Material Safety Data Sheets: Halogen Free Flame Retardant Binders

Identification

Product Name: Halogen Free Flame Retardant Binder
Product Code: HFFR-B123
Manufacturer: FireGuard Polymers Inc.
Supplier Address: 1750 Polymer Park, Springfield, OH 45501, USA
Emergency Phone: +1-800-555-3517
Intended Use: Industrial adhesives and coatings for fire resistance
Recommended Restrictions: Not for household or medical use

Hazard Identification

Hazard Category: Eye Irritant, Skin Sensitizer
Signal Word: Warning
Hazard Statements: May cause mild skin irritation, causes serious eye irritation, can trigger allergic skin reaction in some individuals
Pictograms: Exclamation mark
Precautionary Statements: Wear eye protection, use gloves, avoid breathing in dust or vapors, wash hands thoroughly after handling
Target Organs: Eyes, skin
Routes of Exposure: Eyes, skin, inhalation

Composition / Information on Ingredients

Polyvinyl Acetate (PVAc): 30-60%
Ammonium Polyphosphate (APP): 20-40%
Expandable Graphite: 10-25%
Aluminum Trihydroxide: 10-20%
Additives (Proprietary, non-halogenated): 1-5%
Note: No halogenated compounds present

First Aid Measures

Eye Contact: Rinse carefully with water for several minutes, remove contact lenses if present, seek medical advice if irritation persists
Skin Contact: Wash with soap and water, call a doctor if a rash or irritation develops
Inhalation: Move to fresh air, get medical attention for ongoing cough or breathing difficulty
Ingestion: Rinse mouth, avoid forcing vomiting, seek medical attention if feeling unwell

Fire-Fighting Measures

Suitable Extinguishing Media: Water fog, dry chemical, foam, carbon dioxide
Unsuitable Media: Do not use high-pressure water streams
Specific Hazards: Forms irritating vapors when heated, may release small amounts of carbon oxides and ammonia
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Special Procedures: Cool exposed containers with water spray, avoid inhaling combustion gases

Accidental Release Measures

Personal Precautions: Use gloves, goggles, protective clothing, ensure adequate ventilation
Spill Cleanup Method: Contain spill with inert absorbent (sand, earth), shovel into containers for disposal, wash area with soapy water
Environmental Precautions: Prevent entry to sewers, storm drains, or waterways, notify authorities if significant environmental contamination occurs
Reference to Other Sections: See Exposure Controls and Disposal Considerations below

Handling and Storage

Handling: Keep containers closed, use in well-ventilated areas, avoid contact with skin and eyes, prevent dust and vapor formation
Storage: Store in a cool, dry, well-ventilated place, keep away from heat and ignition sources, prevent container damage
Incompatible Materials: Strong acids, strong bases, oxidizers
Appropriate Packaging: Use approved chemical-resistant containers only

Exposure Controls and Personal Protection

Exposure Limits: No OSHA or ACGIH limits for primary ingredients; observe good industrial hygiene practices
Respiratory Protection: Use approved dust mask if ventilation is poor
Hand Protection: Chemical-resistant gloves (nitrile or neoprene preferred)
Eye Protection: Safety goggles or face shield
Skin Protection: Wear protective clothing, long sleeves recommended
Engineering Controls: Local exhaust ventilation, safety showers and eyewash stations nearby

Physical and Chemical Properties

Appearance: White or pale grey viscous liquid
Odor: Mild, slightly ammoniacal
pH: 6 to 8
Viscosity: 1,500 – 5,000 mPa·s
Boiling Point: >100°C (water-based carrier)
Melting Point: Not applicable
Flash Point: Non-combustible
Solubility (Water): Dispersible
Vapor Pressure: Low at room temperature
Density: 1.20 – 1.40 g/cm³

Stability and Reactivity

Chemical Stability: Stable under normal storage and use conditions
Possibility of Hazardous Reactions: Unlikely in intended use, avoid mixing with incompatible chemicals
Hazardous Decomposition Products: Carbon oxides, phosphorus oxides, ammonia
Conditions to Avoid: Excessive heat, freezing, incompatible materials

Toxicological Information

Acute Toxicity: Not classified as hazardous; irritation possible with prolonged exposure
Skin Contact: Sensitization reactions may occur in susceptible individuals
Eye Contact: Causes moderate to strong irritation
Inhalation: Mild nose and throat irritation possible with dust or fumes
Chronic Effects: No evidence of carcinogenicity or reproductive toxicity
Other Info: Allergic reactions possible with repeated exposure

Ecological Information

Ecotoxicity: Minimal expected impact on aquatic life based on available data
Persistence & Degradability: Components degrade slowly, not readily biodegradable
Bioaccumulation Potential: Low, due to water dispersibility
Mobility in Soil: Moderate; will move with water
Other Adverse Effects: Contains no halogen compounds or heavy metals that persist in the environment

Disposal Considerations

Product Waste: Dispose in accordance with local, state, national regulations, avoid disposal in untreated form
Container Disposal: Empty containers should be triple rinsed, may be recyclable in some jurisdictions
Treatment Options: Chemical incineration or approved solid waste landfill, prevent release to water bodies
Hazardous Waste Classification: Not regulated as hazardous waste under US RCRA laws

Transport Information

UN Number: Not regulated for transport
Transport Hazard Classes: Not assigned
Packing Group: Not applicable
Shipping Name: Non-hazardous for air, sea, and land transport
Special Precautions: Protect containers from puncture and rolling during transit, do not allow freezing

Regulatory Information

OSHA Hazard Communication Standard: Classified as hazardous based on irritant effects
TSCA Inventory: All ingredients listed
SARA Title III (Sections 311/312): Immediate (Acute) Health Hazard
California Proposition 65: No listed substances present
REACH Status: Components comply with EU REACH registration
Other Notes: No halogens, heavy metals, or SVHCs present