MSDS for Melamine Polyphosphate (MPP)

Identification

Product Name: Melamine Polyphosphate (MPP)
Chemical Formula: (C3H6N6·H3PO4)n
Synonyms: Melamine Polyphosphoric Acid Salt
CAS Number: 218768-84-4
Manufacturer: [Insert Manufacturer Name, Address, Emergency Phone Number]
Recommended Use: Flame retardant in plastics, rubbers, and textiles
Supplier Contact: [Insert Supplier Details]

Hazard Identification

GHS Classification: Not classified as hazardous under GHS
Physical Hazards: Powder can become slippery, increasing fall risk in work areas
Health Hazards: May cause mechanical irritation to eyes, nose, or throat
Environmental Hazards: Slightly harmful to aquatic life with long lasting effects
Label Elements: No universally required pictograms, hazard or precautionary statements, precaution should always be observed

Composition / Information on Ingredients

Main Component: Melamine Polyphosphate
Chemical Identity: Melamine Phosphate-based polymer
Concentration Range: >98% by weight
Impurities: Possible traces of unreacted melamine, phosphoric acid, water (<2%)
CAS Number for Melamine: 108-78-1
CAS Number for Phosphoric Acid: 7664-38-2

First Aid Measures

Inhalation: Remove patient to fresh air, monitor breathing. Seek medical attention if symptoms linger.
Skin Contact: Wash area thoroughly with soap and water; remove contaminated clothing. If irritation continues, contact a doctor.
Eye Contact: Rinse immediately with plenty of water for at least 10 minutes, holding eyelids open. Don’t rub.
Ingestion: Rinse mouth thoroughly, do not induce vomiting. Get medical help if discomfort persists.

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide.
Unsuitable Extinguishing Media: Avoid direct stream of water on molten material.
Specific Hazards: Thermal decomposition can release toxic gases such as nitrogen oxides, phosphorus oxides, ammonia.
Special Protective Equipment: Firefighters should wear self-contained breathing apparatus, chemical-resistant suit.
Advice for Firefighters: Cool exposed containers with water spray to reduce pressure buildup.

Accidental Release Measures

Personal Precautions: Use PPE including dust mask and chemical resistant gloves; avoid breathing dust, provide ventilation.
Environmental Precautions: Prevent entry into waterways, drains, and soil. Collect spillage for disposal.
Cleanup Methods: Scoop up mechanically, avoid creating dust. Collect in labeled containers, wash area with water after cleanup.

Handling and Storage

Handling: Use in well-ventilated spaces. Wear appropriate gloves, safety glasses, and dust mask. Prevent dust buildup. Wash hands after use.
Storage: Keep container tightly closed in a dry, cool, well-ventilated place. Store away from strong acids, alkalis, food and feedstuffs. Avoid humidity; material may cake or degrade if exposed to moisture.

Exposure Controls and Personal Protection

Engineering Controls: Install local exhaust ventilation. Use dust collection systems if possible.
Personal Protection: Use safety goggles, chemical-resistant gloves, approved dust mask (N95 or equivalent). Wear work clothes that cover skin.
Hygiene Measures: Do not eat, drink, or smoke during handling. Wash thoroughly after handling.
Exposure Limits: No OSHA or ACGIH exposure limits specific to MPP, but general nuisance dust limits apply (OSHA PEL: 15 mg/m³ total dust, ACGIH TLV: 10 mg/m³ inhalable particulates)

Physical and Chemical Properties

Appearance: White to off-white powder
Odor: Odorless
Odor Threshold: Not applicable
pH: Slightly acidic in water (pH 5.5–7.0 for 10% solution)
Melting Point: Not determined (Decomposes before melting)
Boiling Point / Range: Not applicable
Flash Point: Not applicable
Evaporation Rate: Not applicable
Flammability: Non-flammable
Vapor Pressure: Not applicable
Density: 1.6–1.8 g/cm³
Solubility in Water: Practically insoluble
Partition Coefficient (n-octanol/water): Not determined
Decomposition Temperature: >300°C
Viscosity: Not applicable

Stability and Reactivity

Chemical Stability: Stable at ambient temperatures and normal storage conditions.
Reactivity: No dangerous reactions under normal processing.
Incompatible Materials: Strong acids, strong alkalis, oxidizing agents
Hazardous Decomposition Products: Nitrogen oxides, phosphorus oxides, ammonia gases released at high temperature
Polymerization: No hazardous polymerization

Toxicological Information

Potential Routes of Exposure: Inhalation, skin and eye contact, ingestion
Acute Health Effects: May cause mild mechanical irritation, especially in dust form; no severe acute effects demonstrated in animal studies
Chronic Effects: Chronic exposure to dust may aggravate respiratory conditions; no known carcinogenicity, mutagenicity or teratogenicity
LD50 (oral, rat): >2,000 mg/kg
Skin Corrosion/Irritation: Not corrosive; repetitive exposure could cause dryness
Eye Damage/Irritation: May produce temporary irritation
Sensitization: Not expected to cause skin or respiratory sensitization

Ecological Information

Ecotoxicity: Slightly harmful to aquatic organisms; generally immobile in soil
Persistence/Degradability: Product shows low biological degradability, tends to persist in the environment
Bioaccumulation Potential: Low
Mobility in Soil: Low mobility due to poor water solubility
Other Adverse Effects: No ozone depletion or photochemical ozone creation potential reported

Disposal Considerations

Waste Treatment Methods: Collect all waste material in suitable containers and dispose of as non-hazardous chemical waste in accordance with local, regional, national, and international regulations.
Contaminated Packaging: Empty bags or containers should be triple rinsed before recycling or disposal.
Other Disposal Recommendations: Do not discharge into drains, surface water, or groundwater. Consider incineration if suitable facilities exist.

Transport Information

UN Number: Not regulated for transport
Proper Shipping Name: Not classified as dangerous goods
Transport Hazard Class: None
Packing Group: None
Marine Pollutant: No
Special Precautions: Avoid dust generation during transport, keep dry

Regulatory Information

Global Inventories: Listed or exempt from listing on major chemical inventories (TSCA, EINECS/ELINCS, China IECSC, Japan ENCS, Korea KECI)
OSHA Status: Not regulated as hazardous
DSL/NDSL (Canada): Listed
REACH Status (Europe): Exempted use as polymer
SARA Title III (USA): Not listed
State Regulations: Not listed on California Proposition 65 or Massachusetts Right to Know
Other Regulations: Observe all national and local workplace safety regulations regarding chemical dust and safe storage