Product Name: High-Efficient Flame Retardant for Polyamide (PA) and Polybutylene Terephthalate (PBT)
Chemical Family: Phosphorus-based additive blend
Synonyms: Phosphinate salt, proprietary flame retardant mixture
Manufacturer: Global Advanced Chemicals Ltd.
Manufacturer’s Address: 1400 Industrial Avenue, Houston, Texas, 77001, USA
Phone for Information: +1 713-555-1234
Emergency Contact: 24-Hour Emergency, CHEMTREC 1-800-424-9300
Recommended Use: Additive for enhancing fire resistance in engineering plastics
Restrictions: Not intended for food contact or medical applications
Classification: Eye Irritation Category 2A, Skin Sensitization Category 1, Specific Target Organ Toxicity (Single Exposure) Category 3
Signal Word: Warning
Hazard Statements: Causes serious eye irritation; may cause an allergic skin reaction; may cause respiratory irritation
Pictograms: Exclamation Mark, Health Hazard
Precautionary Statements: Avoid breathing dust; wear eye protection and gloves; wash hands thoroughly after handling; use only outdoors or in a well-ventilated area
Other Hazards: Fine powders may form combustible dust concentrations in the air
Chemical Name: Aluminium diethylphosphinate
CAS Number: 225789-38-8
Concentration: 75–90%
Supporting Ingredients: Proprietary synergists and processing aids, 10–25%
Impurities: Trace phosphorus oxides, less than 1%
Form: Granular powder or pellets, white to off-white
Inhalation: Remove victim to fresh air, loosen tight clothing, offer water, get medical attention if symptoms like coughing or shortness of breath start
Skin Contact: Take off contaminated clothing, wash with soap and water, apply lotion if irritation remains, seek medical advice for persistent rash
Eye Contact: Rinse gently with running water for at least fifteen minutes, hold eyelids open, remove contact lenses if comfortable, continue rinsing, consult an eye specialist for lingering pain or redness
Ingestion: Rinse mouth, offer water to drink, avoid forced vomiting, get medical assessment in the event of abdominal pain, headache, or persistent symptoms
Most Important Symptoms: Skin irritation, respiratory discomfort, stinging or redness in eyes, rashes
Indication of Immediate Attention: Difficulty breathing, prolonged skin or eye discomfort, or if large quantities swallowed
Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide
Unsuitable Extinguishing Media: High pressure water jets, which may spread dust
Hazardous Combustion Products: Phosphorus oxides, carbon oxides, and irritating fumes
Firefighting Instructions: Approach fire from upwind, wear self-contained breathing apparatus and full protective gear, keep containers cool with water spray
Explosion Risk: Dust clouds may ignite if exposed to flame or spark
Additional Info: Residue from burning may pose extra inhalation risk, restrict access and ventilate
Personal Precautions: Wear dust mask, chemical-resistant gloves, goggles, and protective clothing
Environmental Precautions: Prevent entry into drains, sewers, surface water, or soil
Containment: Cover spills with damp cloth or absorbent, avoid producing dust
Clean-Up Methods: Gently sweep or vacuum spillage into containers for recycling or disposal, wash area with detergent and water, collect washings for proper disposal
Disposal: Bag solid wastes in appropriate containers, label for specialized waste contractor
Other Notes: Remove ignition sources, ventilate area, avoid unnecessary contact
Safe Handling Practices: Minimize airborne dust, avoid skin and eye contact, work in well-ventilated areas, empty containers may hold product residues
Protective Gear: Protective gloves, dust mask, safety glasses
Storage Requirements: Store in tightly closed original containers, cool and dry place, away from strong oxidizers, acids, and sources of ignition
Storage Conditions: Typical storage temperature 5–35°C (41–95°F), keep out of direct sunlight, avoid moisture buildup
Incompatible Materials: Strong alkalis, oxidizing agents, strong acids
Special Provisions: Label storage area and keep access limited to trained personnel
Occupational Exposure Limits: Aluminium diethylphosphinate has no established exposure limits; keep workplace levels as low as possible
Engineering Controls: Local exhaust ventilation, dust collection systems, process enclosures
Personal Protection: Chemical-resistant gloves (nitrile or neoprene), safety goggles, fitted dust mask or respirator (NIOSH-approved), long sleeves/pants
Hygiene Measures: Wash before eating, drinking, or smoking, keep work clothes separate, avoid touching face
Environmental Control: Prevent release to environment, use closed systems where possible, proper waste disposal
Appearance: White to off-white powder or granulate
Odor: Faint, bland
Odor Threshold: Not established
pH (1% solution): 5.5–7.5
Melting Point/Freezing Point: > 300°C (decomposes before melting)
Boiling Point: Not applicable (decomposes)
Flash Point: Not flammable in solid state
Evaporation Rate: Not applicable
Flammability: Not easily ignited, but dust may be explosive
Upper/Lower Flammable Limits: Not determined
Vapor Pressure: Negligible at room temperature
Vapor Density: Not applicable
Relative Density: 1.3–1.5 (water = 1)
Solubility: Slightly soluble in water, insoluble in organic solvents
Partition Coefficient (n-octanol/water): Not determined
Auto-ignition Temperature: > 450°C for fine dusts
Decomposition Temperature: > 300°C
Viscosity: Not applicable
Chemical Stability: Product remains stable under normal storage and use
Hazardous Reactions: Reacts with oxidizing agents and strong acids, giving off heat and toxic fumes
Conditions to Avoid: Heating to decomposition, mixing with incompatible chemicals, mechanical impact producing airborne dust
Incompatible Materials: Strong oxidizers, concentrated mineral acids, alkalis
Hazardous Decomposition: Forms phosphorus oxides, carbon monoxide, and carbon dioxide when decomposed by heat
Acute Toxicity: Oral LD50 (rat): >2,000 mg/kg, considered low toxicity
Skin Corrosion/Irritation: Mild irritant on prolonged contact, dermatitis possible
Serious Eye Damage/Irritation: Strong eye irritant, causes redness and watering
Respiratory or Skin Sensitization: Repeated exposure may trigger allergic skin reactions or asthma-like symptoms
Mutagenicity: No evidence in standard mutagenicity screens
Carcinogenicity: No listed by IARC, NTP or OSHA as carcinogenic
Reproductive Toxicity: No known reproductive effects in animal models
Chronic Effects: Prolonged inhalation may worsen existing lung disease or skin allergies
Acute Aquatic Toxicity: Moderately toxic to aquatic life; LC50 (fish, 96h): 10–100 mg/L
Chronic Aquatic Toxicity: Risk of long-term effects in aquatic environment if not properly contained
Persistence and Degradability: Not rapidly biodegradable; persists in moist soil and water
Bioaccumulation Potential: Low risk due to low solubility
Mobility in Soil: Tends to bind to organic matter, low mobility in sand/clay
Other Hazards: Spilled pellets may be physically harmful to wildlife if ingested
Disposal Methods: Incinerate solids in approved hazardous waste facility, avoid landfill dumping, do not flush to sewer
Contaminated Packaging: Clean thoroughly or send for controlled destruction with product residues
Special Precautions: Separate from municipal waste, label bags or drums “Hazardous Chemical Waste”
Local Disposal Regulations: Follow state and federal chemical waste laws; refer to environmental agency for guidance
UN Number: Not regulated for transport under UN Recommendations
Proper Shipping Name: Flame retardant compound, not otherwise specified
Transport Hazard Class: Non-regulated, not flammable or explosive by standard tests
Packing Group: Not applicable
Labeling: No special markings for road, rail, air, or sea
Special Precautions for User: Keep containers sealed, prevent product dust formation, stack securely to avoid toppling
Transport in Bulk: Use sealed, lined containers if transported in bulk quantities
U.S. Inventory (TSCA): Listed
REACH (EU): Pre-registered, not classified as SVHC
OSHA: Regulated as hazardous according to Hazard Communication Standard 29 CFR 1910.1200
Canada (DSL/NDSL): Listed on Domestic Substances List (DSL)
SARA Title III: Not a Section 313 listed substance
RoHS/ELV/WEEE Compliance: Below regulated limits for restricted substances
Other National or Local Requirements: Safety data sheet available for workplace reference; workplace labeling and training needed for compliance with local laws
