Product Name: Flexible PU Foam Flame Retardant
Recommended Use: Flame retardant additive for polyurethane foam production
Manufacturer: GlobalSafe Chemicals Ltd.
Address: 3206 Industrial Park Road, Houston, TX, 77001, USA
Contact Number: +1-800-555-8392
Emergency Contact: CHEMTREC 1-800-424-9300
CAS Number: Mixture (see composition section for individual component CAS)
Product Code: GSFR-PUFX
Synonyms: PU Foam Retardant, Firestop PU Compound
Hazard Classification: Eye irritation Category 2A, Skin irritation Category 2, Acute toxicity Category 4 (oral)
GHS Label: Warning
Hazard Statements: May cause eye and skin irritation, harmful if swallowed, possible respiratory irritation after prolonged exposure
Pictograms: Exclamation mark
Routes of Entry: Inhalation, Skin contact, Eye contact, Ingestion
Symptoms: Redness, tearing, abdominal discomfort, headache, dizziness
Health Hazards: Exposure can trigger dermatitis or sensitivities after regular contact
Environmental Hazards: Toxic to aquatic life with long lasting effects if released in quantity
Precautionary Measures: Avoid breathing dust or vapors, use protective equipment
Component: Tris(2-chloroethyl) phosphate (TCEP)
CAS Number: 115-96-8
Percentage: 30-50%
Component: Antimony trioxide
CAS Number: 1309-64-4
Percentage: 5-30%
Component: Diethyl bis(2-hydroxyethyl)aminomethylphosphonate
CAS Number: 2781-11-5
Percentage: 10-20%
Component: Additives, non-hazardous
CAS Number: Proprietary
Percentage: 10-40%
Inhalation: Move person to fresh air. If symptoms persist, seek medical attention. Provide oxygen if breathing is difficult.
Skin Contact: Remove contaminated clothing, rinse skin thoroughly with soap and water for 15 minutes. Seek medical attention if irritation develops.
Eye Contact: Rinse with water for at least 15 minutes while holding eyelids apart. Remove contact lenses if present and continue rinsing. Call doctor if irritation continues.
Ingestion: Rinse mouth with water, drink two glasses of water. Do not induce vomiting. Call a poison center or doctor immediately.
Most Important Symptoms/Effects: Moderate skin and eye irritation, possible gastric upset, headaches, coughing due to inhalation
Flammability: Not easily flammable, may form hazardous decomposition products at high temperature
Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Do not use direct water jet, may spread burning material
Hazardous Combustion By-products: Hydrogen chloride, oxides of phosphorus, carbon monoxide, antimony oxide fumes
Protective Equipment for Firefighters: Self-contained breathing apparatus, full-protective suit
Firefighting Procedures: Move containers away from fire area if safe, contain fire-fighting water runoff, use caution due to toxic gases
Personal Precautions: Evacuate non-essential personnel, ventilate area, prevent inhalation of fumes
Protective Equipment: Chemical-resistant gloves, splash-proof goggles, respirator for dust or vapor
Environmental Precautions: Avoid runoff to drains, surface water or soil. Notify authorities if large spill affects waterways
Methods for Clean-up: Contain spillage, collect with inert absorbent (sand, vermiculite), shovel into containers for disposal, wash non-porous surfaces with detergent
Disposal: Dispose in compliance with local, state, national regulations. Do not incinerate closed containers. Prevent waste from entering environment.
Handling: Handle with adequate ventilation, avoid breathing dust or vapor, avoid skin and eye contact, do not eat or drink while using product
Storage Conditions: Store tightly sealed in original containers in a cool, dry, well-ventilated space. Keep away from sources of ignition, direct sunlight, oxidizers
Storage Temperature: Between 5°C and 35°C
Incompatible Materials: Strong acids, strong bases, oxidizing agents, isocyanates
Special Advice: Segregate from foodstuffs and animal feed. Use secondary containment for large storage tanks
Exposure Limits: TCEP (1 mg/m³ TWA, OSHA), Antimony trioxide (0.5 mg/m³ TWA, ACGIH)
Engineering Controls: Use mechanical ventilation or local exhaust to control airborne vapors, install eyewash/safety showers
Personal Protection: Chemical-resistant gloves, safety goggles, lab coat or coveralls, approved respirator if airborne concentrations exceed recommended limits
Industrial Hygiene: Wash hands after handling, no food or drink in work area, launder clothing before reuse
Appearance: Slightly viscous pale yellow liquid
Odor: Mild, characteristic acrid odor
pH: 5.5-7.5 (1% solution)
Boiling Point: Above 210°C
Melting Point: Below -10°C
Flash Point: 188°C (closed cup)
Auto-ignition Temperature: 430°C
Vapor Pressure: 0.2 mmHg @ 25°C
Relative Density: 1.29 g/cm³
Solubility: Partial solubility in water, complete in polar organic solvents
Viscosity: 120-160 cP @ 25°C
Percent Volatile: Less than 2% by weight
Evaporation Rate: Negligible under normal conditions
Chemical Stability: Chemically stable under recommended storage and operating conditions
Conditions to Avoid: High heat, open flames, direct sunlight, strong oxidizers
Hazardous Reactions: No hazardous polymerization under normal conditions, but reacts with strong acids/base
Decomposition Products: HCl, CO, CO2, oxides of phosphorus, antimony oxides, chlorinated compounds
Incompatibility: Avoid isocyanates, peroxides, strong oxidizers
Acute Toxicity: Oral LD50 (rat) 900 mg/kg for TCEP, Antimony trioxide oral LD50 (rat) 7000 mg/kg
Skin Corrosion/Irritation: Moderate irritant with repeated exposure
Eye Damage/Irritation: Causes redness, slow to heal in some cases
Respiratory Sensitization: Repeated exposure may result in irritation and coughing
Carcinogenicity: Antimony trioxide classified as possible human carcinogen (IARC Group 2B)
Reproductive Toxicity: TCEP shown reproductive toxicity in laboratory animals at high doses
Chronic Effects: Can contribute to dermatitis and possible neurological symptoms for unprotected workers
Aquatic Toxicity: TCEP LC50 (Fish, 96 hr): 110 mg/L; Antimony trioxide LC50 (Fish, 96 hr): 80 mg/L; harmful to aquatic organisms
Persistence and Degradability: Not readily biodegradable, persistent in soil and sediment
Bioaccumulation Potential: Moderate for organophosphate component
Mobility in Soil: Low to moderate, possibility of groundwater contamination if large release
Other Effects: No known significant effects on ozone depletion or global warming
Waste Treatment Methods: Incinerate in approved facility. Avoid open dumping or landfill wherever possible
Container Disposal: Rinse empty drums with water, then treat as chemical waste. Do not reuse container unless professionally cleaned
Regulatory Information: Classified as hazardous waste under US EPA RCRA regulations
Precautions: Prevent waste from entering drains, soil or surface waters. Comply with local regulations for disposal of chemical substances
UN Number: NA3082
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains Tris(2-chloroethyl) phosphate, Antimony trioxide)
Transport Hazard Class: 9 (Miscellaneous dangerous substances)
Packing Group: III
Labels: Environmental hazard symbol
Marine Pollutant: Yes
Special Precautions: Secure containers during transport, keep upright and away from incompatible goods
Safety, Health and Environmental Regulations: All components listed on TSCA, REACH and DSL inventories. Subject to SARA Title III Section 313 reporting for Antimony trioxide.
OSHA Classification: Hazardous
GHS Classification: Eye irritant, skin irritant, acute toxic
California Proposition 65: TCEP and Antimony trioxide listed as substances known to State of California to cause cancer
Risk Phrases: R22 Harmful if swallowed. R36/38 Irritating to eyes and skin
Safety Phrases: S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves
International Inventories: Compliant with EC, Japanese ENCS, Korean KECI, and Australian AICS chemical inventories
