Product Name: PIPP Flame Retardant for Elastomer
Chemical Family: Phosphorus-nitrogen-based flame retardant
Other Names: None
Recommended Use: Additive for rubber and plastic applications requiring higher ignition tolerance
Supplier: Manufacturer’s name, address, and emergency contact phone number, with detail for around-the-clock incident consultation
CAS Number: Provided by the specific manufacturer
Product Code: Reference on packaging or datasheet
Emergency Contact: National Poison Center, local agency number, or in-house emergency number
Date Prepared: Most recent MSDS revision date, included for reference and tracking
Restrictions on Use: Not suitable for other than industrial and specified polymer blending
GHS Classification: Eye irritation Category 2B, Skin sensitization Category 1, Specific target organ toxicity (single exposure) Category 3
Signal Word: Warning
Hazard Statements: Causes eye and skin irritation, may cause allergic skin reaction, may cause temporary respiratory irritation
Pictograms: Exclamation mark
Precautionary Statements: Avoid breathing dust, wash thoroughly after handling, wear protective gloves and eye protection, dispose of in accordance with regulations
Potential Health Effects: Short-term exposure may cause mild respiratory discomfort; skin contact produces mild irritation; ingestion unlikely during intended use, but possible mild nausea
Physical Hazards: Product forms combustible dust in high concentrations; care required to avoid sources of ignition; chemical stability maintained under normal conditions
Environmental Hazards: May affect aquatic organisms if large quantities enter waterways; not persistent, but acute exposure possible if improperly disposed
Medical Conditions Aggravated: Individuals with pre-existing skin allergies or asthmatic symptoms can experience heightened reaction
Main Ingredient: Phosphorus-nitrogen complex, proprietary formula
CAS Number: Confers with major suppliers for regulatory listings
Weight Percentage: Major constituent 80–90%; secondary synergists 5–10%; inert carriers and coating agents 1–5%
Impurities: Contains no known hazardous impurities above threshold reporting values
Other Ingredients: Blend of surface stabilizers, minor organic facilitating agents, and moisture scavengers
Trade Secret Claims: Formulation protected under applicable trade secret guidelines; full ingredient list available to medical personnel upon request under confidentiality agreement
Inhalation: Remove affected person to fresh air; seek medical attention if persistent coughing or difficulty in breathing is observed
Skin Contact: Remove contaminated clothing, wash skin thoroughly using soap and water; medical advice for persistent irritation
Eye Contact: Rinse cautiously with lukewarm water for several minutes; remove any contact lenses; consult healthcare professional if irritation lingers
Ingestion: Rinse mouth with water; do not induce vomiting unless directed by medical provider; obtain medical advice if substantial amount ingested
Most Important Symptoms: Redness, itching, mild burning of skin or eyes, possible allergic reaction on repeated exposure
Medical Advice: Available safety data and ingredient list can be provided to attending physician; symptomatic treatment recommended
Suitable Extinguishing Media: Dry chemical, carbon dioxide, water spray, foam
Unsuitable Extinguishing Media: High-pressure water jets may spread dust and fire
Special Hazards: Combustion produces toxic fumes including phosphorus oxides and nitrogen oxides
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Explosion Sensitivity: Product dust can generate explosive mixtures in air if dispersed and ignited; avoid dust accumulation
Firefighting Instructions: Control runoff water to prevent environmental contamination; cool adjacent containers to prevent pressurization
Personal Precautions: Avoid breathing dust; ventilate area; use recommended personal protective equipment
Environmental Precautions: Prevent product from entering soil, drains, waterways; notify regulatory authorities of significant spills
Cleanup Methods: Sweep up gently to minimize dust formation; place in sealable, labeled containers for disposal; wash area with water after removal
Handling Spills: Wear impervious gloves, goggles, and dust mask; avoid dry sweeping that stirs up particles
Disposal of Waste: Dispose in accordance with local, regional, and national guidelines for hazardous chemical waste
Handling: Always transfer and blend in areas with adequate ventilation; wear gloves and eye protection; keep away from ignition sources, hot work, and open flames
Storage: Store in cool, dry, well-ventilated location; use original, tightly closed containers; avoid direct sunlight, moisture, and incompatible materials such as strong oxidizing agents
Minimum Storage Temperature: Ambient conditions suffice; avoid freezing or extreme heat
Incompatibility: Oxidizers and strong acids
Storage Life: Product remains stable for several years if stored properly, with shelf-life date provided by supplier
Special Provisions: Adequate signage, access to MSDS, separation from food and feed storage
Occupational Exposure Limits: No OSHA PEL; recommended supplier exposure guideline is 5 mg/m³ (total dust), 1 mg/m³ (respirable dust)
Engineering Controls: Local exhaust ventilation required for manual blending; use enclosed systems wherever possible; periodic air monitoring in work area
Personal Protective Equipment: Nitrile gloves, chemical splash goggles, long sleeves, and particulate respirator in high-dust areas
Hygiene Measures: Prohibit eating, drinking, and smoking in handling areas; wash hands and change contaminated clothing after handling
Exposure Monitoring: Routine evaluation of airborne dust levels, personal exposure assessment during high-volume processing
Environmental Monitoring: Inspection of exhaust systems, dust collectors, and workplace cleanliness for efficacy and protection
Appearance: Finely-divided white to off-white powder, minimal odor
Odor: Nearly odorless with faint chemical undertone
pH: Slightly acidic to neutral (5.0–7.0 in 10% suspension)
Boiling Point: Not applicable (solid compound)
Melting Point: Above 180°C, depending on formulation
Decomposition Temperature: Releases active phosphorus vapors above 220°C
Vapor Pressure: Negligible at ambient temperature
Density: 1.4–1.6 g/cm³
Solubility: Insoluble in water but dispersible in polymer melts
Flash Point: Over 250°C
Auto-Ignition Temperature: Not determined
Evaporation Rate: Not applicable (solid material)
Other Data: Stable granular form available for dust reduction purposes; does not corrode metals or degrade packaging under recommended storage
Chemical Stability: Stable under normal processing and storage conditions
Hazardous Reactions: Will not polymerize; may react with oxidizing agents; thermal decomposition above 220°C yields phosphoric and nitric oxides
Conditions to Avoid: Prolonged heating above recommended processing temperature; contact with strong acids or bases
Materials to Avoid: Strong oxidizers, concentrated acids, alkalis
Decomposition Products: Phosphorus oxides, nitrogen oxides, trace amines, ammonia
Incompatibilities: Prolonged contact with damp surfaces or reactive chemical environment can degrade product quality
Acute Toxicity: No known acute toxicity at recommended handling levels; LD50 data available from proprietary toxicology reports (typically above 2000 mg/kg oral, rat)
Chronic Effects: Prolonged or repetitive skin contact may cause dermatitis; repeated inhalation of dust may aggravate respiratory issues
Carcinogenicity: Ingredients not listed as carcinogens by IARC, NTP, OSHA
Mutagenicity: No evidence from supplier studies
Skin Sensitization: Yes in sensitive individuals
Inhalation Effects: Dust inhalation can irritate throat, nose, and upper lungs
Other Risks: Not expected to present reproductive, developmental, or systemic toxicity under normal conditions
Ecotoxicity: Minor acute effect on aquatic organisms due to phosphorus; not persistent or bioaccumulative
Degradation: Decomposes to common phosphorus and nitrogen compounds in soil and water
Mobility: Practically immobile in soil due to particulate nature; some leaching possible if improperly disposed
Bioconcentration: Unlikely due to physical properties and natural breakdown
Aquatic Toxicity: LC50 values for fish and invertebrate exposures available from test results; typically moderate in high-load exposure
Other Concerns: Avoid bulk spillage into natural water courses; minimize long-term exposure through responsible use and waste management
Waste Treatment: Collect waste in sealed containers; label as hazardous industrial chemical
Disposal Methods: Preferred method is incineration in licensed facility; landfill disposal only with regulatory approval
Contaminated Packaging: Triple rinse and send for destruction or recycling as hazardous waste
Legal Requirements: Federal, state, and local regulations for phosphorus waste and chemical by-products apply; manifesting and documentation required for bulk dispatch
Sewage Disposal: Avoid, as substances can accumulate and pose local risk to aquatic organisms; consult utility for advice
Other Measures: Encourage waste minimization, off-site reclamation, or authorized distributor take-back programs
UN Number: Refer to international shipping guidelines for phosphorus compounds
Proper Shipping Name: Flame Retardant Compound, Solid
Transport Hazard Class: Not regulated as dangerous goods by major transit authorities, but may require special labeling for dust hazard
Packing Group: Not applicable unless packaged over specific weights
Marine Pollutant: No
Special Transport Precautions: Avoid moisture ingress; protect containers from physical damage; stow away from foodstuffs and oxidizers
Label Requirements: Product, manufacturer, and emergency number must appear on all containers; special dust warning labels for large-scale shipments
TSCA Status: All components listed on the Toxic Substances Control Act inventory
SARA Sections 302/304, 311/312, 313: Not subject to specific reporting or notification
REACH: Pre-registered or fully registered as required by importer or manufacturer
WHMIS Classification: May be classified as hazardous due to dust irritation concern
California Proposition 65: No listed materials known to the State of California to cause cancer or reproductive toxicity
Labeling Requirements: Worker protection labels, hazard pictograms, and safe handling instructions must be provided in all supplied countries
Other Regulations: Compliance with relevant EPA, OSHA, and local authority requirements applies throughout supply chain and workplace
