Product Name: Polyolefins Flame Retardant
Chemical Family: Polyolefins blend with halogen-free flame-retardant additives
Uses: Electrical insulation, automotive parts, industrial casing, building materials
Supplier Details: Manufacturer name, address, emergency phone number, and contact information appear on the container label and shipping documents
Classification: Not classified as hazardous under GHS; contains proprietary inorganic and organic flame retardant compounds mixed with polyolefin resin
Signal Word: No specific signal word, but dust and fumes from processing may irritate eyes, skin, or respiratory tract
Hazard Statements: Heated processing can release small amounts of irritating or toxic gases, including hydrogen bromide or ammonia, depending on formulation
Pictograms: None generally required; some batches may carry irritant warning for eyes and respiratory tract damage
Precautionary Statements: Wear suitable protection during handling, especially during processing and fabrication steps that generate dust or fumes
Polyethylene or Polypropylene Base: 70-90% by weight, CAS 9002-88-4 or 9003-07-0
Magnesium Hydroxide: 5-15% by weight, CAS 1309-42-8
Melamine Polyphosphate: 3-10% by weight, CAS 218768-84-4
Intumescent Additives (optional): Ammonium polyphosphate or pentaerythritol, up to 8% total, CAS 68333-79-9 and 115-77-5
Antioxidants and Stabilizers: 0.1-2%, proprietary blends
Fillers: Talc, calcium carbonate, or other minerals, varying amounts for mechanical stability
Inhalation: Move person to fresh air if processing fumes or dust have been inhaled; provide oxygen if breathing is difficult; seek medical attention for ongoing symptoms
Skin Contact: Remove contaminated clothing; wash skin with soap and water; for molten material burns, immediately cool affected area with water and seek medical advice
Eye Contact: Rinse eyes gently with plenty of water for several minutes, remove contact lenses if present and easy to do; consult a physician if irritation persists
Ingestion: Not expected to occur under normal use; if ingested, rinse mouth and seek medical attention, do not induce vomiting unless directed by medical professionals
Suitable Extinguishing Media: Water spray, dry chemical powder, foam, or carbon dioxide
Unsuitable Extinguishing Media: Avoid direct stream of water on burning mass, can scatter and spread fire
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, small amounts of toxic gases such as ammonia or hydrogen bromide if halogenated ingredients are present
Protective Equipment for Firefighters: Wear self-contained breathing apparatus and full protective suit
Firefighting Instructions: Move undamaged containers from hazard area if safe to do so; cool exposed containers with water spray
Personal Precautions: Use appropriate personal protective equipment to avoid inhalation or skin contact with dust
Environmental Precautions: Prevent materials from entering drains or waterways; contain spillage
Cleanup Methods: Collect spilled pellets or granules using shovel or broom; vacuum any dust using equipment with HEPA filtration
Disposal: Place material in approved disposal container for further handling
Handling Recommendations: Work in a well-ventilated area, avoid rough handling that creates dust, clean spills promptly
Storage Conditions: Store in cool, dry, well-ventilated areas away from incompatible substances like strong oxidizers; keep out of direct sunlight and away from extreme temperatures
Containers: Reseal opened bags or containers tightly
Special Instructions: Avoid eating, drinking, or smoking in handling area; wash hands thoroughly before breaks and after handling
Exposure Limits: No specific limits for finished formulations; follow limits for individual ingredients (e.g., 10 mg/m³ total dust for magnesium hydroxide)
Engineering Controls: Use local exhaust at points of dust or fume generation; general ventilation is beneficial
Eye Protection: Safety glasses or goggles during processing
Skin Protection: Gloves suitable for handling polymers or hot melts, long sleeves recommended
Respiratory Protection: Dust mask or respirator if dust or fumes exceed limits
Additional Hygiene Measures: Remove contaminated clothing and wash prior to reuse
Appearance: White or off-white pellets or granules, sometimes powder
Odor: Mild to none
pH: Not applicable
Melting Point: 120-170°C, formulation dependent
Boiling Point: Not applicable
Vapor Pressure: Not applicable
Flammability: Self-extinguishing according to formulation, but base resin can burn
Solubility in Water: Insoluble; dispersive as solid particles
Density: 0.9-1.5 g/cm³, depending on filler load
Other Data: Stable under normal conditions; may become sticky or deform at high temperature
Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: Strong oxidizers can react violently with organic polymer base
Conditions to Avoid: High temperatures above decomposition point, open flame
Hazardous Decomposition Products: Smoke, carbon monoxide, carbon dioxide, irritant fumes when heated to decomposition
Hazardous Reactions: Not prone to dangerous polymerization
Acute Toxicity: Low toxicity expected for polymer blend; certain additives can cause irritation in large exposure situations
Skin and Eye Contact: May cause mechanical irritation, especially in powdered or dusty form
Inhalation Risks: Dust and processing fumes may cause coughing or respiratory irritation; chronic exposure unlikely from finished parts
Long-term Effects: No major chronic health effects linked, according to current data for major components
Other Information: No ingredients listed as carcinogens by NTP, IARC, or OSHA
Aquatic Toxicity: Low solubility and mobility in water; large spills can affect physical environments but not considered highly toxic
Persistence and Degradability: Polyolefins degrade slowly under environmental conditions; additives may persist in soil or sediment
Bioaccumulation: Major components not expected to accumulate significantly in living organisms
Other Effects: Pellet spills may pose a threat to wildlife through ingestion; clean up granules diligently around waterways and storm drains
Waste Disposal: Recover and recycle whenever possible; otherwise, dispose in accordance with local, state, and federal regulations
Container Disposal: Empty containers may contain residue; follow local standards for cleaning and recycling
Special Precautions: Do not incinerate large amounts without pollution controls due to potential for toxic gas formation
UN Number: Not regulated
Proper Shipping Name: Flame Retardant Polyolefin Compounds or Plastics, not otherwise specified
Transport Hazard Class: Not classified as hazardous for transport
Packing Group: Not applicable
Marine Pollutant: No
Special Precautions: Avoid puncturing packaging, keep away from strong oxidizers in transit
OSHA Status: Not classified as hazardous under OSHA standards for finished goods
TSCA (Toxic Substances Control Act): All ingredients appear on TSCA inventory
REACH (Europe): All major substances registered or pre-registered
Other State or Federal Regulations: Subject to labeling and safety data communication requirements
Labeling Requirements: Include product name, hazard pictograms if required, supplier contact, and batch number as standard practice in workplace and transit
