Product Name: Polypropylene Flame Retardant Masterbatch
Recommended Use: Plastic manufacturing, polymer compounding, injection molding, extrusion
Supplier: [Insert manufacturer’s details, phone number, address]
Emergency Contact: [Insert emergency telephone and information line]
Product Code: [Insert code assigned by manufacturer, if applicable]
Classification: Not classified as hazardous under GHS; irritation possible from dust or fumes
Label Elements: No symbol required; precautionary statements on dust inhalation, skin contact
Health Hazards: Dust may cause mild respiratory or eye irritation; hot material can burn skin
Environmental Hazards: Pellet form may present physical hazard to aquatic life if released in bulk
Physical Hazards: Combustible at high temperatures; may release toxic fumes in fire
Precautionary Statements: Avoid breathing dust/fumes, use with adequate ventilation, prevent spillage into drains
Polypropylene Resin: 60–90% CAS No. 9003-07-0
Flame Retardant Additive (usually decabromodiphenyl ethane, magnesium hydroxide, or melamine cyanurate): 10–35% CAS No. [depends on type]
Compatibilizer, dispersing aids: 1–5% CAS No. [proprietary]
Colorant, stabilizer (as needed): <1% CAS No. [proprietary]
Other information: Ingredients are embedded in polymer matrix; composition percentages may vary by supplier and grade
Inhalation: Move to fresh air if dust or fumes cause discomfort; seek medical attention if breathing difficulties occur
Skin Contact: Cool affected area with water if molten product sticks to skin; do not peel off solidified polymer; use soap and water for physical residue removal
Eye Contact: Rinse cautiously with water for several minutes; remove any contact lenses if present and easy to do; obtain medical attention for persistent irritation
Ingestion: Rinse mouth with water; unlikely to cause harm in small amounts; seek medical help if large quantity is swallowed
Suitable Extinguishing Media: Water spray, foam, dry chemical, or carbon dioxide
Unsuitable Media: Direct water jet (may spread molten plastic)
Specific Hazards: Burning may produce toxic gases including carbon monoxide, hydrogen bromide (if brominated additive used), and oxides of nitrogen
Protective Equipment for Firefighters: Full protective clothing and self-contained breathing apparatus
Special Procedures: Remove undamaged product from fire zone if safe; use water to cool containers
Personal Precautions: Wear gloves and goggles to protect from sharp pellets or dust; avoid inhalation of dust
Environmental Precautions: Prevent pellets from entering waterways or sewers; pick up large spills promptly
Cleanup Methods: Sweep up pellets, use industrial vacuum for dust; collect into labeled containers for recycling or disposal; ventilate area
Disposal of Wash Water: Prevent runoff from joining drains; handle residues as solid waste
Safe Handling Practices: Use only in well-ventilated areas; avoid generating dust; avoid ingestion and direct contact with molten polymer
Storage Conditions: Store in cool, dry, well-ventilated warehouse; keep away from heat sources, open flame, or direct sunlight
Incompatible Materials: Strong oxidizers, acids, and bases; avoid long-term exposure to UV light
Packaging: Use sealed bags or containers to prevent moisture uptake and contamination
Special Requirements: Use antistatic bags if static buildup poses a risk
Engineering Controls: Local exhaust ventilation recommended for operations producing dust or fumes
Respiratory Protection: Use dust masks for high dust environments; respiratory protection if dust or fumes are above permissible limits
Hand Protection: Use gloves resistant to abrasion and heat, especially for handling hot polymer
Eye Protection: Safety goggles; face shield during high-heat processing
Skin Protection: Long sleeves and pants; protective apron if handling molten material
Hygiene Measures: Wash hands thoroughly after handling; remove contaminated clothing before eating
Appearance: Opaque granules or pellets; varied color based on formulation
Odor: Odorless or faint plastic smell
Melting Point: 160–170°C (varies with resin grade and additives)
Boiling Point: Not applicable (decomposes before boiling)
Flash Point: >300°C
Specific Gravity: 0.90–1.20 (depends on filler and additives)
Solubility: Insoluble in water
Vapor Pressure: Not relevant under normal conditions
Decomposition Temperature: >300°C; toxic fumes if burnt
Flammability: Modified to improve fire resistance but can burn at high temperatures
Chemical Stability: Stable at normal temperatures and pressures
Reactivity: Not reactive with most substances at room temperature
Conditions to Avoid: Open flame, high heat, direct sunlight for extended periods
Hazardous Decomposition: Releases carbon monoxide, carbon dioxide, and other gases if decomposed; brominated grades may emit hydrogen bromide
Incompatible Materials: Strong oxidizers, acids, and certain solvents
Polymerization: Will not occur under standard use
Acute Toxicity: Low by ingestion, skin, or inhalation; no known oral LD50 for product as a whole
Chronic Exposure: No data indicating long-term health hazards under normal use
Skin Sensitization: Not known to cause allergies; hot material burns possible
Respiratory Effects: Dust or fumes may cause transient irritation; prolonged exposure to decomposition fumes could affect respiratory system
Carcinogenicity: No ingredients listed as carcinogenic by IARC, NTP, or OSHA
Mutagenicity, Reproductive Effects: No evidence for product or main ingredients
Aquatic Toxicity: Product stable in water; risk of pellet ingestion to fish and birds as physical pollutant
Persistence: Polypropylene is non-biodegradable; remains in environment for years
Bioaccumulation: Not expected to bioaccumulate
Mobility in Soil: Pellets may migrate mechanically but unlikely to dissolve or leach
Other Environmental Impacts: Avoid release to environment; collect and dispose responsibly
Waste Disposal Methods: Recycle where possible; disposal in accordance with local, state, federal regulations
Incineration: Only in approved facilities with pollution controls
Landfill: Stable in landfill, non-leaching; best practice is recycling
Container Disposal: Empty containers must be cleaned and disposed per local rules
UN Number: Not regulated
Transport Hazard Class: Not hazardous for transport
Packing Group: Not assigned
Special Precautions: Prevent spillage of pellets; keep dry during shipment
Transport Labels: No special marks required; check if flame retardant additive triggers any transport codes
OSHA Status: Not considered hazardous under OSHA regulations
TSCA (US): Components listed on TSCA inventory
EU Regulation: REACH compliant; no SVHC identified up to latest update
Other International Regulations: Conforms to local chemical and polymer regulations where marketed
Label Requirements: Standard shipping label; safety data sheet available for workplace safety compliance
Restrictions: Some flame retardant additives face restrictions in specific regions (e.g., Europe limits some brominated compounds)
