MSDS for TPU Flame Retardant Phoslite IP-A

Identification

Product Name: TPU Flame Retardant Phoslite IP-A
Chemical Family: Thermoplastic polyurethane compound with integrated flame retardant
Manufacturer: [Insert Manufacturer’s Name and Contact Information]
Recommended Use: Used in cable jackets, consumer electronics, and automotive parts for flame protection
Emergency Contact: [Insert Emergency Telephone Number]
Synonyms: Phosphorus-based polyurethane flame retardant blend

Hazard Identification

Classification: Respiratory tract and skin irritant; eye irritant
Signal Word: Warning
Hazard Statements: Causes mild to moderate skin irritation, may cause eye irritation, dust inhalation could trigger coughing or discomfort
Pictograms: Exclamation mark
Precautionary Statements: Keep container tightly closed, avoid breathing dust, wear gloves and eye protection, wash skin thoroughly after handling
Routes of Exposure: Skin contact, inhalation, eye contact
Target Organs: Respiratory system, skin, eyes

Composition / Information on Ingredients

Component 1: Thermoplastic Polyurethane, approx. 70-85%
Component 2: Phosphorus flame retardant, approx. 15-25%
Component 3: Additives and stabilizers, up to 5%
CAS Numbers: [Manufacturer to disclose for proprietary blends; example: TPU - 9009-54-5, organic phosphorus compound - confidential]
Impurities: No hazardous impurities present above regulatory thresholds

First Aid Measures

Eye Contact: Rinse immediately with plenty of water for at least 15 minutes; seek medical advice if irritation persists
Skin Contact: Remove contaminated clothing; wash skin with soap and water; seek medical attention for persistent irritation
Inhalation: Move person to fresh air; keep at rest; seek medical attention if symptoms occur
Ingestion: Do not induce vomiting; rinse mouth; seek medical assistance
Notes to Physician: Treat symptomatically; no specific antidote

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, carbon dioxide, dry chemical
Unsuitable Extinguishing Media: High-pressure water jets may spread the fire
Hazardous Combustion Products: Carbon oxides; hydrogen cyanide; nitrogen oxides; phosphorus oxides; toxic gases and vapors
Special Protective Equipment: Full protective gear, self-contained breathing apparatus
Firefighting Instructions: Cool containers with water spray; remove undamaged containers from fire area if safe
Flammability: Not highly flammable as supplied; melts and decomposes at elevated temperatures

Accidental Release Measures

Personal Precautions: Use suitable respirator, gloves, eye protection; avoid dust formation
Environmental Precautions: Prevent run-off into drains, surface waters, and soils
Methods for Cleanup: Collect spilled material mechanically; avoid creating dust; transfer to suitable containers for disposal
Reference to Other Sections: See sections on exposure controls and disposal considerations
Spill Handling: Sweep or vacuum up gently; wash contaminated area

Handling and Storage

Handling: Handle with adequate ventilation; avoid dust generation; wear protective clothing; wash hands after use
Storage: Store in dry, cool, well-ventilated area away from direct sunlight and sources of ignition
Incompatible Materials: Strong oxidizing agents, strong acids, strong bases
Specific Requirements: Keep containers tightly closed; avoid moisture ingress
Storage Temperature: 5-30°C recommended

Exposure Controls and Personal Protection

Occupational Exposure Limits: No OSHA or ACGIH limits assigned for blend; minimize dust and vapor exposure
Engineering Controls: Use local exhaust ventilation at processing points
Personal Protective Equipment: Protective gloves (nitrile or PVC); safety goggles; dust mask or respirator for dust-producing operations
Hygiene Measures: Do not eat, drink, or smoke during use; wash hands after handling
Environmental Controls: Ensure exhaust is filtered or scrubbed if required

Physical and Chemical Properties

Appearance: Granular solid or pellets; off-white or beige color
Odor: Slight, characteristic
pH: Not applicable
Melting Point: 120-160°C
Boiling Point: Decomposes before boiling
Flash Point: >300°C (estimated)
Vapor Pressure: Negligible at ambient temperature
Solubility in Water: Insoluble
Density: 1.20-1.35 g/cm³
Viscosity: Not applicable
Decomposition Temperature: Starts around 270°C

Stability and Reactivity

Chemical Stability: Stable under ordinary storage and handling conditions
Hazardous Reactions: No hazardous polymerization
Conditions to Avoid: Strong heat, direct sunlight, open flames
Incompatible Materials: Strong acids, bases, oxidizers
Hazardous Decomposition Products: Toxic gases such as carbon monoxide, hydrogen cyanide, phosphorus compounds on burning or heating

Toxicological Information

Acute Toxicity: Low oral and dermal toxicity expected
Skin Corrosion/Irritation: May cause mild to moderate irritation on prolonged or repeated contact
Serious Eye Damage/Irritation: Dusts or granules may cause eye discomfort or redness
Respiratory Effects: Dust may irritate upper airways or lungs
Chronic Effects: No significant data for chronic toxicity or carcinogenicity from similar blends
Sensitization: Not expected to cause skin sensitization
Mutagenicity: No known genetic risks

Ecological Information

Ecotoxicity: Compound has low bioavailability in environment; no acute aquatic toxicity expected from available data
Persistence and Degradability: Not readily biodegradable
Bioaccumulative Potential: Low due to polymeric structure
Mobility in Soil: Low
Other Adverse Effects: Contains phosphorus—avoid uncontrolled environmental release

Disposal Considerations

Waste Treatment Methods: Safe for landfill disposal if local regulations allow; incinerate under controlled conditions where permitted
Container Disposal: Rinse thoroughly before recycling or disposal; do not reuse containers for other purposes
RCRA Hazardous Waste: Not classified as hazardous waste
Waste Code: Consult local, regional, or national regulations

Transport Information

UN Number: Not regulated
UN Proper Shipping Name: Not classified as hazardous for transport
Transport Hazard Class: None assigned
Packing Group: Not applicable
Environmental Hazards: Not considered a marine pollutant
Special Precautions: Avoid mechanical shocks and impacts during transport

Regulatory Information

OSHA Hazard Communication Standard: Meets definition of hazardous chemical
TSCA Status: Compliant for commercial use in the United States
DSL/NDSL (Canada): Components listed
EINECS/ELINCS (Europe): Components listed or exempt
Labeling Requirements: Safety data sheet available; proper workplace labeling required
SARA Title III: No ingredients subject to reporting requirements
Other Regulations: Subject to workplace regulations for hazardous materials; additional local and regional requirements may apply