MSDS: Pure Piperazine Pyrophosphate Mflam QZ10-4

Identification

Product Name: Piperazine Pyrophosphate Mflam QZ10-4
Chemical Formula: C4H10N2·2H3PO4
CAS Number: 12576-45-1
Recommended Use: Flame retardant for plastics, coatings, and textiles.
Contact Information: Manufacturer/Supplier: [Insert Name, Address, Phone, Emergency Contact]
SDS Number: QZ10-4-PP
Synonyms: Bis(piperazine) pyrophosphate, pyrophosphoric acid di(piperazin-1-yl) ester

Hazard Identification

Classification: Irritant (Eye, Skin, Respiratory), Harmful if Swallowed
Label Elements: GHS pictograms (Exclamation mark)
Signal Word: Warning
Hazard Statements: May cause eye and skin irritation, respiratory tract discomfort, can lead to nausea and headache if inhaled in large amounts
Precautionary Statements: Avoid direct contact, use in well-ventilated area, wear protection
Potential Health Effects: Shortness of breath, irritation, redness of eyes and skin, coughing, upset stomach
Environmental Hazard: Harmful to aquatic organisms, possible long-term effects in aquatic environments

Composition / Information on Ingredients

Chemical Name: Piperazine Pyrophosphate
Concentration: 100%
CAS Number: 12576-45-1
Impurities: Trace moisture & proprietary stabilizers (<0.5%)
Additives: None

First Aid Measures

Eye Contact: Rinse immediately with plenty of water for at least 15 minutes, remove contact lenses when present and easy to do, seek medical attention if irritation persists
Skin Contact: Wash with soap and water, remove contaminated clothing and shoes, consult physician if symptoms appear
Inhalation: Move person to fresh air, keep comfortable for breathing, call poison control if symptoms develop
Ingestion: Do not induce vomiting, rinse mouth thoroughly, drink water if conscious, seek medical help
Most Important Symptoms: Dryness, burning, irritation of eyes or skin, coughing, sore throat
Notes for Doctor: Treat symptomatically, monitor for allergic reactions, no specific antidote known

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry powder, foam, carbon dioxide
Unsuitable Extinguishing Media: Strong water jets
Specific Hazards: Thermal decomposition releases oxides of nitrogen, phosphorus, and toxic fumes
Protective Equipment: Full protective gear, self-contained breathing apparatus
Additional Information: Cool fire-exposed containers with water, remove persons from danger zone, prevent run-off from entering drains or water bodies

Accidental Release Measures

Personal Precautions: Wear protective gloves, goggles, mask, avoid dust formation
Emergency Procedures: Evacuate area, ensure adequate ventilation, restrict access
Environmental Precautions: Keep product out of waterways, avoid soil contamination
Clean-Up Methods: Scoop spilled material into labeled waste containers, wipe with damp cloth, ventilate area, dispose as hazardous waste
Reference to Other Sections: See Exposure Controls, Disposal Considerations for details

Handling and Storage

Handling: Work in well-ventilated area, avoid inhaling dust, wash hands after handling, minimize dust generation
Storage: Store in cool, dry area with adequate ventilation, keep container tightly closed, segregate from oxidizers and acids, protect from moisture
Incompatible Materials: Strong acids, bases, oxidizers
Conditions to Avoid: High humidity, extreme temperatures, direct sunlight
Packing Materials: Corrosion-resistant drums or bags with proper sealing

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits; treat as irritant
Engineering Controls: Local exhaust ventilation, process enclosures, eye wash stations
Personal Protective Equipment (PPE): Chemical-resistant gloves (nitrile, neoprene), safety glasses with side shields, lab coat, NIOSH-approved dust mask where needed
Hygiene Measures: Do not eat, drink, or smoke near product, wash hands before breaks and after work
Environmental Exposure Controls: Collect washings separately, prevent product from entering drains

Physical and Chemical Properties

Appearance: White crystalline powder
Odor: Odorless or faint amine smell
pH (1% solution): 5.5-7.5
Melting Point: 180-220°C (decomposes above 220°C)
Boiling Point: Not applicable (decomposes)
Solubility: Slightly soluble in water at room temperature
Density: 1.65-1.80 g/cm³
Vapor Pressure: Negligible
Flash Point: Not applicable
Partition Coefficient: Data not available
Evaporation Rate: Not relevant (solid)

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions, deteriorates in moist or hot environments
Reactivity: Reacts with acids and strong oxidizers
Decomposition Products: Releases nitrogen oxides, phosphorus oxides under high heat
Hazardous Polymerization: Not expected under normal use
Other Information: Protect from humidity, dust buildup, and excessive heat

Toxicological Information

Likely Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Toxicity: May cause irritation, swallowing large amounts causes nausea, headache, vomiting
Chronic Effects: Prolonged exposure can cause dermatitis or respiratory irritation
Sensitization: Possible for sensitive individuals but rare
Carcinogenicity: Not classified as carcinogen by ACGIH, IARC, NTP or OSHA
Mutagenicity/Teratogenicity: No relevant data in available studies
Symptoms and Effects: Irritation of respiratory tract, sneezing, skin redness, watery eyes, gastrointestinal upset

Ecological Information

Toxicity: Data indicates product is slightly hazardous for aquatic life at high concentrations, fish and daphnia tadpoles affected above 100 mg/L
Persistence and Degradability: Limited biodegradation, tendency to remain in solid phase in soil
Bioaccumulation Potential: Low predicted accumulation in organisms, based on molecular structure
Mobility: Will settle out in water, unlikely to evaporate or migrate in soil
Other Adverse Effects: No known dangerous effects on ozone, photochemical reactivity not indicated

Disposal Considerations

Product Disposal: Treat as hazardous waste, dispose by authorized chemical waste contractors, comply with local, national, federal regulations
Contaminated Packaging: Rinse thoroughly before recycling, dispose as solid waste if contamination is minor, label if residue remains
Methods of Disposal: Incineration or landfilling in approved sites
Special Considerations: Do not dispose in drains, sewers, or open environment

Transport Information

UN Number: Not regulated under UN category
Transport Hazard Class: Not classified as dangerous for transport
Packing Group: Not applicable
Labels Required: None under standard shipping; label as irritant if shipment exceeds local thresholds
Environmental Hazards: Not identified as marine pollutant
Special Precautions: Secure packaging, prevent movement or damage in transit
Transport in Bulk: Not regulated

Regulatory Information

US Regulation (TSCA): Listed
EU Regulation (REACH): Registered or pre-registered as industrial substance
Labeling Requirements: Eye, skin, respiratory hazard warnings
OSHA Hazard Communication: Covered
Other Regulations: Not flagged by DOT, IMDG, IATA, or major regulatory lists for high hazard
Restriction: Industrial and professional use only, not approved for consumer use
SARA Title III, Section 313: Not listed
California Proposition 65: Not listed