Product Name: Thermoplastic Flame Retardant
Synonyms: Polymeric flame retarder, Halogenated flame inhibitor
Manufacturer: SafeChem Polymers Inc.
Address: 4276 Westbrook Industrial Dr, Hardford, NY 10016, USA
Emergency Phone: +1 800-456-7853
Recommended Use: Fire retardant additive for plastics fabrication
Restrictions on Use: Not intended for food-contact or medical applications
GHS Classification: Acute Toxicity (Oral, Dermal, Inhalation) Category 4, Skin Sensitizer Category 1, Eye Irritation Category 2A
Signal Word: Warning
Hazard Statements: Harmful if swallowed or inhaled. May cause skin and eye irritation. May provoke allergic reactions in sensitive individuals.
Pictograms: Exclamation mark, Health hazard
Precautionary Statements: Avoid dust formation. Use protective gloves, eye protection. Wash hands thoroughly after handling. Do not eat, drink, or smoke during use.
Main Substance: Proprietary blend of organophosphorus compounds (CAS: withheld) 65-85%
Co-polymer Additive: Polyethylene (CAS: 9002-88-4) 5-25%
Synergist Agent: Antimony trioxide (CAS: 1309-64-4) 1-3%
Filler: Magnesium hydroxide (CAS: 1309-42-8) 5-10%
Other Non-Hazardous Ingredients: Stabilizers, dispersants, proprietary <5%
Inhalation: Move person to fresh air. Supply oxygen if breathing is difficult. Get medical attention if symptoms develop.
Skin Contact: Remove contaminated clothing. Wash skin with soap and water. Seek care if irritation persists.
Eye Contact: Rinse with water for 15-20 minutes, lifting eyelids frequently. Remove contact lenses if present. Immediate medical help if irritation continues.
Ingestion: Rinse mouth. Do not induce vomiting. Seek medical advice if large amounts ingested or if symptoms occur.
Suitable Extinguishing Media: Foam, dry chemical, carbon dioxide, water spray
Hazardous Combustion Products: Phosphoric acid vapors, carbon monoxide, carbon dioxide, antimony fumes
Advice for Firefighters: Wear full protective gear. Use self-contained breathing apparatus. Avoid runoff, may pose environmental hazard.
Unusual Fire Hazards: Powder or dust can form explosive mixtures in air.
Personal Precautions: Ventilate area. Wear respiratory protection, gloves, safety goggles. Avoid breathing dust.
Spill Cleanup: Collect spilled material using non-sparking tools. Sweep or vacuum without generating dust. Place in suitable, closed containers for disposal.
Environmental Precautions: Prevent entry into drains, sewers, or waterways. Notify authorities if substantial quantities enter environment.
Decontamination: Wash surfaces with water after material pick-up. Avoid creating a dusty atmosphere.
Handling: Work in well-ventilated areas. Minimize dust generation and accumulation. Wash hands after handling. Do not mix with incompatible substances like strong oxidizers.
Storage Conditions: Keep container tightly closed, dry, and in a cool, well-ventilated place, away from direct sunlight. Store separately from food and drink. Maintain product below 40°C.
Packaging Materials: Use original containers or approved high-density polyethylene drums.
Incompatibilities: Strong oxidizing acids, alkalis, combustible compounds.
Exposure Limits: Antimony trioxide OSHA PEL: 0.5 mg/m³, ACGIH TLV: 0.5 mg/m³
Engineering Controls: Local exhaust ventilation to prevent airborne dust accumulation. Closed system transfers recommended.
Personal Protection: Wear chemical resistant gloves (nitrile or neoprene), long-sleeved clothing, safety glasses or goggles, disposable dust mask or respirator (NIOSH N95 or better) for routine handling.
Hygiene Measures: Wash hands and exposed skin thoroughly after handling. Remove contaminated clothing promptly.
Physical State: Granular solid or powder
Color: White to off-white
Odor: Slight, non-offensive
Solubility: Insoluble in water
Melting Point: 140-180°C
Boiling Point: Not applicable (decomposes before boiling)
Density: 1.6-1.8 g/cm³
pH (suspension): 6-8
Flash Point: Not flammable; decomposition may release toxic fumes above 260°C
Vapor Pressure: Negligible at ambient temperatures
Evaporation Rate: Not relevant (solid product)
Auto-ignition Temperature: >300°C
Explosive Properties: Dust cloud can be explosive in air under certain conditions
Partition Coefficient (n-octanol/water): Not determined for mixture
Chemical Stability: Stable under recommended storage and handling conditions
Conditions to Avoid: Excessive heat, sparks, open flames, strong oxidizers
Incompatible Materials: Strong acids, alkalis, oxidizers
Hazardous Decomposition Products: Phosphoric acid gases, carbon monoxide, carbon dioxide, antimony compounds
Thermal Decomposition: Releases toxic gases above 260°C
Polymerization: Will not occur under normal handling
Acute Toxicity (Oral): LD50 (rat) 900 mg/kg (proprietary flame retardant blend)
Acute Toxicity (Inhalation): LC50 (rat, 4h) >2.5 mg/L (dust)
Skin Corrosion/Irritation: Mild to moderate skin irritation possible
Eye Damage/Irritation: Causes eye irritation
Respiratory Sensitization: Frequent or prolonged inhalation of dust can provoke asthmatic responses
Carcinogenicity: Some components (antimony trioxide) classified as possible human carcinogen, IARC Group 2B
Chronic Effects: Long-term exposure can impact lungs; may cause dermatitis
Ecotoxicity: Harmful to aquatic life with long-lasting effects; avoid release to watercourses
Persistence and Degradability: Principally not biodegradable, persists in natural environment
Bioaccumulation Potential: Low for polymer, moderate for antimony content
Mobility in Soil: Little mobility; product tends to remain in soil sediment
Other Adverse Effects: High concentrations may disrupt aquatic organisms' reproductive cycle
Waste Disposal Methods: Place waste material in properly labeled container. Dispose according to local, regional, and national regulations. Avoid landfill without prior treatment.
Contaminated Packaging: Triple rinse drums before recycling or reusing. Residual product must be processed as hazardous waste.
Disposal of Large Quantities: Seek permits from environmental authorities. Prefer incineration in approved facilities with proper emission controls.
UN Number: Not regulated for transport under UN model regulations
Proper Shipping Name: Polymeric flame retarder mixture
Hazard Class: Non-hazardous for road, sea, air
Packing Group: Not applicable
Special Precautions: Avoid mechanical shocks and prevent release of dust during loading/unloading
Labels Required: None required under standard transport, observe company-specific labeling guidelines
TSCA (USA): All ingredients manufactured or imported in compliance with TSCA inventory
REACH (EU): Components registered or pre-registered as required by ECHA
OSHA Hazard Communication Standard: Classified hazardous
SARA Title III, Section 313: Antimony compounds reportable if thresholds exceeded
California Proposition 65: Product contains chemical(s) known to the State of California to cause cancer
RoHS Directive: No listed RoHS substances present above threshold concentrations
