff from entering drains

Accidental Release Measures

Personal Precautions: Wear suitable personal protective equipment including gloves, goggles, and resistant clothing; ensure adequate ventilation
Environmental Precautions: Prevent product from entering drains, surface water, or soil; notify authorities in case of large spills
Spill Clean-up: Collect spillage with an absorbent non-combustible material like sand, scoop up and containerize, wash contaminated area with water, dispose of according to regulations

Handling and Storage

Handling: Use with adequate ventilation, avoid breathing dust or fumes, keep containers tightly closed, avoid contact with eyes, skin, and clothing, wear appropriate protective equipment
Storage: Store in original containers in a cool, dry, and well-ventilated area, keep away from food and drink, keep out of reach of children, avoid exposure to moisture, high temperatures, and incompatible materials like oxidizers

Exposure Controls and Personal Protection

Engineering Controls: Provide general ventilation or local exhaust to minimize airborne exposure
Occupational Exposure Limits: No established occupational exposure limit values for RDP, but keep exposure as low as reasonably achievable
Personal Protection: Safety glasses with side-shields or chemical goggles, nitrile or latex gloves, long-sleeved protective clothing, and in case of insufficient ventilation, use a P2 or N95 rated mask
Hygiene: Do not eat, drink, or smoke during use, wash hands and face thoroughly after handling, remove contaminated clothing and wash before reuse

Physical and Chemical Properties

Appearance: Clear, viscous liquid
Odor: Mild aromatic
pH: Not applicable
Melting Point: < -20°C
Boiling Point: >300°C
Flash Point: >250°C (closed cup)
Density: 1.21-1.25 g/cm³ at 25°C
Solubility: Practically insoluble in water, miscible with many organic solvents
Viscosity: 260-370 mPa·s at 20°C
Vapor Pressure: Very low at 20°C

Stability and Reactivity

Chemical Stability: Stable under normal use and storage conditions
Conditions to Avoid: Heat, moisture, open flame, high energy ignition sources
Incompatible Materials: Strong oxidizing agents, strong acids, alkalis
Hazardous Decomposition Products: Phosphorus oxides, carbon oxides, phenol derivatives formed during combustion or thermal decomposition

Toxicological Information

Acute Toxicity: LD50 (oral, rat): > 5,000 mg/kg, low toxicity by ingestion
Eye Irritation: Causes moderate to severe irritation on direct contact
Skin Irritation: Mild irritation in sensitive individuals
Inhalation: Low vapor pressure means inhalation risk low under normal conditions
Long-term Exposure: No evidence for carcinogenicity or reproductive effects in available studies
Sensitization: Not expected to cause skin sensitization in standard tests

Ecological Information

Aquatic Toxicity: EC50 (daphnia): > 10 mg/L (acute), shows short-term harmful effects on aquatic organisms
Persistence and Degradability: Moderately persistent, limited biodegradability
Bioaccumulation: Potential for bioaccumulation exists due to hydrophobic nature
Mobility in Soil: Low mobility, tends to bind to soil particles and sediments
Other Adverse Effects: Avoid release to the environment, chronic aquatic impacts possible if not handled properly

Disposal Considerations

Product Disposal: Dispose of as hazardous waste according to local, state, and national regulations, incineration preferred over landfilling
Container Disposal: Rinse containers with suitable solvent and dispose of as hazardous waste, do not reuse empty containers for other purposes
Special Instructions: Do not discharge into drains, surface water, or groundwater, consult a licensed waste disposal contractor for guidance

Transport Information

UN Number: Not regulated for transport under UN, IMDG, IATA, or DOT codes
Proper Shipping Name: Not classified as hazardous for shipping
Packing Group: Not applicable
Hazard Class: None assigned
Special Precautions: Transport in closed and upright containers, keep secure to prevent leakage, comply with all local and international shipping rules

Regulatory Information

EU Regulations: Listed under REACH as a registered chemical, does not appear on SVHC list
TSCA Status (US): Listed and allowed for manufacture, import or use in the US
Other Regulations: Not listed as a carcinogen by IARC, NTP, or OSHA, not regulated as a hazardous substance under CERCLA or SARA Title III
Label Requirements: Comply with GHS labeling, Safety Data Sheets required for workplace use, observe relevant national and local chemical safety regulations