Product Name: Polyethylene Flame Retardant Additives
Synonyms: PE Flame Retardant Masterbatch, Brominated Flame Retardant Polyethylene Compound, Halogen-Free Flame Retardant PE Additive
Manufacturer: BlendsTech Chemical Co., Ltd.
Recommended Uses: Wire and cable insulation, plastic sheeting, pipe coating, technical textile back-coating, cable ducts, construction panels
Emergency Contact: CHEMTREC: +1-800-424-9300
Product Code: FR-PEXLCA1203
Address: 3429 Polymer Avenue, Tulsa, OK 74116, USA
GHS Classification: Eye Irritant (Category 2B), Skin Sensitizer (Category 1), Acute Oral Toxicity (Category 4), Not rated as a flammable solid
Signal Word: Warning
Hazard Statements: Causes mild eye irritation, May cause allergic skin reactions, Harmful if swallowed, May cause slight respiratory irritation
Precautionary Statements: Avoid breathing dust, Use only outdoors or in well-ventilated area, Wear protective gloves and eyewear, Wash hands thoroughly after handling, Do not eat, drink or smoke during use
Pictograms: Exclamation Mark, Health Hazard
Polyethylene Resin: 50-60% – CAS: 9002-88-4
Intumescent Flame Retardant (Ammonium Polyphosphate): 20-35% – CAS: 68333-79-9
Brominated Organic Compounds (Decabromodiphenyl Ether): 5-12% – CAS: 1163-19-5
Antimony Trioxide: 2-8% – CAS: 1309-64-4
Mineral Filler (Talc/ATH): 3-10% – CAS: 14807-96-6 / 21645-51-2
Synergist (Zinc Borate): 1-4% – CAS: 1332-07-6
Stabilizers and Lubricants: Proprietary, <1%
Inhalation: Remove to fresh air, rest in a position comfortable for breathing. Seek medical advice if symptoms persist: coughing, shortness of breath, or throat irritation.
Skin Contact: Remove contaminated clothing, rinse with plenty of water and mild soap. If redness or irritation develops, seek medical attention.
Eye Contact: Rinse cautiously with clean water for 15 minutes, hold eyelids apart to ensure thorough flushing. Seek medical care if discomfort continues.
Ingestion: Rinse mouth, drink one or two glasses of water. Do not induce vomiting except on medical advice. Call poison center or physician if large amounts swallowed or symptoms develop.
Suitable Extinguishing Media: Dry chemical, foam, water spray, carbon dioxide
Specific Hazards: Thermal decomposition releases toxic and irritating fumes such as hydrogen bromide, antimony compounds, phosphorus oxides
Protective Equipment: Self-contained breathing apparatus, full protective gear
Hazardous Combustion Products: Smoke, carbon monoxide, carbon dioxide, brominated compounds, phosphoric acid fumes
Special Instructions: Evacuate area, douse containers with water to keep cool if exposed to fire; avoid runoff to waterways
Personal Precautions: Use gloves, goggles, dust mask. Ventilate area, avoid generating dust.
Environmental Precautions: Prevent entry into drains, surface or groundwater. Notify authorities if bulk quantities enter waterways.
Methods for Cleanup: Collect material mechanically using non-sparking tools, place in closed, labeled containers for proper disposal. Use vacuum with HEPA filter for fine dust; avoid sweeping dry dust.
Waste Disposal: Dispose in accordance with local, regional, and federal regulations.
Handling: Avoid contact with skin and eyes, prevent dust formation, handle in well-ventilated spaces. Do not eat, drink, or smoke during use. Use proper lifting techniques.
Storage Conditions: Store tightly closed in a cool, dry, well-ventilated place away from ignition sources and incompatible materials (oxidizers, acids). Keep away from direct sunlight and moisture. Stack containers safely to avoid tipping.
Storage Temperature: 5–35°C (41–95°F)
Incompatible Materials: Strong acids, alkalis, oxidizing agents, ammonia-rich products
Engineering Controls: Local exhaust in processing and handling areas, process enclosure or mechanical ventilation to reduce airborne dust.
Personal Protection: Chemical-resistant gloves (nitrile, PVC), safety goggles, dust respirator (NIOSH N95 or higher), coveralls and safety boots.
Hygiene Practices: Wash hands thoroughly after use, remove contaminated clothing, shower after large exposures.
Exposure Limits: Antimony trioxide ACGIH TLV: 0.5 mg/m³ (8-hr TWA). Decabromodiphenyl ether: OSHA/NIOSH REL: 1 mg/m³.
Appearance: Off-white or light gray granules or pellets
Odor: Mild, faint chemical/plastic
pH: Not applicable (solid, not soluble in water)
Melting Point: 110–140°C (230–284°F)
Decomposition Temperature: Around 320°C (608°F)
Boiling Point: Not applicable
Flash Point: Not determined (non-volatile solid)
Solubility: Insoluble in water
Specific Gravity: 1.1–1.8 (depending on additives present)
Vapor Pressure: Negligible
Evaporation Rate: Not applicable
Chemical Stability: Stable under recommended storage and use. Not sensitive to shock.
Conditions to Avoid: Excess heat, open flames, strong oxidizing/reducing agents, moisture ingress.
Incompatible Materials: Strong acids, peroxides, alkalis, oxidizers
Hazardous Decomposition Products: Hydrogen bromide, phosphorus oxides, carbon monoxide, antimony fumes, unknown organic compounds
Polymerization: Will not occur in storage or normal handling conditions
Acute Toxicity: Oral LD50 (rat): >2,000 mg/kg (mixture), low acute toxicity but harmful if large amounts ingested
Skin Contact: May cause irritation in sensitive individuals, especially with prolonged or repeated exposure
Eye Contact: Dust particles can trigger swelling, redness, and tearing
Respiratory: Dust inhalation may aggravate allergies, asthma, respiratory illness
Carcinogenicity: Antimony trioxide listed as possible carcinogen (IARC Group 2B); decabromodiphenyl ether possible reproductive hazards in chronic exposures
Sensitization: Repeated exposure can cause skin and respiratory sensitization
Chronic Effects: Chronic inhalation of dust can impact lung function, cause cough, bronchitis
Ecotoxicity: Additives may pose toxicity to aquatic organisms, especially if significant quantities released in water bodies
Persistence and Degradability: Most flame retardants are persistent; do not biodegrade quickly, some may bioaccumulate
Mobility: Pellets and granules remain in soil and sediment
Bioaccumulation: Certain components (brominated compounds, antimony trioxide) may bioaccumulate in aquatic systems
Aquatic Toxicity: Studies note LC50 values for aquatic species in low mg/L range for some additives
Environmental Precautions: Strict landfill control, do not flush into natural water sources
Waste Management: Collect in closed, labeled containers for final disposal at licensed facilities
Product Disposal: Incineration at approved facility with flue gas cleaning or secure landfill
Packaging Disposal: Triple rinse, recycle if feasible or treat as chemical waste
Regulations: Dispose in accordance with local, state, national, and international law; hazardous waste status may apply based on region
Precautions: Do not attempt open burning; restrict access to disposal areas
UN Number: Not regulated for ground, air, or sea transport
DOT / ADR / IATA / IMDG: Not classified as a hazardous material
Packaging: Ship in original, intact packaging; avoid exposure to moisture
Special Precautions: Block and brace to prevent movement during transit, handle with care to avoid spillage
Transport Conditions: Ambient temperature, dry containers
OSHA Hazard Communication: Meets requirements under 29 CFR 1910.1200
TSCA Inventory: All listed ingredients appear on TSCA inventory
REACH: Europe: substances registered, subject to SVHC monitoring (brominated additives follow ECHA guidelines)
RoHS Directive: Some components may exceed RoHS-mandated levels for EEE uses unless halogen-free grades selected
SARA Title III: Section 313: Antimony Compounds reportable; meets Tier II reporting
California Proposition 65: Contains chemicals (e.g., antimony trioxide, certain brominated flame retardants) known to the State of California to cause cancer
Globally Harmonized System (GHS): Hydraulic, health, and environmental labeling applies
