Urea Phosphate (UP) Material Safety Data Sheet (MSDS)

Identification

Product Name: Urea Phosphate (UP)
Chemical Formula: CO(NH2)2·H3PO4
Synonyms: Urea Phosphoric Acid, UP 17-44-0
Recommended Use: Fertilizer, Water Treatment, Cleaning Agent
Manufacturer Details: Name, address, and contact number listed on package or available from supplier
Emergency Number: Local emergency and poison control center contacts
CAS Number: 4861-19-2

Hazard Identification

GHS Classification: Eye Irritant Category 2, Skin Irritant Category 3
Signal Word: Warning
Hazard Statements: Causes eye irritation, may cause mild skin irritation, can irritate respiratory system
Pictograms: Exclamation mark (irritant hazard)
Precautionary Statements: Avoid breathing dust, wash thoroughly after handling, use eye protection, avoid contact with skin, store in well-ventilated place
Other Dangers: Dust can form explosive mixtures with air in rare situations involving large spills in enclosed spaces

Composition / Information on Ingredients

Chemical Identity: Urea Phosphate
CAS Number: 4861-19-2
Concentration: 98% or higher
Impurities: Trace amounts of urea (CAS 57-13-6) and phosphoric acid (CAS 7664-38-2), often less than 2% combined
Nature of Mixture: Solid compound formed from urea and phosphoric acid

First Aid Measures

Inhalation: Move person to fresh air, check for clear breathing, provide oxygen if available, seek medical advice for persistent symptoms
Eye Contact: Immediately flush eyes with plenty of water for 15 minutes, lift eyelids while flushing, seek medical attention if irritation continues
Skin Contact: Wash with soap and plenty of water, remove contaminated clothing, do not rewear clothing until thoroughly cleaned, seek doctor if rash develops
Ingestion: Rinse mouth with water, drink water to dilute, do not induce vomiting, consult doctor if significant amount swallowed or symptoms persist
Most Important Symptoms: Redness, irritation, coughing, sore throat, no specific antidote reported

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry powder, foam, carbon dioxide
Specific Hazards: Product does not ignite, can emit toxic fumes (nitrogen oxides, phosphorus oxides) at high temperatures
Special Protective Equipment: Firefighters wear self-contained breathing apparatus and protective clothing
Firefighting Instructions: Cool unopened containers exposed to heat, avoid breathing vapors or smoke, prevent runoff from contaminating water supplies
Explosion Data: No explosive properties, dust explosions possible in confined spaces but not common

Accidental Release Measures

Personal Precautions: Ventilate area, use personal protective equipment (gloves, goggles, dust mask), avoid contact with eyes and skin
Environmental Precautions: Prevent entry into drains, sewers, or waterways, contain spill with sand or similar inert material
Spill Cleanup Methods: Sweep up material and shovel into dry, labeled containers, wash spill area with lots of water after picking up solid product
Waste Disposal: Dispose of in line with local, state, and national regulations for chemical waste, avoid creating dust during cleanup

Handling and Storage

Handling: Wear protective gloves, goggles, dust mask, keep away from incompatible substances like strong bases and alkalis, do not eat or drink in work area, wash hands after handling
Storage Conditions: Store in cool, dry, well-ventilated space, keep away from moisture and sources of ignition, tightly close containers, keep separate from bases and oxidizers
Packaging Materials: Use plastic-lined bags or corrosion-resistant containers, keep containers upright and clearly labeled, avoid damage to packaging during transfer

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established TLV, OSHA, or ACGIH limits for urea phosphate itself
Engineering Controls: Use local exhaust or general room ventilation where dust may form, install eyewash stations nearby
Personal Protection: Wear chemical-resistant gloves (nitrile or PVC), tight-fitting safety goggles or face shield, dust mask or respirator if handling bulk powder or during spills, long sleeve clothing, closed shoes
Hygiene Measures: Remove contaminated clothes and wash hands after work, keep work area clean

Physical and Chemical Properties

Appearance: White powder or granules
Odor: Odorless
pH (1% Solution): 1.6 to 2.2 (acidic)
Melting Point: Begins to decompose above 115ºC
Solubility: Very soluble in water (approximately 600 grams per liter at room temperature)
Boiling Point: Not applicable (decomposes before boiling)
Vapor Pressure: Negligible at room temperature
Relative Density: 1.78 g/cm³
Reaction with Metals: May release hydrogen gas with certain reactive metals
Other Properties: Non-flammable, non-volatile, dust formation possible during transfer

Stability and Reactivity

Chemical Stability: Stable in dry, cool conditions, starts to break down in presence of moisture and heat
Reactivity: Reacts with bases and strong oxidizers, can release ammonia or phosphoric acid vapors in specific chemical reactions
Incompatible Materials: Avoid strong alkalis, reactive metals, oxidizing agents
Hazardous Decomposition Products: Ammonia, nitrogen oxides (NOx), phosphorus oxides (POx)
Conditions to Avoid: Exposure to excess moisture, extreme heat, and contact with incompatible substances accelerates decomposition

Toxicological Information

Acute Effects: Eyes may sting or redden, slight skin irritation possible, headache or coughing if dust inhaled
Long-Term Exposure: Usually not expected to cause chronic illness, but continued exposure to dust may lead to skin dryness, discomfort, or minor respiratory effects
Oral LD50 (Rat): Not precisely established, estimated >5000 mg/kg (indicates low toxicity)
Skin Sensitization: Usually none reported, wash skin to avoid irritation
Carcinogenicity, Mutagenicity, Reproductive Effects: Not known, based on current data no evidence of cancer or gene mutation risk in standard studies

Ecological Information

Aquatic Toxicity: High concentrations can harm aquatic life due to acidification of water
Mobility: Product dissolves in water and may leach into soil or watercourses, impacting pH balance
Persistence and Degradability: Breaks down to urea and phosphates, can contribute to nutrient loads and cause algal blooms
Bioaccumulation: Not expected to accumulate in aquatic organisms
Environmental Risks: Avoid release into surface waters, control runoff from agricultural use to prevent contamination of streams and lakes

Disposal Considerations

Waste Treatment Methods: Collect unused material and send to licensed landfill or incineration facility
Disposal of Containers: Rinse containers thoroughly, dispose in line with local hazardous waste regulations
Other Precautions: Do not dump into natural water bodies, avoid land application beyond agronomic recommendations to limit nutrient pollution
Legal Requirements: Check with state or municipal agencies for disposal rules in your area

Transport Information

UN Number: Not classified as dangerous for transport under current UN guidelines
Proper Shipping Name: Urea Phosphate
Hazard Class: None assigned
Packing Group: None assigned
Special Precautions: Keep containers upright and secure, avoid exposure of product to moisture during transportation, use well-sealed packaging where spillage could result in shipment loss
Other Notes: Local transport may have extra requirements for bulk shipments, check regional transport authorities for details

Regulatory Information

Labeling Requirements: Follow local and international standards for labeling irritant chemicals
Environmental Regulation: Product use in agriculture or cleaning may be subject to nutrient management plans or effluent limits
Worker Safety: OSHA, EU REACH, or other national workplace standards may apply, provide appropriate training and protective measures for handlers
Reporting Obligations: Large spills or off-label disposal might require notification of regional environmental authorities
Chemical Inventory Status: Listed in US TSCA, EU REACH, and other main chemical inventories