Material Safety Data Sheet: Monopotassium Phosphate (MKP), Food Grade

1. Identification

Product Name: Monopotassium Phosphate, Food Grade (MKP)
Chemical Formula: KH2PO4
CAS Number: 7778-77-0
Synonyms: Potassium dihydrogen phosphate, MKP
Recommended Use: Food additive, fertilizer, nutrient source
Supplier: [Insert company information here]
Emergency Contact: [Insert local emergency number]

2. Hazard Identification

Classification: Not classified as hazardous according to GHS criteria
Signal Word: None
Hazard Statements: May cause mild eye and skin irritation with prolonged exposure
Pictograms: Not required
Precautionary Statements: Avoid inhaling dust, wash hands after handling, maintain good ventilation when working with powder

3. Composition / Information on Ingredients

Chemical Name: Monopotassium Phosphate
Common Name: MKP
CAS Number: 7778-77-0
PERCENTAGE: >99% for food grade quality
Impurities: Trace minerals and metal ions (below regulatory thresholds for food applications)

4. First Aid Measures

Inhalation: Move person to fresh air, seek medical advice if symptoms such as coughing or shortness of breath develop
Skin Contact: Wash skin with soap and water, remove contaminated clothing
Eye Contact: Rinse thoroughly with water for several minutes, remove contact lenses if present and easy to do, get medical attention if irritation persists
Ingestion: Rinse mouth with water, give small amount of water to drink, seek medical attention if feeling unwell
Notes for Physician: Treat symptomatically, monitor electrolyte levels

5. Fire-Fighting Measures

Flammability: Non-flammable
Explosion Risk: Product not explosive
Extinguishing Media: Use appropriate media for surrounding fire (water, dry powder, foam, carbon dioxide)
Special Hazardous Products: Heated product may release phosphorus oxides
Protective Equipment: Firefighters wear suitable protective clothing and self-contained breathing apparatus

6. Accidental Release Measures

Personal Precautions: Avoid dust formation, use protective gloves and goggles
Environmental Precautions: Prevent large amounts from entering waterways, sweep up spills to avoid slip hazard
Methods for Clean-Up: Collect spills using a clean, dry shovel or vacuum cleaner with HEPA filter, place in labeled containers for reuse or disposal, flush residue with plenty of water

7. Handling and Storage

Handling: Minimize dust generation, handle in well-ventilated areas, wear suitable protective equipment
Storage: Store in tightly sealed containers, keep in dry, cool area away from strong acids and alkalis, avoid exposure to moisture, store away from incompatible substances to prevent contamination
Specific Use: Follow food safety protocols, keep food grade product segregated from industrial chemicals

8. Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific limit set for MKP; use general particulate limits
Engineering Controls: Use local exhaust ventilation for dusty situations
Personal Protection Equipment: Safety glasses, gloves, dust mask or respirator for dusty work, change contaminated clothing promptly, maintain good workplace hygiene by washing hands and arms after use

9. Physical and Chemical Properties

Appearance: White crystalline powder or granules
Odor: Odorless
Molecular Weight: 136.09 g/mol
Solubility: Highly soluble in water, forms a clear solution
pH (1% solution): Around 4.3-4.7
Melting Point: Decomposes above 252°C
Density: 2.34 g/cm³
Other: Hygroscopic, may cake if exposed to high humidity

10. Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: May react with strong acids to produce heat and phosphoric acid, avoid strong oxidizers and alkalis
Hazardous Polymerization: Will not occur
Hazardous Decomposition Products: Phosphorus oxides, potassium compounds on strong heating

11. Toxicological Information

Acute Toxicity: Low toxicity; oral LD50 (rat) >2000 mg/kg
Potential Health Effects: May cause transient irritation to eyes, skin, respiratory tract
Chronic Exposure: Large or repeated ingestion could affect mineral balance, rare in normal food use
Sensitization: No evidence of allergic or sensitizing effects
Carcinogenicity: Not listed as carcinogenic
Mutagenicity / Reproductive Toxicity: No evidence in studies

12. Ecological Information

Ecotoxicity: Not considered acutely toxic to aquatic or terrestrial organisms at typical dilution levels
Persistence and Degradability: Dissolves readily in water, partakes in natural phosphate cycle
Bioaccumulation: Not expected to bioaccumulate
Mobility in Soil: High, readily leaches to groundwater in large spills
Other Information: Nutrient enrichment from large discharges can lead to algal blooms (eutrophication) in surface waters; advisable to minimize release into environment

13. Disposal Considerations

Disposal Methods: Reuse when possible; dispose of surplus and non-recyclable materials via licensed waste company; follow local, regional, and national regulations; avoid release to sewer or natural water bodies
Container Disposal: Rinse empty containers, recycle or dispose following local legislation
Other Recommendations: Do not incinerate with general wastes, do not allow uncontrolled release

14. Transport Information

UN Number: Not classified as dangerous for transport
Transport Hazard Class: Not regulated
Packing Group: Not applicable
Proper Shipping Name: Monopotassium Phosphate
Environmental Hazards: No significant hazard in packaged form; prevent bulk releases during transport
Special Precautions for Transport: Store dry, protect from moisture, ensure containers are secure and correctly labeled

15. Regulatory Information

Food Additive Status: Approved by FDA and EFSA for use in food at specified levels
OSHA (US): No specific requirements as it does not possess major health risks under normal use
REACH (EU): Registered for manufacture and use in European Union
Other Specific Regulations: Compliant with Codex Alimentarius and JECFA food additive standards, not listed under US CERCLA, SARA Title III, or TSCA restrictions for food applications
Workplace Marking: Follow national workplace safety guidelines for chemical labeling and safety data communication