Material Safety Data Sheet: Polypropylene Flame Retardant Compound

1. Identification

Product Name: Polypropylene Flame Retardant Compound
Synonyms: PP Flame Retardant Compound, Fire Retardant Polypropylene Blend
Recommended Use: Injection molding, extrusion, electrical components, automotive panels
Manufacturer Contact: [Company Name], [Address], [Phone Number], [Emergency Number]
Date of Issue: [Date]

2. Hazard Identification

Classification: Not classified as hazardous under GHS guidelines, though thermal decomposition releases irritant fumes
Label Elements: No standard pictogram; signal word ‘Warning’ for molten material
Health Risks: Hot melt burns skin, fumes can irritate eyes, nose, throat, coughing, dizziness possible with poor ventilation
Environmental Impact: Fine dust or pellets present slip hazard, possible aquatic harm if washed into waterways
Physical Hazards: Heated material may stick to skin, pellets present inhalation risk if dust forms

3. Composition / Information on Ingredients

Polypropylene Resin: 60–85% (CAS: 9003-07-0)
Ammonium Polyphosphate: 10–20% (CAS: 68333-79-9)
Decabromodiphenyl Ether or Equivalent Brominated Flame Retardant: 5–10% (CAS: 1163-19-5 or alternative)
Antimony Trioxide (if present): 1–5% (CAS: 1309-64-4)
Proprietary Additives and Stabilizers: 1–5%

4. First Aid Measures

Inhalation: Move person out of dust/fume; fresh air, monitor breathing, consult physician if irritation persists
Skin Contact: Wash with soap and cool water, do not peel hot material if stuck—seek medical attention
Eye Contact: Rinse immediately with water holding eyelids open, remove contact lenses if easy, continue rinsing, get medical help
Ingestion: Do not force vomiting, rinse mouth, get medical advice for large exposure or persistent symptoms

5. Fire-Fighting Measures

Suitable Extinguishing Media: Use foam, dry chemical powder, CO2, water spray
Specific Hazards: Releases toxic fumes—carbon monoxide, carbon dioxide, hydrogen halides, antimony compounds
Firefighter Protection: Full protective gear and positive-pressure self-contained breathing apparatus
Hazardous Combustion Products: Dense smoke, irritating vapors, unidentified organic compounds
Additional Advice: Cool containers with water, evacuate area if heavy smoke, avoid runoff into drains

6. Accidental Release Measures

Personal Precautions: Avoid breathing dust, ventilate area, wear protective gloves and goggles during clean up
Environmental Precautions: Prevent entry of spilled pellets or dust into waterways, drains, or soil
Cleanup Methods: Sweep up or vacuum to avoid raising dust, shovel into labeled containers for proper disposal
Other Considerations: Residue may create slip hazard, wash area thoroughly after cleanup

7. Handling and Storage

Handling: Minimize dust generation, avoid skin contact with heated resin, use local exhaust if processing
Storage: Keep bags or containers tightly closed, place in a dry, cool, well-ventilated area away from strong acids, bases, or oxidizers
Incompatible Materials: Strong oxidizing agents, concentrated acids
Special Considerations: Use antistatic measures to avoid dust ignition, store away from direct sunlight and sources of ignition

8. Exposure Controls and Personal Protection

Engineering Controls: Local exhaust at points of dust/fume generation, good general room ventilation
Personal Protection: Safety glasses with side shields, heat-resistant gloves during molding, dust masks or respirators for fine dust
Workplace Exposure Levels: Antimony trioxide (if present) TLV: 0.5 mg/m3 TWA, check national limits for other ingredients
Hygiene Measures: Wash thoroughly after handling, do not eat, drink, or smoke during use, keep work clothes separate from home clothing

9. Physical and Chemical Properties

Form: Solid pellets or granules
Color: White to off-white, may be color-tinted
Odor: Mild plastic smell
Melting Point: 160–170°C
Density: 0.9–1.2 g/cm3
Solubility: Insoluble in water
Flash Point: >350°C
Vapor Pressure: Negligible
Autoignition Temperature: Approx. 450°C
Decomposition Temperature: >250°C (with emission of irritating fumes)

10. Stability and Reactivity

Chemical Stability: Stable under normal conditions, avoid temperatures above 230°C for extended time
Reactivity: No strong reactivity expected under recommended use
Hazardous Reactions: Violent reaction possible with strong oxidizers
Hazardous Decomposition Products: Carbon monoxide, brominated vapors, hydrogen halides, antimony oxides
Conditions to Avoid: Open flame, high heat, incompatible materials

11. Toxicological Information

Acute Effects: Fumes after heating and burning cause respiratory irritation, headache, dizziness, nausea
Chronic Effects: Prolonged dust inhalation may affect lungs, flame retardant chemicals suspect for thyroid/liver effects in animals
Skin Contact: Hot melt causes burns, prolonged or repeated contact may cause mild irritation
Eye Contact: Dust/fumes irritate
Ingestion: Not likely toxic in small amounts, large ingestion leads to nausea or stomach upset
Sensitization: Rare—avoid repeated skin exposure

12. Ecological Information

Environmental Fate: Pellets persist, risk for aquatic life by ingestion
Bioaccumulation: Brominated flame retardants sometimes detected in food web
Aquatic Toxicity: Some additives harmful to aquatic invertebrates at high levels
Mobility: Granules may migrate through soil, slowly biodegrade
Recommendations: Prevent entry to soil, drains, rivers; collect spills quickly

13. Disposal Considerations

Waste Disposal: Follow local regulations, dispose as non-hazardous plastic waste if not contaminated
Incineration: Only at licensed facilities with gas scrubbing
Recycling: Recycle wherever possible, avoid mixing with incompatible materials
Packaging Disposal: Empty bags/liners according to local requirements; prevent pellet release to environment

14. Transport Information

Proper Shipping Name: Plastic Granules, Not Regulated
Hazard Class: Not classified as Dangerous Goods
UN Number: Not applicable
Packaging Requirements: Sealed, sturdy bags or containers to prevent spillage
Special Precautions: Use pellet-proof packaging to avoid environmental spills during transit

15. Regulatory Information

GHS Classification: Not classified for physical or health hazards under GHS
US TSCA: Components listed or exempt
EU REACH: Ingredients registered where applicable
Workplace Safety: Follow OSHA/NIOSH guidelines for dust and additives
Labeling: Safety data sheet available on request; inform workers about potential hazards and handling instructions