Material Safety Data Sheet: Sodium Tripolyphosphate (STPP) Industrial Grade

1. Identification

Product Name: Sodium Tripolyphosphate
Common Synonyms: STPP, pentasodium triphosphate
CAS Number: 7758-29-4
Recommended Use: Cleaning agents, detergents, water softener, ceramics, textile processing
Supplier: Please contact your local supplier directly for up-to-date information
Emergency Contact: Refer to the manufacturer’s contact line for emergencies or local poison control center.

2. Hazard Identification

Hazard Classification: Eye irritation (Category 2A), Skin irritation (Category 2)
Label Elements: Signal word “Warning”, exclamation mark hazard pictogram
Hazard Statements: Causes serious eye irritation, may cause skin irritation on prolonged contact
Precautionary Statements: Wash hands thoroughly after handling, wear suitable protective gloves and eye protection
Other Hazards: Dust formation can irritate respiratory tract, not listed as carcinogenic by IARC, NTP, or OSHA.

3. Composition / Information on Ingredients

Chemical Name: Sodium Tripolyphosphate
Formula: Na5P3O10
Concentration: ≥ 94% by weight
Other Components: Minor impurities may include sodium phosphate, water (<1%), no hazardous stabilizers or additives indicated.

4. First Aid Measures

Inhalation: Move person to fresh air, support breathing as needed, seek medical advice if symptoms persist (coughing, throat irritation)
Skin Contact: Remove contaminated clothing, rinse affected skin with plenty of water, wash with soap, seek medical attention if irritation develops
Eye Contact: Immediately flush eyes gently with plenty of water for at least 15 minutes, remove contact lenses if present and easy, seek medical attention
Ingestion: Rinse mouth, do not induce vomiting, drink water if conscious, seek medical assistance right away.

5. Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, foam, dry chemical, or CO2 for surrounding fire
Unsuitable Media: Avoid high-pressure water streams that may spread powder
Specific Hazards: Material is not flammable, product decomposes at high temperatures producing sodium oxide and phosphorus oxides gases
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear
Special Procedures: Cool exposed containers with plenty of water, avoid release of contaminated fire run-off into environment.

6. Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, use personal protective equipment to prevent dust contact with skin and eyes
Environmental Precautions: Prevent product from entering drains, waterways, and soil
Cleanup Methods: Avoid dust formation, carefully sweep or vacuum up material, collect in a suitable container for proper disposal, ventilate area as needed.

7. Handling and Storage

Handling: Wear safety goggles, gloves, and dust mask, avoid breathing dust, keep away from food, beverages, and incompatible substances like strong acids
Storage: Store in tightly closed containers in cool, dry, well-ventilated areas, keep away from moisture and direct sunlight, do not stack heavy loads on top, store away from acids and oxidizing agents.

8. Exposure Controls and Personal Protection

Exposure Limits: No specific OSHA or ACGIH exposure limits, use good industrial hygiene practices
Engineering Controls: Use local exhaust ventilation or other engineering controls to keep airborne levels below recommended exposure limits
Personal Protective Equipment: Wear chemical-resistant gloves, safety goggles, dust mask or NIOSH-approved respirator, protective clothing if handling large amounts
Hygiene Measures: Wash hands and face thoroughly after handling, remove contaminated clothing and wash before reuse, avoid eating or smoking while working with the product.

9. Physical and Chemical Properties

Appearance: White crystalline or granular powder
Odor: Odorless
pH (1% solution): 9–10
Melting Point: >600°C (decomposes)
Boiling Point: Not applicable (decomposes on heating)
Solubility in Water: 14.5g/100g at 25°C
Specific Gravity: 2.52
Bulk Density: Approximately 0.9–1.1 g/cm3
Vapor Pressure: Not applicable
Flash Point: Not flammable
Explosive Properties: Not explosive
Oxidizing Properties: Not classified as oxidizing
Other Data: Hygroscopic, absorbs moisture from air.

10. Stability and Reactivity

Chemical Stability: Stable under normal conditions, does not polymerize
Conditions to Avoid: Exposure to moisture, high temperatures, and acids
Incompatible Materials: Strong acids, strong oxidizers, aluminum, magnesium
Hazardous Decomposition Products: Heating can produce toxic fumes of sodium oxide and phosphorus oxides
Reactivity: Reacts with acids to release heat and phosphorus-containing gases, attacks some metals in the presence of moisture.

11. Toxicological Information

Acute Toxicity: LD50 (oral, rat): ~3,120 mg/kg, low toxicity via inhalation or skin contact
Skin Corrosion/Irritation: Prolonged contact may cause moderate irritation, redness, dryness
Serious Eye Damage/Irritation: Causes serious eye irritation
Respiratory Sensitization: Dust inhalation may trigger throat and nose symptoms
Long-Term Effects: Prolonged overdoses in industrial settings could result in kidney or bone effects (rare).
Carcinogenicity: Not listed as carcinogen by IARC, NTP, or OSHA
Other Effects: Not mutagenic or teratogenic in standard studies on phosphate salts.

12. Ecological Information

Ecotoxicity: Large releases may contribute to water eutrophication, can reduce oxygen levels and harm aquatic life
Aquatic Toxicity: LC50 (fish, 96 hours): >100 mg/L
Persistence and Degradability: Inorganic material, not biodegradable, breaks down into phosphates in water
Bioaccumulation Potential: Not bioaccumulative
Mobility in Soil: High solubility, leaches into the soil and water easily
Other Adverse Effects: Excess nutrients can stimulate algal blooms, leading to ecological imbalances.

13. Disposal Considerations

Waste Disposal: Collect waste product in labeled containers, comply with local, state, and federal disposal regulations
Disposal Methods: Disposal at permitted municipal or industrial waste facilities
Environmental Cautions: Avoid disposal into storm drains, open land, water bodies, minimize impact by using according to recommended applications, do not burn waste
Contaminated Packaging: Clean container thoroughly before recycling or disposal.

14. Transport Information

UN Number: Not classified as dangerous for transport
Proper Shipping Name: Sodium Tripolyphosphate
Transport Hazard Class: Not hazardous
Packing Group: Not assigned
Special Precautions: Protect packaging from moisture, condensation, and rough handling during shipment
Marine Pollutant: Not regulated as marine pollutant (check local regulations)
IMDG/IATA/ADR: No special requirements due to low hazard classification.

15. Regulatory Information

OSHA Status: Not regulated as a hazardous chemical under OSHA HCS 29 CFR 1910.1200
TSCA: Listed in US Toxic Substances Control Act Inventory
EU Regulations: EINECS/ELINCS listed (231-838-7), not classified as hazardous under EU CLP
SARA 313: Not subject to reporting
California Proposition 65: Not listed
Other USA/State Regulations: Follow applicable regional or local requirements, product labeling to include hazard and precautionary details as outlined by GHS standards.