Product Name: Low Halogenated Flame Retardant for Polypropylene
Synonyms: Halogen-modified polymer fire inhibitor
Manufacturer: PolyChem Additives Incorporated, 1789 Composite Lane, Springfield, OH 45501, USA
Recommended Use: Flame retardant additive for polypropylene plastics in construction materials, electronics, automotive parts
Emergency Contact: CHEMTREC: 1-800-424-9300 (24 hours)
Classification: Skin irritant (Category 2), Eye irritant (Category 2), Specific target organ toxicity – single exposure (Category 3)
Label Elements:
Hazard pictogram: Exclamation mark
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation, may cause respiratory irritation
Precautions: Avoid breathing dust, wear protective gloves, rinse eyes if product contact occurs
Brominated Organic Compound: 20–30% CAS No: 1163-19-5
Chlorinated Synergist: 15–20% CAS No: 63449-39-8
Antimony Trioxide: 3–7% CAS No: 1309-64-4
Polypropylene Carrier Resin: 45–55% CAS No: 9003-07-0
Other Additives: Proprietary stabilizers and process aids, less than 5%
Inhalation: Remove person to fresh air, seek medical advice if symptoms like coughing or dizziness persist
Skin Contact: Wash affected area thoroughly with soap and plenty of water, remove contaminated clothing
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing
Ingestion: Rinse mouth with water, do not induce vomiting unless directed by medical personnel, get medical help if feeling unwell
Suitable Extinguishing Media: Water spray, foam, dry chemical powder, carbon dioxide
Unsuitable Extinguishing Media: High-volume water jet (may cause product dispersion)
Specific Hazards: Burning may give off toxic fumes of hydrogen bromide, hydrogen chloride, antimony compounds
Special Protective Equipment: Firefighters should wear full gear, including self-contained breathing apparatus, and avoid inhaling vapors
Fire Fighting Instructions: Use water to cool surrounding containers, fight fire from a safe distance, contain runoff to prevent contamination
Personal Precautions: Keep away from dust, wear protective gloves, goggles, and dust mask
Environmental Precautions: Prevent entry into drains, watercourses, or soil, in case of spillage notify relevant authorities
Cleaning Methods: Scoop up powder or granules carefully, put in labeled containers for disposal or recovery, wash area with water after cleanup
Handling: Use only with local ventilation or in a well-ventilated area, avoid generating dust, do not eat or drink while handling
Storage Conditions: Store in tightly closed containers in a dry, cool, and well-ventilated area, keep away from heat or open flame
Incompatible Materials: Strong acids, strong bases, oxidizers, avoid storage with food or animal feed
Packaging: Use original containers or containers made of compatible polymer, keep container tightly sealed after each use
Engineering Controls: Local exhaust ventilation, eyewash stations, safety showers
Exposure Limits: Antimony trioxide (OSHA PEL: 0.5 mg/m3), brominated and chlorinated compounds not specifically regulated but minimize exposure
Personal Protection: Gloves (nitrile or neoprene), chemical safety goggles, long-sleeved clothing, respiratory protection (dust mask or PAPR if airborne particles are high)
Appearance: Off-white to pale yellow powder or granule
Odor: Faint chemical or resinous odor
Melting Point: 110–180°C (dependent on grade and composition)
Density: 1.03–1.31 g/cm3
Solubility: Insoluble in water
Flash Point: >250°C
Vapor Pressure: Negligible at room temperature
pH: 6–8 (aqueous suspension)
Decomposition Temperature: Above 295°C
Viscosity: Not applicable (solid material)
Chemical Stability: Stable under normal handling and storage conditions
Conditions to Avoid: Extreme heat, flame, exposure to strong acids and bases
Hazardous Reactions: No dangerous reactivity expected under normal conditions
Decomposition Products: Burning yields toxic gases such as hydrogen halides, antimony oxides, and organic vapors
Acute Toxicity: Inhalation of dust can cause respiratory irritation, ingestion causes mild gastrointestinal discomfort
Skin Corrosion/Irritation: Repeated or prolonged contact can cause redness, itching, or minor dermatitis
Eye Damage/Irritation: Direct contact with powder or dust may cause redness, watering, or irritation
Chronic Effects: Inhalation of fine particulate over long periods may affect lung function, particularly antimony trioxide component
Carcinogenicity: Antimony trioxide classified as possible human carcinogen (IARC Group 2B), brominated and chlorinated organics under investigation for long-term effects
Sensitization: Not expected to cause allergic reactions under normal use
Aquatic Toxicity: Compounds exhibit low to moderate toxicity to aquatic organisms, risk of bioaccumulation in sediment
Persistence and Degradability: Halogenated organics do not break down easily in natural environments, may persist for long periods
Mobility in Soil: Low mobility due to high molecular weight, possible leaching if released in fine powder form
Other Adverse Effects: Chronic exposure in large quantities may disrupt aquatic life, as halogenated compounds resist biodegradation
Disposal Methods: Collect and send to approved hazardous waste facility, incineration may be allowed under controlled conditions
Contaminated Packaging: Triple rinse containers, then dispose with hazardous materials or process as industrial waste
Local Regulations: Adhere to all regional, state, and federal provisions relating to halogenated chemical and antimony disposal
UN Number: Not regulated as a hazardous material for transport under UN recommendations
Transport Hazard Classes: Not classified as dangerous under ADR/RID, IMDG, IATA
Packing Group: Not applicable
Special Precautions: Avoid spillage, keep dry during transit, mark shipments to indicate chemical content in case of emergency
USA: Subject to TSCA inventory status, SARA Section 313 (antimony trioxide) reporting required
EU: Meets REACH registration requirements for flame retardant chemicals, labeling required per CLP regulations
Canada: WHMIS classification: D2A (materials causing other toxic effects)
Other: Not listed as restricted under the Montreal Protocol or Stockholm Convention, product safety datasheet must be provided with bulk sales
