Product Name: Polyethylene Fire Resistance Masterbatch
Chemical Family: Polyolefin blend
Recommended Use: Flame retardant additive for plastics manufacturing
Supplier: Name, address, and contact phone of supplier or manufacturer
Emergency Contact: 24-hour spill and fire response contact
Physical State: Solid pellets or granules
Color and Odor: White to off-white, faint chemical smell
Primary Hazards: Minor respiratory exposure risks from dust, irritation if handled improperly, risk of inhaling decomposed gases during fire situations
Signal Word: Caution
GHS Classification: Not classified as hazardous, but certain fire retardants can raise health alerts
Hazard Statements: Causes mild eye and skin irritation, dust may cause respiratory irritation
Polyethylene Carrier Resin: 60-80%
Fire Retardant Additives (e.g., Alumina Trihydrate, Magnesium Hydroxide, Brominated Compounds): 20-35%
Other Additives (Stabilizers, Processing Aids): up to 5%
Impurities: Trace levels below hazardous thresholds
CAS Numbers: Polyethylene 9002-88-4; Aluminum Trihydrate 21645-51-2; additional as supplied
Inhalation: Move to fresh air, seek medical help for persistent cough or discomfort
Skin Contact: Wash with soap and water, remove contaminated clothing
Eye Contact: Rinse under gentle running water for several minutes, seek help if irritation remains
Ingestion: Rinse mouth, drink water, seek medical attention for large amounts or persistent symptoms
Guidance for Medical Practitioners: Treat symptoms as presented, no specific antidote known
Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: Avoid direct streams which might spread melted polymer
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, possible halogen acids or oxides depending on fire retardant type
Special Equipment for Firefighters: Full protective gear, self-contained breathing apparatus
Additional Advice: Keep run-off out of drains and watercourses, cool closed containers exposed to fire with water
Spill Response: Sweep up spillage, avoid generating dust, transfer to suitable container for disposal
Personal Protection: Gloves, safety goggles, dust mask for dry cleanup
Environmental Precautions: Prevent product from entering drains and waterways, dispose safely
Methods of Cleanup: Mechanical collection, wash area to remove residues
Handling: Minimize dust release, use with adequate ventilation, avoid sources of heat and ignition during transfer
Safe Storage Conditions: Store in tightly closed containers, cool and dry location, away from incompatible chemicals
Avoidance: Keep away from oxidizing agents and open flames
Incompatibilities: Strong acids, oxidizers
Engineering Controls: Local exhaust ventilation at points of dust or fume generation
Personal Protective Equipment: Gloves suited for chemicals, goggles, respirators if dust exceeds limits
Occupational Exposure Limits: Polyethylene and most fillers — not assigned; specific limits apply for certain halogenated fire retardants
Hygiene Measures: Wash hands before eating, avoid smoking during use, change contaminated clothing
Appearance: Coarse granules or pellets
Color: White to grayish
Odor: Neutral to mild plastic
Melting Point: 110-140°C (depending on PE carrier)
Solubility: Insoluble in water
Specific Gravity: 1.0 to 1.7 (varies with additives)
Flash Point: Above 300°C
Decomposition Temperature: Over 250°C
Chemical Stability: Stable under recommended use and storage
Reactivity: Avoid contact with strong oxidants, acids
Hazardous Decomposition: CO, CO₂, possible acidic gases from certain flame retardants
Polymerization: Not known to occur under normal conditions
Conditions to Avoid: Excessive heat, ignition sources
Acute Toxicity: Low toxicity by inhalation, skin contact, and ingestion in typical use
Chronic Effects: Prolonged exposure to flame retardant dust may affect respiratory system
Routes of Exposure: Skin, eyes, inhalation of dust or smoke
Irritation: Low chance unless exposed to high concentrations of contaminants or hot melt
Sensitization: Not reported in typical use
Carcinogenicity: No components classified as carcinogenic in their supplied form
Other Effects: Additives like brominated compounds can produce irritation during fire
Ecotoxicity: Not acutely toxic to aquatic life in pellet form, but releases persistent plastic if spilled
Persistence and Degradability: Polyethylene structure degrades slowly, persists in environment
Bioaccumulative Potential: Can accumulate in soil and water sediment
Mobility in Soil: Generally immobile but small particles may migrate
Other Adverse Effects: Certain flame retardant additives can increase concern if released in quantity
Waste Treatment Methods: Recycle where possible, otherwise incinerate under controlled conditions or landfill according to local requirements
Container Disposal: Clean, reuse, or recycle following site protocols
Precautions for Disposal: Avoid incineration in open air to reduce toxic gas emissions
UN Number: Not regulated under most classifications for solid plastic pellets
Transport Hazard Classes: Not assigned
Packing Group: None required
Environmental Hazards in Transport: Pellet spills can create cleanup issues near water bodies
Transport Labeling: No special labeling except to mark as industrial material
Classification: Not listed as hazardous material under major international standards for solids
Inventory Status: All components typically included in chemical inventories such as TSCA, REACH, DSL
Additional Regulatory Information: Local laws may restrict use of certain flame retardants due to environmental or health concerns
Right To Know Listings: States like California may require disclosure of brominated or phosphorus compounds
Worker Protection: Training required for safe handling, spill, and disposal procedures in most industrial settings
