Piperazine Pyrophosphate Mflam 1420 – Full Material Safety Data Sheet Overview

Identification

Product Name: Piperazine Pyrophosphate Mflam 1420
Chemical Family: Nitrogen-phosphorus compound
Recommended Use: Flame retardant for plastics and resins
Synonyms: Mflam 1420, Piperazine polyphosphate
Manufacturer: Contact supplied distributor or manufacturer for details
Supplier Contact: Locate emergency phone found on product packaging or technical datasheet
CAS Number: 68611-50-7
UN Number: Not regulated for ground transportation
Emergency Contact Number: Local supplier, regional poison control, or emergency response line

Hazard Identification

Classification: Not classified as hazardous under GHS; product may irritate eyes, skin, respiratory system in bulk powder form
Physical Dangers: Dust from powder may trigger mild respiratory or mucous membrane irritation
Health Risks: Overexposure through inhalation could cause coughing and short-term discomfort; extended skin contact might result in mild rash or redness
Environmental Impact: Large releases may be damaging in aquatic environments
Pictogram: No GHS pictograms; use general caution signage in handling/storage areas
Label Elements: Avoid breathing dust, wash exposed skin, use only with adequate ventilation

Composition / Information on Ingredients

Chemical Formula: C4H10N2·H4P2O7
Main Compound: Piperazine Pyrophosphate, 98–100% by weight
Other Components: Unreacted pyrophosphate, minor ammonium salts, trace moisture
Impurities: No major hazardous impurities present
CAS Registry Numbers: Principal compound 68611-50-7
Hazardous Ingredients: None listed under current regulatory classification

First Aid Measures

Inhalation: Move exposed individual to fresh air, support breathing, rinse mouth if any dust inhaled
Skin Contact: Wash area thoroughly with plenty of water, remove contaminated clothing, seek care if irritation persists
Eye Contact: Rinse eyes gently with running water; hold eyelids open, continue flush for minimum 15 minutes, remove contact lenses if worn
Ingestion: Rinse mouth, encourage water intake; do not induce vomiting unless instructed by medical professional
Medical Attention: Seek medical help for persistent cough, rash, visual changes, or if large quantities are inhaled or ingested

Fire-Fighting Measures

Suitable Extinguishers: Use foam, dry powder, water spray, or CO2; avoid direct high-pressure hoses
Combustion Hazards: May release toxic phosphorus oxides, ammonia, and nitrogen oxides at high temperatures
Firefighting Gear: Full protective equipment, including self-contained breathing apparatus recommended
Special Procedures: Avoid breathing smoke or vapors, contain runoff from fire control water
Flammability: Product formulated as a fire retardant, does not readily burn, may char at temperatures over 220°C

Accidental Release Measures

Spill Cleanup: Ventilate area as much as possible, sweep or vacuum up powder, use non-sparking tools, avoid creating dust clouds
Personal Protection: Protective gloves, goggles, disposable mask for fine powders
Environmental Protection: Do not wash into drains or open waterways; collect spilled product in labeled waste containers
Decontamination: Surfaces can be cleaned with water and mild detergent, followed by thorough drying
Disposal of Residues: Store washings and debris for safe disposal as per disposal considerations below

Handling and Storage

Handling Procedures: Handle in areas with adequate ventilation, use minimal amount to reduce dust, avoid eating or drinking near open packages
Personal Hygiene: Wash hands before breaks and after contact, remove contaminated clothing, avoid touching face or eyes
Storage Conditions: Store sealed in dry, cool, well-ventilated space, away from incompatible substances like strong acids, oxidizers
Container Requirements: Keep in original packaging or tightly closed container, ensure labeling remains visible
Compatibility: Keep away from sources of high heat or open flames, check local guidelines for container storage recommendations

Exposure Controls and Personal Protection

Exposure Limits: No published occupational exposure limits; control dust to lowest practicable level
Engineering Controls: Use exhaust ventilation, local dust extraction, or enclosures for powder handling
Protective Equipment: Safety goggles or glasses, chemical-resistant gloves (nitrile or neoprene suggested), disposable dust mask (P2 or better) if dusting occurs
Work Practices: Do not consume food or beverages or smoke where handling product, use hand-washing facilities nearby
Environmental Controls: Install collecting pans and spill barriers for large storage areas, ensure no product enters public drains or soil

Physical and Chemical Properties

Appearance: White, fine, free-flowing powder
Odor: Odorless or very faint, non-specific smell
Solubility: Slight solubility in water, forms colloidal suspension
Melting Point: Starts above 200°C with slow decomposition
Boiling Point: Not applicable (decomposes before boiling)
Flash Point: Not flammable
Explosive Limits: No explosive properties detected
Density: 1.3–1.5 g/cm³
pH (5% Suspension): 6–8
Vapor Pressure: Negligible at room temperature
Stability: Stable in normal shipping and storage conditions
Viscosity: Not relevant for solid powder
Partition Coefficient: Not established, likely low environmental mobility

Stability and Reactivity

Chemical Stability: Maintains form under normal storage and transport
Conditions to Avoid: Prolonged exposure to strong heat, strong acids or oxidizers
Hazardous Reactions: Will not polymerize, may slowly hydrolyze in presence of excess water and high temperature
Decomposition Products: Ammonia, phosphorus oxides, nitrogen oxides on burning or charring above 220°C
Incompatibles: Strong acids, alkali, oxidative chemicals, avoid mix with peroxides or strong bases
Shelf Life: Can stay effective for years if kept in original, dry packaging under ambient conditions

Toxicological Information

Acute Oral Toxicity: Low toxicity; estimated LD50 (oral, rat) greater than 2000 mg/kg
Acute Dermal Toxicity: Low risk of harm through skin absorption
Inhalation Risks: May irritate if dust levels rise; symptoms may include mild coughing, sneezing, discomfort
Chronic Effects: No evidence of skin sensitization or chronic organ toxicity with intended use patterns
Carcinogenicity: Product does not contain listed carcinogens in IARC, NTP, OSHA indices
Mutagenicity: Negative results in standard mutagenicity studies
Other Information: Avoid excessive dust and minimize long-term contact; always use sensible personal hygiene after exposure

Ecological Information

Eco-Toxicity: Mildly toxic to aquatic animals if large spill enters waterways, low bioaccumulation risk
Persistence/Degradability: Gradual mineralization; slow breakdown under sunlight and microbial action
Mobility in Soil: Limited movement, tends to stay bound in upper soil layers
Aquatic Impact: Avoid bulk discharges, finely suspended powder can persist and increase turbidity
BOD/COD: No significant oxygen demand in water systems
Bioaccumulation: Does not concentrate in living organisms
Summary: Use spill control to prevent entry into environment, follow local environmental protection rules

Disposal Considerations

Waste Handling: Collect in tightly sealed, correctly labeled containers for disposal
Methods: Preferred method is controlled incineration or landfill under guidance of local authorities
Packaging Disposal: Empty containers may contain traces; clean before recycling or dispose as chemical waste
Regulatory Considerations: Review and follow community regulations; do not dump in municipal waste streams or surface water
Unused Material: Ship by approved hazardous waste handlers if in bulk or unused form, avoid mixing with incompatible chemicals

Transport Information

UN Number: No assigned UN number for standard land shipment
ADR/RID/IMDG/IATA: Not classified as dangerous goods
Hazard Label: Not required, powder may be shipped as non-hazardous cargo
Handling Requirements: Avoid rough handling of bags or drums, double-check closures before moving
Shipping Practices: Check packaging integrity on arrival, report leaks or dust seen in transport container
Local Restrictions: Check for local shipping advisories if moving internationally

Regulatory Information

TSCA Status: Included on US EPA TSCA Inventory
REACH Compliance: Registered under European REACH legislation
OSHA Status: Not regulated under specific sections, follow general safe chemical handling practices
Canada DSL: Listed or notified
EU Labeling: Product exempt from classification under Regulation EC 1272/2008
Other Regional Listings: Japan ENCS, Australia AICS, Korea ECL, China IECSC – all present
Workplace Control: Not subject to specific control measures beyond basic chemical hygiene laws