MSDS List for Polypropylene Halogen Free Flame Retardant

Identification

Product Name: Polypropylene Halogen Free Flame Retardant
Synonym: PP HFFR Compound
Recommended Use: Plastics processing, cable sheathing, automotive parts
Supplier: Name, address, and phone number of manufacturer or distributor
Emergency Contact: 24/7 emergency telephone, contact person responsible for safety

Hazard Identification

Classification: Not classified as hazardous under GHS guidelines
Main Hazards: Heated vapors may cause irritation to respiratory tract, eye irritation from dust, skin irritation after prolonged exposure
Symbols: None required by current standards
Routes of Exposure: Inhalation of dust/fumes, skin/eye contact
NFPA Ratings: Health: 1, Flammability: 1, Reactivity: 0

Composition / Information on Ingredients

Polypropylene Resin: 60–85% by weight, CAS 9003-07-0
Halogen-Free Flame Retardant Additive: 10–35% by weight, proprietary blend, may include magnesium hydroxide, melamine polyphosphate, aluminum trihydrate (exact concentrations available on request, not considered hazardous)
Processing Aids and Lubricants: <3%, classified as non-hazardous

First Aid Measures

Inhalation: Move affected person to fresh air, keep comfortable. Seek medical attention if coughing or respiratory symptoms persist.
Eye Contact: Rinse immediately with plenty of water for 15 minutes. Remove contact lenses if present. Call a doctor if irritation does not go away.
Skin Contact: Wash off immediately with soap and water. Remove contaminated clothing. Medical help for persistent redness or discomfort.
Ingestion: Rinse mouth. Drink water. Get medical advice if feeling unwell.

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, phosphorus oxides, ammonia-like vapors may release under incomplete combustion
Protective Equipment: Firefighters wear self-contained breathing apparatus and full gear
Unusual Hazards: Molten polymer can cause severe burns

Accidental Release Measures

Personal Precautions: Use protective gloves, dust mask, goggles; avoid breathing dust
Environmental Precautions: Keep granules or powders out of drains and natural watercourses
Clean-Up Methods: Sweep or vacuum up material, shovel into suitable container for recycling or disposal, avoid raising dust, ventilate area

Handling and Storage

Handling: Operate with local exhaust or ventilation during processing. Avoid dust generation, wash hands after handling
Storage Conditions: Store in original packaging, cool, dry place, away from incompatible substances like strong oxidizers, keep containers tightly closed
Special Requirements: Protect against moisture and direct sunlight, stack bags properly to prevent shifting

Exposure Controls and Personal Protection

Control Parameters: No specific workplace exposure limits for product, keep dust below 5 mg/m³ (inhalable)
Personal Protection: Wear protective gloves, long-sleeved clothing, safety goggles, and approved dust mask. Local exhaust recommended for dust control
Hygiene Measures: Do not eat, drink, or smoke during use. After shift, clean skin thoroughly

Physical and Chemical Properties

Form: Granules or pellets
Color: White, grey, or as specified
Odor: Nearly odorless
Melting Point/Range: 150–170°C
Density: 1.05–1.40 g/cm³
Solubility: Insoluble in water
Flash Point: >350°C
Auto-Ignition Temperature: >400°C
VOC Content: None

Stability and Reactivity

Chemical Stability: Stable at normal room temperature and pressure
Conditions to Avoid: Open flame, hot surfaces, sources of ignition, prolonged UV exposure
Materials to Avoid: Strong acids, strong oxidizers
Decomposition: Heating beyond decomposition releases smoke and irritating fumes

Toxicological Information

Acute Toxicity: No significant acute hazards based on available data
Chronic Effects: Prolonged skin contact may cause dryness, uncontrolled processing fumes may cause respiratory discomfort
Sensitization: No known sensitizing effects
Carcinogenicity: Polypropylene and ingredients not listed as carcinogenic under IARC, NTP, or OSHA
Inhalation Effects: Dust or fumes from thermal decomposition may irritate lungs and throat

Ecological Information

Environmental Impact: Not readily biodegradable, persistent in environment
Aquatic Toxicity: Low toxicity to fish and aquatic organisms based on polymer nature
Mobility: Non-volatile, low solubility, tends to settle in sediment
Bioaccumulation: Unlikely due to high molecular weight and insolubility

Disposal Considerations

Waste Disposal Methods: Recycle material whenever possible. Dispose in accordance with local, regional, or national regulations
Incineration: Permitted only in controlled facility, avoid open burning
Packaging Disposal: Clean and recycle empty packaging or dispose as solid industrial waste

Transport Information

UN Number: Not classified as hazardous for transport
Proper Shipping Name: Not regulated
Transport Hazard Class: Not applicable
Packing Group: Not applicable
Environmental Hazards: No

Regulatory Information

Labelling Requirements: No special labeling required under GHS
Chemical Inventories: All ingredients listed in TSCA (USA), DSL (Canada), EINECS (Europe)
Restrictions: Observe workplace safety regulations regarding synthetic polymers
SARA/Title III: Product contains no chemicals subject to reporting