Material Safety Data Sheet for Melamine Cyanurate Non-halogenated Flame Retardant Master

1. Identification

Product Name: Melamine Cyanurate Non-halogenated Flame Retardant Master
Trade Name: MCA Masterbatch
Synonyms: Melamine–Cyanuric acid complex, Flame Retardant MCA
Recommended Use: Flame retardant additive in plastics such as polyamide, thermoplastics, textiles
Manufacturer: [Insert Specific Company Based on Region]
Supplier Address: [Insert Manufacturer Address]
Contact Information: [Insert Telephone, Email]
Emergency Phone: [Insert Emergency Contact Number, available 24 hours]

2. Hazard Identification

GHS Classification: Not classified as hazardous according to OSHA Hazard Communication Standard 29 CFR 1910.1200
Label Elements: No pictogram or signal word necessary under GHS
Health Hazards: May cause mild mechanical irritation to eyes and skin; dust inhalation can irritate respiratory tract; no evidence for acute systemic toxicity
Environmental Hazards: Not classified as an aquatic toxicant; spills may affect wastewater treatment; high concentrations potentially persistent
Other Hazards: Combustion may generate nitrogen oxides and cyanuric derivatives
Physical Hazards: Dust can pose explosion risk under specific circumstances

3. Composition / Information on Ingredients

Chemical Name: Melamine Cyanurate
CAS Number: 37640-57-6
Percentage (w/w): 65–75%
Other Components: Polyolefin or polyamide carrier resin (balance)
Impurities: Trace unreacted melamine, cyanuric acid, less than 1%
Additives: Processing aids or lubricants below 2% (proprietary, non-hazardous)

4. First Aid Measures

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes; remove contact lenses if present and safe to do so; seek medical help if irritation persists
Skin Contact: Wash skin with soap and water; remove contaminated clothing and footwear; prolonged contact is not harmful, but persistent irritation should be evaluated by a doctor
Inhalation: Move person to fresh air; keep at rest in a position comfortable for breathing; obtain medical attention if symptoms persist such as coughing or wheezing
Ingestion: Rinse mouth with water thoroughly; do not induce vomiting; obtain medical advice
Most Important Symptoms: Eye and airway discomfort; red, itchy skin
Notes to Physician: Treat symptomatically based on patient’s condition and route of exposure

5. Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide
Unsuitable Media: Direct high-pressure water jets can scatter dust
Specific Hazards: Product decomposes at high temperature to produce nitrogen oxides, ammonia, carbon monoxide, and cyanuric gasses
Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective gear
Special Precautions: Avoid breathing smoke; contain runoff water to avoid environmental contamination; evacuate non-essential people from the area

6. Accidental Release Measures

Personal Precautions: Avoid dust generation; use respirators and goggles in case of massive dust; keep unprotected persons away
Environmental Measures: Prevent material from entering drains or water sources; sweep up spills promptly
Methods for Cleanup: Use antistatic tools and containers; collect mechanically, avoid creating airborne dust; place in suitable labeled containers for disposal
Decontamination: Wash affected area with water after removal of solid material

7. Handling and Storage

Handling Precautions: Use with effective ventilation; minimize dust formation; avoid contact with eyes, skin, and clothing; wear protective equipment; handle in accordance with good industrial hygiene
Safe Storage Conditions: Store in tightly closed containers; keep in dry, cool, well-ventilated area; avoid exposure to heat, flame, and strong oxidizers; prevent build-up of dust on surfaces
Incompatible Materials: Strong acids, oxidizers, bases, or materials that might release heat on contact

8. Exposure Controls / Personal Protection

Occupational Exposure Limits: No specific OSHA or ACGIH limits for melamine cyanurate; use total or respirable dust limits as guidance (e.g., OSHA PEL: 15 mg/m³ total dust; 5 mg/m³ respirable)
Engineering Controls: Provide local exhaust ventilation; isolate sensitive operations
Eye Protection: Safety glasses with side shields; goggles during bulk, dusty handling
Hand Protection: Protective gloves; nitrile or PVC recommended
Skin Protection: Work clothing covering arms, legs, and feet
Respiratory Protection: NIOSH-approved dust mask or respirator if dust levels are excessive
Additional Controls: Facilities for eye-washing and emergency showers in work area

9. Physical and Chemical Properties

Appearance: White to off-white granular masterbatch or powder
Odor: Odorless
Odor Threshold: Not applicable
pH: 5.5 – 7.0 (10% aqueous suspension)
Melting Point/Freezing Point: Decomposes above 350°C
Boiling Point: Not applicable (decomposes before boiling)
Flash Point: Not flammable in solid form
Evaporation Rate: Not applicable
Flammability: Non-flammable as manufactured; suppresses flammability in host polymers
Vapor Pressure: Negligible
Vapor Density: Not applicable
Specific Gravity: 1.5 – 1.7 g/cm³
Solubility in Water: Slightly soluble
Partition coefficient: Not determined
Auto-Ignition Temperature: Above 450°C
Decomposition Temperature: Approaching 350°C, emits toxic fumes
Viscosity: Not applicable to solid form

10. Stability and Reactivity

Chemical Stability: Stable under normal conditions of handling, storage, and use
Reactivity: Inert with most commercial materials
Hazardous Reactions: No known dangerous reactions under normal conditions
Conditions to Avoid: Excessive heat, open flame, strong oxidizers
Incompatible Materials: Strong acids, bases, oxidizers
Hazardous Decomposition Products: Melamine, cyanuric acid, carbon monoxide, ammonia, nitrogen oxides due to thermal breakdown

11. Toxicological Information

Acute Toxicity (oral/dermal/inhalation): Oral LD50 (rat): > 5000 mg/kg; low acute toxicity
Skin Corrosion/Irritation: Not a skin irritant in animal studies
Eye Damage/Irritation: May cause minor mechanical irritation
Respiratory Sensitization: No evidence
Skin Sensitization: Not a sensitizer
Germ Cell Mutagenicity: Not mutagenic based on available data
Carcinogenicity: IARC, NTP, OSHA: Not listed as carcinogen
Reproductive Toxicity: No adverse effects reported
Specific Target Organ Toxicity (single/repeat): Not expected
Aspiration Hazard: Not applicable
Route(s) of Exposure: Inhalation, eye and skin contact

12. Ecological Information

Ecotoxicity: Fish LC50 (96h): > 100 mg/L (low toxicity); Daphnia EC50: > 100 mg/L
Persistence and Degradability: Partially persistent under environmental conditions; slow degradation expected
Bioaccumulation Potential: Low; not expected to bioaccumulate significantly
Mobility in Soil: Slight mobility due to low water solubility
Other Adverse Effects: Large spills may interfere with physical characteristics of waterways

13. Disposal Considerations

Waste Treatment Methods: Dispose according to local, regional, and national regulations
Product Disposal: Landfill or incineration in approved facilities; recycling into compatible products is possible
Packaging Disposal: Clean, empty containers can be recycled or disposed according to local waste management protocols
Precautions: Do not discharge to surface water or sewers

14. Transport Information

UN Number: Not regulated as a hazardous material
UN Proper Shipping Name: Not applicable
Transport Hazard Class: Not classified as dangerous goods
Packing Group: Not assigned
Environmental Hazards: Not considered Marine Pollutant
Special Precautions: Protect from moisture and direct sunlight; avoid excessive stacking
DOT/IMDG/ICAO/IATA: No special transport requirements

15. Regulatory Information

Chemical Inventory Status: Listed on TSCA (US), EINECS (EU), DSL (Canada), ENCS (Japan)
SARA Title III: Not subject to SARA Section 313 reporting
OSHA: Not classified as hazardous chemical
REACH: Registered; no authorization or restriction
California Proposition 65: Not listed
Other Regulations: Compliance with RoHS and WEEE Directives for electronics
Labeling Requirements: No special hazard labeling required