Product Name: Low Bromine Flame Retardant for Polypropylene (PP)
Chemical Family: Brominated Organic Compounds
Synonyms: Low Br FR, Polypropylene Bromine Compound
Intended Use: Additive for fire resistance in plastics processing
Manufacturer: [Manufacturer Information]
Emergency Contact: [Contact Phone Number]
Product Code: [Product Code, typically alphanumeric]
Address: [Physical Manufacturer Address]
Recommended Use Restrictions: Not for direct contact with food
Date of Preparation: [Date]
GHS Classification: Eye irritation, skin irritation, acute aquatic toxicity
Signal Word: Warning
Hazard Statements: May cause skin irritation, causes serious eye irritation, hazardous to aquatic environment
Pictograms: Exclamation mark, environment
Precautionary Statements: Avoid breathing dust, wash exposed skin, prevent release to waterways
Potential Health Effects: Respiratory irritation, eye redness, mild dermatitis in prolonged exposure
Environmental Hazards: Harmful to fish and aquatic organisms
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Chemical Identity: Brominated Organic Compound Blend
CAS Number: [CAS Number, proprietary or mixture]
Concentration (%): 60–90% brominated core compound
Other Ingredients: Synergists (antimony trioxide <20%), carrier polymer or additive (5–10%)
Impurities: Trace halogenated organics, residual solvents below 1%
Specific identities available upon request or in accordance with local regulations
Inhalation: Move affected person to fresh air, monitor for breathing difficulty, seek medical help if symptoms persist
Skin Contact: Rinse with soap and plenty of running water, remove contaminated clothing, seek attention for persistent redness
Eye Contact: Flush eyes continuously with water, remove contact lenses if present, keep flushing, consult physician
Ingestion: Rinse mouth, drink small amounts of water, do not induce vomiting, medical assistance recommended
Symptoms: Watery eyes, dry throat, red patches on skin
Medical Attention: Advise healthcare provider of product identity and exposure circumstances
Suitable Extinguishing Media: Foam, water spray, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Strong water jets may spread material
Special Hazards: Releases hydrogen bromide, carbon oxides, dense black smoke in fire scenarios
Fire Fighting Instructions: Wear full protective clothing, self-contained breathing apparatus
Cool Exposed Containers: Use water fog on surrounding containers
Combustion Products: Bromine vapors, antimony oxides, possible unidentified toxic and corrosive gases
Explosion Hazard: Not expected under normal conditions, but dust may present explosion risk if finely divided in air
Personal Precautions: Evacuate area, avoid dust, use proper PPE (gloves, goggles, dust mask)
Cleanup Procedures: Scoop up solid with non-sparking tools, place in labeled waste containers
Spillage Containment: Prevent dispersal into drains, moisten dust before sweeping
Decontamination: Wash area with plenty of water after material removal
Advice for Non-Emergency Personnel: Do not touch spilled material, keep unprotected people away
Disposal: Store collected material in covered, chemically compatible containers, send for proper disposal
Safe Handling: Minimize dust, use in ventilated area, avoid breathing particles
Technical Measures: Use grounding/bonding when transferring material
Incompatible Materials: Strong acids, strong bases, oxidizers
Conditions to Avoid: High temperatures, ignition sources, direct sunlight
Storage: Store in original containers, cool dry location, tightly closed
Personal Hygiene: Wash hands after handling, remove contaminated clothing promptly
Storage Stability: Stable under recommended conditions for one year minimum
Engineering Controls: Mechanical ventilation in work area, local exhaust hood
Respiratory Protection: NIOSH-approved dust mask or air-purifying respirator for workplace exposure
Skin Protection: Chemical-resistant gloves (nitrile, neoprene), long sleeves
Eye Protection: Safety goggles with side shields or face shield
Workplace Hygiene: Remove contaminated PPE and wash before reuse, do not eat or drink in work zone
Occupational Exposure Limits: Antimony trioxide 0.5 mg/m³ (ACGIH TLV), no established limit for main compound
Environmental Exposure Controls: Prevent release to soil or waterways, use spill containment tools
Appearance: White to off-white powder or granular solid
Odor: Slight, faintly chemical
Odor Threshold: Not established
pH: 6–8 (suspension in water)
Melting Point: 240–320°C (may soften below this)
Decomposition Temperature: >250°C
Solubility: Insoluble in water, soluble in various organic solvents
Boiling Point: Not determined (decomposes before boiling)
Vapor Pressure: Negligible at room temperature
Density: 1.4–1.9 g/cm³
Partition Coefficient: Not applicable (solid mixture)
Flash Point: >200°C (open cup)
Evaporation Rate: Not relevant for solid
Explosive Limits: No data, danger in fine dust-air mixtures
Viscosity: Not applicable
Chemical Stability: Stable under normal temperatures and recommended storage
Hazardous Reactions: No dangerous reactions in ordinary use
Potential Reactivity: May react with strong oxidizers, generating heat and toxic fumes
Conditions to Avoid: Open flames, excess heat, direct exposure to acidic or basic environments
Incompatible Materials: Ammonia, strong acids (such as sulfuric acid), oxidizing agents (such as bleach)
Hazardous Decomposition Products: Hydrogen bromide, brominated organic fragments, carbon monoxide, antimony fumes
Acute Toxicity: Oral LD50 (rat)>2000 mg/kg for base compound, variable for synergists
Skin Irritation: Mild to moderate with prolonged or repeated contact
Eye Irritation: Causes redness, tearing, possible corneal injury
Mutagenicity: Not classified as genotoxic, but data gaps for full mixture
Carcinogenicity: No evidence for main compound, antimony trioxide classified as possible carcinogen (IARC 2B)
Chronic Effects: Prolonged inhalation induces cough, mild respiratory distress
Inhalation: Particulate may produce sneezing, coughing, sore throat
Sensitization: Not classified as allergen, cases are rare
Specific Target Organ Toxicity: No evidence for single exposure at typical handling doses
Ecotoxicity: Product has moderate to high toxicity for aquatic organisms (96h LC50 (fish) 1–10 mg/L)
Persistence and Degradability: Brominated components are persistent, breakdown slowly in environment
Bioaccumulation Potential: Medium, potential to accumulate in aquatic ecosystems, low in mammals
Mobility in Soil: Binds to sediment and organic matter, low mobility
Aquatic Toxicity: Toxic to algae and daphnia, chronic effects in sediment organisms
Additional Environmental Notes: Avoid uncontrolled release to surface water or sewer drains, no significant photodegradation in sunlight
Waste Treatment Methods: Dispose of waste through licensed hazardous waste contractor
Landfill Disposal: Permissible under controlled conditions, follow local regulations
Incineration: High-temperature incineration recommended to limit halogen gas formation
Packaging Disposal: Triple rinse containers, offer for recycling where possible
Regulatory Disposal Requirements: Classified as hazardous in several countries due to bromine and antimony
Precautions: Do not dump in nature, do not discharge into sewer systems
Labeling: Use appropriate hazard pictograms and disposal statements on all waste containers
UN Number: Not regulated as dangerous good under UN Model Regulations
Proper Shipping Name: Not classified for regular transport, generic name: Organic solid, n.o.s.
Transport Hazard Class: Not assigned
Packing Group: Not assigned
Marine Pollutant: Yes, prevent bulk release
Special Transport Precautions: Keep containers sealed, cool, dry transport, avoid shifts and spills
Other Information: No special handling under ADR/RID/IMDG/IATA unless mixed with other hazardous materials
TSCA Status: Some components listed
REACH Registration: Components pre-registered or registered in EU
US OSHA Regulation: Meets criteria for hazardous chemicals, Safety Data Sheet required
SARA Title III: Contains antimony—subject to reporting
California Prop 65: May contain trace antimony trioxide, listed chemical
DSL/NDSL Canada: Components listed
Other Food/Drug Use Restrictions: Not intended for direct food contact, pharmaceutical, or potable water systems
Labeling Requirements: GHS hazard pictograms, Signal Word "Warning", hazard and precautionary statements
Workplace Regulations: Ensure workers receive chemical safety training, provide access to Safety Data Sheet
