Material Safety Data Sheet for Exolit OP1230 Flame Retardant

Product Identification

Product Name: Exolit OP1230
Chemical Family: Organophosphorus Compound
Product Code: OP1230
Manufacturer: Clariant International Ltd.
Emergency Telephone: Refer to regional emergency contacts on product label
Intended Use: Flame retardant additive in polymer processing
Physical Form: White to off-white powder
Synonyms: Aluminum diethylphosphinate-based flame retardant
Recommended Restrictions: Not recommended for food, drug, or cosmetic applications
Supplier Address: Listed on packaging or official datasheets provided by manufacturer

Hazard Identification

GHS Classification: Eye irritant (Category 2A), Skin irritant (Category 2), Specific target organ toxicity - single exposure (Category 3, respiratory tract irritation)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, may cause respiratory irritation, may cause skin irritation
Pictograms: Exclamation mark
Precautionary Statements: Avoid inhaling dust, wear protective gloves and eye/face protection, handle under proper ventilation, wash thoroughly after handling
Potential Health Effects: Eye redness and discomfort, skin drying or cracking, coughing and mild respiratory discomfort on inhalation, no known chronic effects in normal industrial use

Composition / Information on Ingredients

Main Ingredient: Aluminum Diethylphosphinate
Chemical Formula: C4H10AlO4P2
CAS Number: 225789-38-8
Concentration: ≥ 95%
Other Ingredients: Minor process impurities and moisture content up to 5%
Impurities: Not regarded as hazardous based on supplier information
Stabilizers or Additives: No intentional additives present

First Aid Measures

Inhalation: Move to fresh air, support breathing if discomfort persists, seek medical attention for persistent symptoms
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, consult a physician if irritation develops
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, obtain medical attention if irritation continues
Ingestion: Rinse mouth, drink water if conscious, avoid inducing vomiting, seek medical advice based on the amount swallowed and symptoms
Most Important Symptoms: Eye discomfort, mild respiratory irritation, transient skin redness

Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry powder, carbon dioxide, water spray
Unsuitable Media: Direct water jet
Specific Hazards: Decomposes under intense heat releasing phosphorus oxides, carbon oxides, and irritating fumes
Protective Equipment: Self-contained breathing apparatus, full protective gear for firefighters
Special Firefighting Procedures: Cool exposed containers with water spray, avoid inhaling combustion gases, evacuate area if necessary
Explosion Sensitivity: Not sensitive, dust buildup in processing areas can create explosion risk if allowed to accumulate

Accidental Release Measures

Personal Precautions: Use proper personal protective equipment (respirator, goggles, gloves), avoid raising dust, ventilate area
Environmental Precautions: Prevent dispersion into drains, sewers, water bodies
Containment Methods: Collect with a suitable vacuum or moisten to minimize dust, sweep up into dedicated containers
Cleanup Methods: Wash remaining residues from floors with water, decontaminate equipment
Disposal Considerations: Dispose of collected waste as per local regulations and supplier recommendations

Handling and Storage

Handling: Avoid dust generation, handle under local exhaust ventilation, use recommended PPE, avoid contact with skin and eyes, keep work area clean
Storage Conditions: Store in tightly closed original containers, in cool, dry, and well-ventilated places, away from strong acids, bases, and oxidizers
Packaging Materials: Use original packaging or resistant bulk containers
Special Requirements: Keep out of reach of children and unauthorized personnel
Storage Stability: Stable under standard warehouse conditions, protect from humidity and direct sunlight

Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits assigned for Exolit OP1230, observe dust exposure thresholds (inhalable dust OSHA PEL: 15 mg/m3, respirable dust OSHA PEL: 5 mg/m3)
Engineering Controls: Local exhaust ventilation preferred, use only in well-ventilated areas
Personal Protective Equipment: Safety goggles or face shield, chemical-resistant gloves (nitrile or PVC), long-sleeved clothing, dust mask or respirator (P2 or N95), safety shoes
Hygiene Measures: Wash hands after handling, do not eat, drink, or smoke in work area, remove contaminated clothing before entering common areas

Physical and Chemical Properties

Appearance: White to off-white fine powder
Odor: Low, faint chemical smell
Odor Threshold: Not determined
pH: 5–8 (10g/L water)
Melting Point: > 300°C
Flash Point: Not flammable in solid state
Boiling Point: Not applicable (decomposes)
Solubility: Poorly soluble in water, dispersible
Vapor Pressure: Not relevant
Density: Approx. 1.3 g/cm³
Explosive Properties: Dust may cause explosive mixtures in air
Viscosity: Not applicable
Partition Coefficient (n-octanol/water): Not determined for mixture

Stability and Reactivity

Chemical Stability: Product remains stable under recommended handling and storage
Reactivity: Non-reactive under normal use, avoid contact with strong acids, alkalis, strong oxidizers
Hazardous Reactions: None known under recommended conditions
Decomposition Products: Generates phosphorus oxides, hydrocarbons, and irritant fumes at high temperatures
Conditions to Avoid: Excessive heat, conditions favoring strong dust formation, high humidity

Toxicological Information

Acute Oral Toxicity: Low toxicity, LD50 (rat) > 2000 mg/kg (study data available)
Acute Dermal Toxicity: LD50 (rat) > 2000 mg/kg
Inhalation Toxicity: Dust may irritate respiratory tract, no evidence of acute toxicity at typical workplace exposure
Skin Irritation: Mild skin irritation possible, particularly with prolonged contact
Eye Irritation: Causes moderate to severe eye irritation
Carcinogenicity: No data showing carcinogenic properties
Specific Target Organ Toxicity: No evidence for chronic effects
Other Data: No sensitizing effects reported, no reproductive or developmental toxicity revealed in standard animal tests

Ecological Information

Persistence and Degradability: Poor biodegradability in soil and water based on structure
Aquatic Toxicity: Not acutely toxic to fish, daphnia, or algae at typical environmental concentrations
Bioaccumulation: Low potential for bioaccumulation due to water insolubility
Soil Mobility: May remain bound to soil particles, unlikely to leach to groundwater
Other Ecotoxic Effects: Avoid uncontrolled release into surface water, soils, or sewer systems
Wastewater Impact: Can be removed by appropriate effluent treatment processes

Disposal Considerations

Product Waste: Dispose through approved landfill or incineration according to local environmental regulations
Contaminated Packaging: Rinse thoroughly, recycle or dispose according to local policies
Sewage Disposal: Do not allow product or cleaning water to enter drains unless authorized
Special Instructions: Avoid creating dust during disposal, use protective equipment, follow relevant waste regulations for hazardous substances

Transport Information

UN Number: Not regulated for transport
UN Proper Shipping Name: Not classified as dangerous goods under IATA, IMDG, or ADR/RID
Transport Hazard Class: Non-hazardous for all modes of transport
Packing Group: Not assigned
Environmental Hazards: Not considered a marine pollutant
Special Precautions: Avoid spilling bags or containers, keep dry during transit
Transport Labeling: Standard goods labeling, no special marking required

Regulatory Information

Labeling: Complies with EU CLP Regulation, US OSHA GHS requirements, local country chemical safety regulations
Inventory Status: Listed or notified under REACH, TSCA, DSL, AICS, ENCS, and other national inventories
Hazard Symbols: Exclamation mark (GHS07)
SARA/Title III/California Prop 65: Not listed as a carcinogen or reproductive toxin
Restrictions: Use only for intended industrial applications, do not use in medical or food applications
Additional Information: Safety datasheets provided in compliance with local and international safety standards, keep documentation accessible to operators and emergency responders