Product Name: Piperazine Pyrophosphate Blend
Common Names: Flame Retardant Additive, Piperazine Salt Blend
Synonyms: PAPP Blend
Manufacturer: [Insert Manufacturer’s Name]
Emergency Contact: [Insert Emergency Number]
Recommended Use: Flame retardant applications in plastics, textiles, coatings
Hazard Class: Acute Toxicity (Oral, Dermal), Skin Irritation, Eye Damage
Signal Word: Warning
Pictograms: Exclamation mark, Health hazard
Hazard Statements: May cause skin and eye irritation, harmful if swallowed, may cause respiratory irritation on inhalation
Precautionary Statements: Wear protective gear, avoid breathing dust, wash hands after handling, do not eat or drink while using the product
Chemical Name: Piperazine Pyrophosphate
CAS Number: 66034-17-1
Concentration: 85-95%
Other Ingredients: Stabilizers and processing aids (proprietary, up to 15%), trace impurities may include ammonia salts, phosphate compounds
Inhalation: Move victim to fresh air, keep at rest, seek medical help if coughing or irritation persists
Skin Contact: Remove contaminated clothing, wash affected skin with soap and water, see a doctor for persistent irritation
Eye Contact: Rinse thoroughly with water for at least 15 minutes, remove contact lenses, seek immediate medical attention
Ingestion: Rinse mouth, do not induce vomiting, drink water if conscious, call poison control or a healthcare provider as soon as possible
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Fire Hazards: Product can emit hazardous phosphorus oxides, nitrogen oxides, and ammonia fumes on burning
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing
Special Procedures: Cool exposed containers with water, keep run-off out of water sources and sewers
Personal Precautions: Avoid dust, ventilate area, wear gloves, goggles, and dust mask
Environmental Precautions: Prevent contamination of waterways, do not let material enter drains
Spill Cleanup Methods: Use shovel or vacuum to collect material, place in sealed containers, sweep up and avoid generating dust, dispose in accordance with local regulations
Handling: Use in well-ventilated areas, avoid contact with skin and eyes, do not inhale dust, avoid eating and drinking during handling
Storage: Store in a dry, cool, well-ventilated space, keep containers tightly closed, separate from incompatible chemicals like strong acids and oxidizers, keep away from food and animal feed
Engineering Controls: Local exhaust ventilation, enclosed handling systems tested for dust emissions
Occupational Exposure Limits: None established for blend; recommended as nuisance dust 10 mg/m³ (total), 5 mg/m³ (respirable)
Respiratory Protection: Approved dust mask or respirator when dust forms
Skin Protection: Nitrile gloves, protective sleeves or apron
Eye Protection: Safety goggles or face shield
Hygiene Measures: Wash hands and face before eating or drinking, immediately remove contaminated clothing and wash before reuse
Appearance: White crystalline powder or granules
Odor: Mild ammonia-like
Odor Threshold: Not available
pH (1% Solution): 6.5-7.5
Melting Point: Decomposes above 300°C
Boiling Point: Not applicable (decomposes on heating)
Flash Point: Not flammable
Solubility: Low in water, soluble in dilute acids
Vapor Pressure: Negligible at room temperature
Relative Density: 1.4–1.6 g/cm³
Chemical Stability: Stable under ordinary conditions
Reactivity: Reacts with strong acids to produce toxic gases
Hazardous Decomposition Products: Ammonia, phosphorus oxides, nitrogen oxides
Incompatible Materials: Strong acids, oxidizing agents, strong bases
Polymerization: No hazardous polymerization expected
Acute Toxicity: Oral LD₅₀ (rat): >2000 mg/kg (low toxicity); skin contact may cause irritation
Chronic Effects: No evidence of carcinogenic or mutagenic activity in available studies
Skin Irritation: May trigger redness or rash with prolonged contact
Eye Irritation: Causes moderate to severe irritation
Respiratory Effects: Repeated inhalation of dust can irritate nose and throat, high exposure may cause headaches
Aquatic Toxicity: Not expected to bioaccumulate, limited mobility in soil due to low solubility
EC50 (Aquatic Invertebrates): >100 mg/L (low hazard classification)
Degradability: Breakdown pathways in the environment not fully studied, expected to persist in soil for some time
Other: Large spills may pose a risk to aquatic life from changes in water pH, avoid runoff into surface waters
Waste Disposal: Follow local, state, and federal laws, deposit in licensed landfill or incinerate at approved facility
Empty Containers: Triple rinse, puncture and dispose of as industrial waste
Special Precautions: Do not release to environment, do not allow to enter sewage or drains
UN Number: Not regulated for road, rail, air, or sea
Transport Hazard Class: Not a hazardous material
Packing Group: Not applicable
Label: None required for transport
Special Transport Precautions: Keep container sealed and dry, avoid rough handling that could release dust
US Regulations: TSCA (Toxic Substances Control Act) listed, SARA Title III not listed
EU Regulations: Not classified as hazardous under CLP Regulation
Other International: Not subject to Montreal Protocol, Rotterdam Convention, or Stockholm Convention
Workplace Safety: Subject to local occupational health and safety regulations, check with regional requirements for storage and use
