Material Safety Data Sheet (MSDS) – Monopotassium Phosphate (MKP)

1. Identification

Product Name: Monopotassium Phosphate (MKP)
Chemical Formula: KH2PO4
Common Synonyms: Potassium dihydrogen phosphate, potassium phosphate monobasic
CAS Number: 7778-77-0
Recommended Use: Fertilizer, food additive, buffering agent for industrial and laboratory processes
Supplier: [Supplier’s contact details typically here, such as address, emergency phone number, fax, and email address for specific inquires or emergencies]
Emergency Contacts: [Local emergency response or poison control center phone numbers]

2. Hazard Identification

GHS Classification: Eye Irritant Category 2A, Skin Irritant Category 3
Signal Word: Warning
Hazard Statements: Causes moderate eye irritation, may cause slight skin irritation with prolonged or repeated contact, not highly toxic
Pictograms: Exclamation mark (for irritation)
Precautionary Measures: Avoid dust inhalation, prevent eye and skin contact, keep away from food and beverages

3. Composition / Information on Ingredients

Main Component: Monopotassium Phosphate
Percentage: ≥99%
Impurities: Trace amounts of sodium, calcium, or magnesium compounds (usually below 1%)
Additives: None reported

4. First Aid Measures

Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present, continue rinsing, seek medical attention if irritation persists
Skin Contact: Wash with plenty of soap and water, remove contaminated clothing, medical advice if irritation develops
Inhalation: Move to fresh air, provide oxygen if breathing is difficult, seek medical advice if symptoms persist
Ingestion: Rinse mouth thoroughly, drink water, seek medical advice if symptoms develop, do not induce vomiting unless instructed by medical personnel

5. Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical powder, carbon dioxide
Unsuitable Media: No specific restrictions known
Combustion Hazards: Product does not burn, may release irritating or toxic fumes (phosphorus oxides, potassium oxides) when heated to decomposition
Protective Equipment: Firefighters should wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes
Special Procedures: Avoid water runoff, cool containers with water mist to prevent pressure build-up

6. Accidental Release Measures

Personal Protection: Wear gloves, goggles, dust mask or respirator, avoid dust generation
Spill Clean-Up: Sweep up spilled material gently to avoid dust, collect in a suitable container, ventilate area
Environmental Protection: Prevent material from entering water systems or drains, report large spills to local authorities as required
Disposal Method: Place recovered material in authorized landfill or waste disposal facility

7. Handling and Storage

Handling: Use in a well-ventilated area, avoid creating or breathing dust, wash hands after working with the product, keep containers tightly closed when not in use, use appropriate PPE
Storage Requirements: Store in a cool, dry, well-ventilated area, keep away from moisture, incompatible substances (strong oxidizers), keep away from food and drink, store in original labeled containers, protect containers from damage

8. Exposure Controls and Personal Protection

Occupational Exposure Limits: No established OSHA or ACGIH exposure limits for MKP dust; general nuisance dust limits may apply (10 mg/m³ total dust, 3 mg/m³ respirable dust)
Engineering Controls: Local exhaust ventilation, dust collection systems for handling large quantities, process enclosure
Personal Protection: NIOSH-approved dust mask or respirator for dusty conditions, safety glasses with side shields, chemical-resistant gloves, antistatic work clothes
Hygiene Measures: Wash hands before eating or drinking, remove contaminated clothing and wash before reuse, keep food and drinks away from work area

9. Physical and Chemical Properties

Appearance: White crystalline powder or granules
Odor: Odorless
Solubility: Easily soluble in water
pH (1% solution): Slightly acidic, around pH 4.2–4.7
Boiling Point: Decomposes before boiling
Melting Point: ~252 °C (decomposes)
Density: ~2.34 g/cm³ at 20°C
Vapor Pressure: Not applicable
Explosion Properties: Not explosive
Oxidizing Properties: Does not have oxidizing properties
Flash Point: Not applicable (inorganic solid)

10. Stability and Reactivity

Stability: Stable under recommended handling and storage conditions
Incompatible Materials: Strong oxidizers, bases
Decomposition Products: Produces potassium oxides and phosphorus oxides at high temperatures
Hazardous Polymerization: Does not occur

11. Toxicological Information

Acute Toxicity: Low oral toxicity, LD50 (rat) estimated at >5,000 mg/kg
Skin Contact: May cause mild irritation after prolonged contact
Eye Contact: May cause irritation
Inhalation: High airborne concentrations may irritate nose, throat, respiratory tract
Chronic Effects: No reported long-term human health effects from repeated or chronic exposures
Carcinogenicity: Not listed by IARC, NTP, OSHA as a carcinogen
Mutagenicity & Teratogenicity: No known genetic or reproductive toxicity

12. Ecological Information

Ecotoxicity: Not expected to be toxic to aquatic life at low concentrations, excessive release can cause eutrophication in water bodies
Persistence & Degradability: Product dissolves and dissociates in water, natural components (potassium and phosphate) are common nutrients in the environment
Bioaccumulation Potential: Not expected to bioaccumulate or magnify in food chains
Mobility in Soil: Highly soluble, moves easily in soil and water, may contribute to phosphorus enrichment in surface waters
Other Effects: High concentration in waterways can lead to algae blooms and oxygen depletion in aquatic environments

13. Disposal Considerations

Waste Disposal Methods: Reuse uncontaminated product where possible, for waste and contaminated residues consult local, state, national regulations
Packaging Disposal: Clean emptied packaging before reuse or recycling, dispose of in approved landfill or by incineration as appropriate
Environmental Precautions: Prevent large releases to surface waters, contain spills, consult authorities before draining into sewer or watercourses
Special Considerations: Do not combine with incompatible wastes, keep waste segregated

14. Transport Information

UN Number: Not classified as dangerous goods for transport
Proper Shipping Name: Monopotassium Phosphate
Transport Hazard Class: Not regulated
Packing Group: Not regulated
Special Precautions: Ensure containers are secure and protected from moisture and rough handling during transport, label containers with appropriate product identification and hazard information

15. Regulatory Information

TSCA (Toxic Substances Control Act): Listed
REACH Status: Pre-registered or registered in the EU
Canadian DSL: Listed
WHMIS Classification: Not classified as hazardous
Inventory Listings: On most international inventories (Australia AICS, Japan ENCS, China IECSC, Korea ECL)
SARA Title III: Not a hazardous substance under Sections 302, 304, 313
Other National or Local Requirements: User must review local and national regulations regarding chemical handling, labeling, environmental discharge, and occupational health