Product Name: Halogen Free Flame Retardant for Nylon
Product Use: Additive for improved fire resistance in polyamide materials
Manufacturer: Named supplier with current address, direct contact phone, and email
Emergency Contact: 24-hour hotline, including international access
Other Names: Commercial synonyms and alternative chemical identifiers
Relevant Identified Uses: Industrial compounding, injection molding, extrusion
Restrictions on Use: Applications outside thermoplastic resin compounding, non-industrial handling
SDS Issue Date: Most recent version date for reference
Classification: Non-toxic, combustion inhibitor, non-corrosive, not sensitizing by skin contact
Hazard Statements: Exposure to decomposition produces irritating gases; inhalation of dust may irritate upper respiratory tract
Precautionary Statements: Avoid dust generation, ventilate processing areas, wear proper PPE
GHS Label Elements: Signal word: Warning; pictograms for irritant
Other Hazards: Dust may aggravate asthma, thermal processing may create hazardous by-products
Hazard Risk Codes: Contains no PBT or vPvB substances, free of halogen content
Chemical Description: Inorganic phosphorus-nitrogen compound blend
Typical Components: Ammonium polyphosphate (CAS: 68333-79-9): 60-80%, Melamine polyphosphate (CAS: 15541-60-3): 15-35%, Synergistic minerals (e.g., magnesium hydroxide, aluminum distearate): 1-10%, Residual organic process aids: <1%
Impurities: Free of halogen, antimony, and heavy metals
Concentration Range: Varies by production batch, full analysis available upon request
Inhalation: Move person to fresh air, monitor for persistent cough or shortness of breath, seek medical attention if irritation remains
Skin Contact: Wash exposed skin with mild soap and lukewarm water, cover open wounds, apply emollient for persistent irritation
Eye Contact: Rinse eyes with water for 20 minutes, remove contact lenses if worn, keep eyelids open, seek medical care as necessary
Ingestion: Rinse mouth, drink water, do not induce vomiting, observe for symptoms, consult a physician
Acute/Delayed Symptoms: Immediate irritation of mouth, eyes, or respiratory passages, no known chronic poisoning symptoms
Medical Advice: Person attending should wear gloves to avoid secondary exposure, provide material label to medical personnel
Suitable Extinguishing Media: Foam, carbon dioxide, dry chemical, water spray
Unsuitable Media: High-pressure water jets may spread powder
Specific Hazards: Combustion generates oxides of nitrogen and phosphorus gas, dense smoke
Protective Equipment: Self-contained breathing apparatus, full turnout gear
Special Procedures: Dike runoff to prevent environmental contamination, cool containers with water spray
Personal Precautions: Avoid breathing dust, ventilate area, evacuate unnecessary personnel, use PPE
Spill Response: Collect with vacuum or damp sweeping methods, avoid raising dust clouds, use antistatic tools
Environmental Protection: Prevent entry into sewers or watercourses, report significant releases to regulatory authorities
Clean-Up Methods: Place recovered material in properly labeled containers, dispose via licensed waste contractor
Handling: Use only in designated, well-ventilated, spark-free areas, avoid eating and drinking while working, practice good hygiene, ensure all users trained in material risks
Storage Requirements: Store in original, tightly closed packaging, away from incompatible materials (oxidizers, strong acids), keep dry and cool (5–30°C), maintain segregation from food, beverages, animal feed
Other Controls: Keep pallets stable, check regularly for packaging integrity
Occupational Limits: No specific ACGIH or OSHA limit, recommend keeping airborne dusts below 1 mg/m³ (total inhalable particles)
Engineering Measures: Local exhaust ventilation, dedusting filters, process enclosures at transfer or mixing points
Personal Protection: NIOSH-approved dust mask, non-permeable gloves (e.g., nitrile or PVC), splash-proof safety glasses, full coveralls and closed shoes
Hygiene Measures: Wash exposed skin after use, remove contaminated clothing before breaks, launder clothing regularly
Environmental Protection: Install dust collectors, regularly monitor workplace dust levels
Appearance: White or off-white fine powder or small granulated particles, nearly odorless
Odor Threshold: Not detectable by typical methods
pH (10% aqueous solution): 5.0–7.5 (mildly acidic to neutral)
Melting Point: Decomposition above 300°C, chemically stable until processing temperatures
Solubility: Practically insoluble in water and most common solvents
Density: 1.7–2.0 g/cm³ depending on formulation
Flammability: Non-combustible, designed to retard ignition in polymers
Vapor Pressure: Not applicable (solid)
Particle Size: Typically d50 = 10–40 μm
Decomposition Products: Nitrogen oxides, phosphate fumes under fire conditions
Chemical Stability: Stable under normal ambient and anticipated storage conditions
Reactivity: Unreactive under ordinary use; strong acids can cause decomposition
Conditions to Avoid: Exposure to strong oxidizers or acids, high humidity, prolonged overheating
Hazardous Decomposition: Fumes from thermal breakdown may contain ammonia, phosphorus oxides, and irritating organics
Polymerization: No known risk of uncontrolled polymerization
Route of Exposure: Inhalation, skin/eye contact, ingestion (accidental)
Acute Toxicity: Low acute oral and dermal toxicity (LD50 > 5000 mg/kg, rat, oral); not a skin or eye corrosive
Chronic Effects: Repeated excessive inhalation may cause reversible respiratory irritation
Carcinogenicity: Components not classified as carcinogenic by IARC, NTP, or OSHA
Mutagenicity: No evidence of DNA or cellular mutations in standardized tests
Irritation/Sensitization: Does not cause delayed hypersensitivity
Environmental Toxicity: Not toxic to aquatic or terrestrial organisms in standard laboratory screening
Persistence/Degradability: Insoluble and stable in natural waters, undergoes slow mineralization in soil
Bioaccumulation: Insignificant potential for accumulation in living organisms
Mobility: Low mobility in soil or sediment due to insolubility
Other Adverse Effects: No halogen, heavy metal or persistent organic pollutants detected in effluent
Wastewater Consideration: Pre-filter before sewer disposal to remove solids
Waste Handling: Collect into sealed containers; avoid generating dust during transfer
Landfill Disposal: Use designated landfill sites for non-hazardous solids, comply with local consents
Recovery: Clean uncontaminated product can be recycled for production use
Incineration: Suitable for municipal facility that accepts industrial wastes, monitor for toxic fume control
Packaging Disposal: Contaminated packaging requires incineration or disposal as solid waste; clean packaging may be recycled
UN Number: Not regulated for transport as a hazardous material
Proper Shipping Name: Non-hazardous flame retardant additives
Transport Hazard Class: Not classified under ADR, IMDG, IATA
Packing Group: Not applicable
Special Precautions: Secure against tipping or mechanical shock; moisture protection strongly encouraged
Hazard Label: None required for road, rail, air, or sea transport
Inventory Status: All main ingredients listed on TSCA (US), REACH (EU), DSL (Canada)
REACH Registration: Pre-registered and fully registered for volume and use class
OSHA Classification: Not classified as hazardous
SARA Title III: Non-listed, not a Section 313 substance
RoHS and WEEE: Fully compliant—contains zero restricted substances
Japan ENCS: Registered under Use Category 7 (Polymers – Additives)
Other Approvals: China IECSC, Korea ECL, Australia AICS, Taiwan TCSI: all notified
Labeling Requirements: Hazard communication consistent with GHS, include warning for combustion byproducts
