Material Safety Data Sheet (MSDS) – Textile Non-Durable Flame Retardant

Identification

Product Name: Textile Non-Durable Flame Retardant
Chemical Family: Inorganic phosphate and ammonium salt blend
Product Use: Treatment of textiles to add flame resistance
Supplier: XYZ Chemical Solutions, 101 Mill Road, City, State, ZIP
Emergency Contact: 24-hour hotline: 1-800-555-0199
Synonyms: Temporary Flame Retardant Solution, Wash-Off FR Agent
CAS Number: Mixture (see composition section)

Hazard Identification

GHS Classification: Eye irritation (Category 2A), Skin irritation (Category 3), Acute toxicity oral (Category 5), Not classified as carcinogenic
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, may cause mild skin irritation, harmful if swallowed in large amounts
Pictograms: Exclamation mark symbol
Precautionary Statements: Avoid eye contact, wash hands thoroughly after use, do not ingest, keep away from food and drink, use only in ventilated spaces
Potential Health Effects: Eyes: burning, redness, watering. Skin: dryness, irritation on repeated contact. Inhalation: No significant vapors at room temperature. Ingestion: nausea, vomiting at high doses.

Composition / Information on Ingredients

Ammonium Polyphosphate: 40%-55% (CAS: 68333-79-9)
Tetrakis(Hydroxymethyl) Phosphonium Sulfate: 20%-30% (CAS: 55566-30-8)
Water: 20%-30% (CAS: 7732-18-5)
Minor Additives / Wetting Agents: 1%-3% (proprietary, non-hazardous)
Contaminants: No known hazardous impurities present

First Aid Measures

Inhalation: Remove to fresh air, keep comfortable, and get medical advice if symptoms develop
Skin Contact: Wash with plenty of soap and water, remove contaminated clothing, seek medical attention if irritation persists
Eye Contact: Rinse carefully with water for at least 15 minutes, keep eyelids apart, remove contact lenses, get medical help if irritation continues
Ingestion: Rinse mouth with water, drink a small amount of water, do not induce vomiting, seek medical attention
Recommendations for Medical Personnel: Treat symptoms, consider splashing and ingestion risks for airway and digestive tract

Fire-Fighting Measures

Suitable Extinguishing Media: Water fog, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: None known for the solution itself
Special Hazards from Fire: Thermal decomposition can produce irritating and potentially toxic fumes including ammonia, oxides of phosphorus, and nitrogen oxides
Protective Equipment for Firefighters: Use self-contained breathing apparatus and full protective gear
Advice: Avoid breathing mist or fumes, cool exposed containers with water, contain contaminated runoff to prevent environmental release

Accidental Release Measures

Personal Precautions: Wear gloves and eye protection, avoid bare skin and contact with eyes, avoid splashing and spills, ventilate area
Environmental Precautions: Prevent larger spills from entering drains, soil, or waterways
Containment and Cleanup: Stop leak if safe, absorb liquid with inert material (sand, soil, universal absorbent), collect in suitable containers, rinse area with plenty of water, dispose according to regulations
Notification: Report release to local authorities if required

Handling and Storage

Safe Handling: Always wear gloves, goggles, and apron, avoid direct contact, do not eat, drink, or smoke while working, wash up before breaks and after use
Technical Measures: Use in well-ventilated area, keep solutions tightly closed, handle away from incompatible materials
Storage Conditions: Store in cool, dry, well-ventilated place, keep out of reach of children and pets, protect from freezing and sun exposure
Incompatible Materials: Strong acids, alkalies, oxidizers, and combustible materials
Packaging: Store in corrosion-resistant containers clearly labeled with contents and hazard warning

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established limits for the mixture, refer to limits for component ingredients if available
Engineering Controls: Provide general or local exhaust ventilation if misting or prolonged exposure is possible
Personal Protection: Nitrile or neoprene gloves, safety goggles or shield, long-sleeved garments, boots
Respiratory Protection: Not normally needed, use mask if aerosol formed or solution is sprayed
Hygiene Measures: Do not eat, drink, or smoke during use, wash hands and face thoroughly before breaks and after handling

Physical and Chemical Properties

Appearance: Clear to slightly cloudy colorless liquid
Odor: Slight ammonia-like scent
pH: 6.5 - 8.0
Melting Point/Freezing Point: Below 0°C (can freeze)
Boiling Point: Over 100°C
Flash Point: Not flammable in liquid state
Evaporation Rate: Similar to water
Explosive Limits: Not applicable
Vapor Pressure: Negligible
Solubility: Completely soluble in water
Density: 1.10-1.30 g/cm³
Partition Coefficient: Not determined
Decomposition Temperature: Above 200°C (releases fumes)

Stability and Reactivity

Chemical Stability: Stable under normal storage and usage conditions
Reactivity: No dangerous reactions known under normal conditions
Conditions to Avoid: High temperatures, freezing, contact with strong acids or oxidizers
Hazardous Decomposition Products: Ammonia, oxides of phosphorus, irritating phosphorus compounds
Possibility of Hazardous Reactions: No polymerization, but can react with incompatible chemicals to release gases
Incompatibility: Avoid storing or mixing with bleach (hypochlorites), acids, or caustic soda

Toxicological Information

Acute Toxicity: Oral LD50 (rat) over 2000 mg/kg (for main components)
Skin Corrosion/Irritation: Prolonged or repeated contact can cause dryness and mild irritation
Serious Eye Damage/Irritation: Causes noticeable irritation, tearing, discomfort
Respiratory or Skin Sensitization: No reports of sensitization
Carcinogenicity: Not classed as a cancer risk by OSHA, IARC, or NTP
Mutagenicity: No data available for mixture, main components negative in standard tests
Other Information: Large ingestion can upset digestive tract, rarely leads to serious health effects from workplace exposure

Ecological Information

Aquatic Toxicity: Harmful in large quantities, phosphate content can contribute to algal blooms if released uncontrolled
Persistence and Degradability: Main ingredients degrade over time, but nutrient load builds up in water
Bioaccumulation Potential: Not expected to bioaccumulate
Mobility in Soil: Moves easily with water, can reach groundwater if spills are not contained
Other Adverse Effects: May impact aquatic organisms and change water chemistry if large spills enter waterways

Disposal Considerations

Product Waste: Collect in leak-proof containers, treat as chemical waste if unused, do not pour large quantities down sewers
Disposal Methods: Dispose through licensed chemical waste contractor, follow local regulations for hazardous waste, dilute small quantities with plenty of water and drain if allowed
Packaging: Rinse empty containers, recycle or dispose as required, do not reuse packaging for food or drink
Do Not: Mix with acids or strong oxidizers during disposal

Transport Information

UN Number: Not regulated as dangerous goods for road, sea, or air
Proper Shipping Name: Textile Chemical Solution, non-hazardous
Transport Hazard Class: Not classified
Packing Group: Not applicable
Environmental Hazards: Not a marine pollutant
Special Precautions: Protect containers from tipping, avoid extreme temperatures, keep tightly closed during transport

Regulatory Information

Safety, Health, and Environmental Regulations Specific for the Substance: All main ingredients listed in TSCA Inventory, not subject to SARA Title III Section 302/304/313 or CERCLA reporting requirements, ingredients generally regarded as safe under normal workplace practices
Workplace Labeling: Must display hazard warnings, personal protective equipment pictograms, and emergency procedures
Global Inventories: Components listed in EU, Canada, Australia chemical inventories
Other Regulations: Not classified as hazardous waste under RCRA, not listed as a California Prop 65 chemical